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dr hab. inż. Michał Strankowski
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- Associate professor at Department of Polymers Technology
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total: 79
Catalog Publications
Year 2024
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A Review of Recent Advances in Human-Motion Energy Harvesting Nanogenerators, Self-Powering Smart Sensors and Self-Charging Electronics
PublicationIn recent years, portable and wearable personal electronic devices have rapidly developed with increasing mass production and rising energy consumption, creating an energy crisis. Using batteries and supercapacitors with limited lifespans and environmental hazards drives the need to find new, environmentally friendly, and renewable sources. One idea is to harness the energy of human motion and convert it into electrical energy...
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Synthesis and Properties of the Ba2PrWO6 Double Perovskite
PublicationWe report details on the synthesis and properties of barium praseodymium tungstate, Ba2PrWO6, a double perovskite that has not been synthesized before. Room-temperature (RT) powder X-ray diffraction identified the most probable space group (SG) as monoclinic I2/m, but it was only slightly distorted from the cubic structure. X-ray photoelectron spectroscopy confirmed that the initial (postsynthesis) material contained praseodymium...
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Transport Mechanism of Paracetamol (Acetaminophen) in Polyurethane Nanocomposite Hydrogel Patches—Cloisite® 30B Influence on the Drug Release and Swelling Processes
PublicationThis article describes the swelling and release mechanisms of paracetamol in polyurethane nanocomposite hydrogels containing Cloisite® 30B (organically modified montmorillonite). The transport mechanism, swelling and release processes of the active substance in nanocomposite matrix were studied using gravimetric and UV-Vis spectroscopic methods. Swelling and release processes depend on the amount of clay nanoparticles in these...
Year 2022
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Graphene Reinforced Phenolic Foams
PublicationPhenolic foams (PF) belong to the polymeric materials, which are very attractive from the point of many possible applications such as insulation or fire protection materials. This chapter attempts to explain the influence of graphene and graphene derivatives on the phenolic foams. This work briefly presents different graphene nanoparticles introduced to the phenolic foams matrix, in terms of impact on the thermal, mechanical, and...
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High-density polyethylene/EPDM rubber blend composites of boron compounds for neutron shielding application
PublicationNovel materials with neutron shielding property were fabricated by incorporating boron compounds into highdensity polyethylene (HDPE)/Ethylene propylene diene monomer rubber (EPDM) blends. A detailed investigation on the morphological, thermal, mechanical, and neutron attenuation properties of suitable proportion of HDPE/EPDM blend with boric acid (BA), boron carbide (BC), and nano boron carbide (NBC) were performed. Morphology...
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Super tough interpenetrating polymeric network of styrene butadiene rubber‐poly (methyl methacrylate) incorporated with general purpose carbon black ( N660 )
PublicationA classic set of polymeric interpenetrating polymeric network (IPN) microcomposites has been fabricated using an elastomer—styrene butadiene rubber [SBR], a thermoplastic poly(methyl methacrylate)-PMMA and with carbon black (CB)-N660 as a filler and reinforcing agent. This synthesized IPN composite can be promisingly employed as a toughened plastic and vibrational damper in a wide service range with excellent thermal stability,...
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Synthesis Attempt and Structural Studies of Novel A2CeWO6 Double Perovskites (A2+ = Ba, Ca) in and outside of Ambient Conditions
PublicationSynthesis Attempt and Structural Studies of Novel A 2 CeWO 6 Double Perovskites (A 2+ = Ba, Ca) in and outside of Ambient Conditions Damian Wlodarczyk,* Mikolaj Amilusik, Katarzyna M. Kosyl, Maciej Chrunik, Krystyna Lawniczak-Jablonska, Michal Strankowski, Marcin Zajac, Volodymyr Tsiumra, Aneta Grochot, Anna Reszka, Andrzej Suchocki, Tomasz Giela, Przemyslaw Iwanowski, Michal Bockowski, and Hanka Przybylinska Cite This: ACS Omega...
Year 2021
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Fabrication of toughened plastic using styrene butadiene rubber-poly (methyl methacrylate) interpenetrating polymer networks
PublicationA standard set of interpenetrating polymeric networks (IPNs) has been contrived using an elastomerstyrene butadiene rubber and a thermoplastic poly (methyl methacrylate) through sequential polymerization protocol. This low-cost material can be hopefully engaged as a toughened plastic with cocontinuous morphology. Different morphological protocols including Raman imaging are effectively utilized to envisage the effect of blend ratio...
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Shape Memory Materials from Rubbers
PublicationSmart materials are much discussed in the current research scenario. The shape memory effect is one of the most fascinating occurrences in smart materials, both in terms of the phenomenon and its applications. Many metal alloys and polymers exhibit the shape memory effect (SME). Shape memory properties of elastomers, such as rubbers, polyurethanes, and other elastomers, are discussed in depth in this paper. The theory, factors...
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Shape-Memory Polyurethane Polymers
PublicationPolyurethanes (PUs) are one of the most widely used polymers in research and industry. They can be synthesized from chemical sources and natural sources. PUs are a very useful class of polymers and exhibit many desirable properties that can be exploited in various applications. PUs are formed by the reaction between polyols and isocyanates. A wide variety of polyols and isocyanates are available for synthesis, and hence we can...
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Structural evaluation of percolating, self-healing polyurethane–polycaprolactone blends doped with metallic, ferromagnetic, and modified graphene fillers
PublicationComposites with differently shaped micro- and nanofillers show various, unique thermal, and physicochemical properties when mixed with carefully chosen polymer matrix. Selected composition holds strategic value in achieving desired properties that is biodegradability, thermoelectric conductivity, and shape memory for organic coating. The main aim of this work is to briefly examine structural changes after reaching percolation threshold...
Year 2020
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Synergistic effect of MWCNTs and MA-g-PP on the thermal and viscoelastic properties of immiscible PTT/PP blends
PublicationThe properties of immiscible blends of PTT and PP were modified by grafting and nanoparticle inclusion. The observed synergistic effect of MWCNTs and MA-g-PP on the thermal and viscoelastic properties of PTT/PP blends was studied in detail and the properties of the composites were compared with those of ungrafted PP.
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Transport of paracetamol in swellable and relaxing polyurethane nanocomposite hydrogels
PublicationPolyurethane hydrogels are potentially attractive materials for biomedical applications. They are able to absorb large amount of water, biological fluids or active substances, and thus, they have potential to be used as absorbents or wound-healing dressings. They are also used for the controlled release of therapeutics because of their capacity to embed biologically active agents in their water-swollen network. The presence of...
Year 2018
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EFFECT OF ANTIOXIDANTS ON THE STABILITY OF PITCH- BASED POLYMER TO THERMO-OXIDATIVE ACTION
PublicationThe influence of stabilizers – hydrogen donors – on the processes of thermooxidative destruction of pitch-based polymer has been investigated. It is shown that Irganox has not stabilizing effect on pitch-based polymer and melamine slightly retards the destructive process. A mixture of melamine and Irganox exhibits synergetic stabilizing effect and at the optimum ratio it can be used to prevent unwanted thermooxidative processes...
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Effect of Variation of Hard Segment Content and Graphene-Based Nanofiller Concentration on Morphological, Thermal, and Mechanical Properties of Polyurethane Nanocomposites
PublicationThis study describes the development of a new class of high-performance polyurethane elastomer nanocomposites containing reduced graphene oxide (RGO) or graphene nanoplatelets (GNP). Two types of polyurethane elastomers with different contents of hard segments (HS) were used as a polymer matrix. The developed nanocomposites were characterized by thermal analysis (DSC, TG), dynamic mechanical testing (DMA), hardness testing, mechanical...
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Morphology, Mechanical and Thermal Properties of Thermoplastic Polyurethane Containing Reduced Graphene Oxide and Graphene Nanoplatelets
PublicationPolyurethane/graphene nanocomposites were synthesized using commercial thermoplastic polyurethane (TPU, Apilon 52DE55), and two types of graphene derivatives: graphene nanoplatelets (GNP) and reduced graphene oxide (RGO). Fourier Transformation Infrared Spectroscopy Fourier Transformation Infrared Spectroscopy (FTIR) spectroscopy, TEM, and SEM microscopy and XRD techniques were used to chemically and structurally characterize GNP...
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Recycled Polyurethane as a Second Phase in Thermoset Blends and Its Effect on Thermal Degradation Kinetics Studies
PublicationA new approach is introduced in the modification of thermosetting polymer by using different amount of polyurethane of waste origin. The post consumer polyurethane foam coatings are degraded using glycolysis process and the recycled product is further converted into new polyurethane. The blending of recycled polyurethane with epoxy exhibits transparency and produces nanostructures. The effective interaction between two polymers...
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Tuning of microstructure in engineered poly (trimethylene terephthalate) based blends with nano inclusion as multifunctional additive
PublicationImmiscible blends and their composites are heterogeneous and have variable morphology due to variation in mesophase regions. Tuning, i.e. controlling the phase dimension is important, thereof we report a “super-combo” effect of multiwalled carbon nanotubes (MWCNTs) in poly (trimethylene terephthalate)/polypropylene (PTT/ PP) blend system. MWCNTs act as a good reinforcing agent and compatibilizer in the otherwise immiscible PTT/...
Year 2017
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Elastic polyurethane foams containing graphene nanoplatelets
PublicationElastic polyurethane foams were produced from two-component polyurethane systems (SPECFLEX NE 113 izocyjanian/NR 816 poliol system—SPC and Elastic MBMarket company system POLYOL ET MB 500/ISO ET MB 800—ET) by using a one-step method. The foams were a graphene nanoplatelets (GNP) in the amount ranging from 1 to 2 wt.%. The effect of the nanofiller on polyurethane matrix was determined by analyzing the chemical structure, static...
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Nanosize effect of clay mineral nanoparticles on the drug diffusion processes in polyurethane nanocomposite hydrogels
PublicationStudies of swelling and release of naproxen sodium (NAP) solution by polyurethane nanocomposite hydrogels containing Cloisite® 30B (organically modified montmorillonite (OMMT)) have been performed. Polyurethane nanocomposite hydrogels are hybrid, nontoxic biomaterials with unique swelling and release properties in comparison with unmodified hydrogels. These features enable to use nanocomposite hydrogels as a modern wound dressing....
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Nonlinear Viscoelastic Properties of Polyurethane Nanocomposites
PublicationIn recent years, the nonlinear viscoelastic behaviors of elastomeric nanocomposites have been examined, especially for a wide range of rubbery composite (including natural rubber) materials. This chapter describes the influence of fillers and nanofillers on the nonlinear viscoelastic properties of elastomeric polyurethane systems. These filled elastomers (similar to the classic natural rubber reinforced elastomers), also exhibit...
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Shape Memory Polyurethane Materials Containing Ferromagnetic Iron Oxide and Graphene Nanoplatelets
PublicationIntelligent materials, such as memory shape polymers, have attracted considerable attention due to wide range of possible applications. Currently, intensive research is underway, in matters of obtaining memory shape materials that can be actuated via inductive methods, for example with help of magnetic field. In this work, an attempt was made to develop a new polymer composite—polyurethane modified with graphene nanoplates and...
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Synthesis and characterization of cycloaliphatic hydrophilic polyurethanes, modified with l-ascorbic acid, as materials for soft tissue regeneration
PublicationIn this paper we described synthesis and characteristic of obtained hydrophilic polyurethanes (PURs) modified with ascorbic acid (commonly known as vitamin C). Such materials may find an application in the biomedical field, for example in the regenerative medicine of soft tissues, according to ascorbic acid wide influence on tissue regeneration Flora (2009), Szymańska-Pasternak et al. (2011), Taikarimi and Ibrahim (2011), Myrvik...
Year 2016
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Chemical modifications of graphene and their influence on properties of polyurethane composites: a review
PublicationPolyurethane composites are materials of great interest nowadays due to their wide range of available forms and applications in industry. Controlling and achieving unique properties via matrix modifications and addition of various specific nanofillers seems be one of the key elements to success. The purpose of this work is to briefly present some examples of graphene nanoderivatives, their syntheses, properties and influence on...
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Eco-Friendly Electromagnetic Interference Shielding Materials from Flexible Reduced Graphene Oxide Filled Polycaprolactone/Polyaniline Nanocomposites
PublicationHybrid nanocomposites have the unique ability of enhancing material properties due to the existing synergistic effect of the fillers. In this study, the authors report such an eco-friendly hybrid nanocomposite comprising of polyaniline and reduced graphene oxide in polycaprolactone. The conducting polyaniline improved the processability of polycaprolactone, and the final composites were prepared by incorporating graphene oxide...
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Polyurethane Nanocomposites Containing Reduced Graphene Oxide, FTIR, Raman, and XRD Studies
PublicationRecently, graphene and other graphene-based materials have become an essential part of composite science and technology. Their unique properties are not only restricted to graphene but also shared with derivative compounds like graphene oxide, reduced graphene oxide, functionalized graphene, and so forth. One of the most structurally important materials, graphene oxide (GO), is prepared by the oxidation of graphite. Though removal...
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Thermal and Mechanical Properties of Microporous Polyurethanes Modified with Reduced Graphene Oxide
PublicationMicroporous polyurethanes (MPU) were modified by adding 0.25%–1.25 wt% of reduced graphene oxide (RGO). The materials were prepared without solvent via in situ polymerization. From a technological point of view, it is very important to obtain functional materials by using reacting compounds only. The thermal characteristics of obtained MPU were investigated using TGA, DSC, and DMA techniques. In comparison to nonmodified microporous...
Year 2015
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Effect of ground tire rubber on structural, mechanical and thermal properties of flexible polyurethane foams
PublicationFlexible polyurethane foams were modified with two kinds of ground tire rubber, untreated and thermo-mechanically reclaimed. A reclamation process was performed in auto-thermal conditions, which reduced the cost of the process and decreased the environmental impact of devulcanization (e.g., emission of gases). The reclamation process was carried out in a continuous manner using a co-rotating twin screw extruder. The foams were...
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Morphology and the physical and thermal properties of thermoplastic polyurethane reinforced with thermally reduced graphene oxide
PublicationIn this study, thermally reduced graphene oxide (TRG)-containing polyurethane nanocomposites were obtained by the extrusion method. The content of TRG incorporated into polyurethane elastomer systems equaled 0.5, 1.0, 2.0 and 3.0 wt%. The morphology, static and dynamic mechanical properties, and thermal stability of the modified materials were investigated. The application of TRG resulted in a visible increase in material stiffness...
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Polyurethane/ground tire rubber composite foams based on polyglycerol: processing, mechanical and thermal properties
PublicationDuring the synthesis of rigid polyurethane foams, petrochemical polyol was substituted with polyglycerol, the product of thermo-catalytic polycondensation of waste glycerol, resulting from biodiesel production. Two types of ground tire rubbers, untreated and thermo-mechanically reclaimed, were used to obtain ‘‘green’’ polyurethane-polyglycerol composite foams. Samples were prepared by a single-step method for the ratio of NCO/OH...
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Rigid polyurethane foams modified with ground tire rubber - mechanical, morphological and thermal studies
PublicationRigid polyurethane foams, prepared by a single step method, were modified with the two types of ground tire rubber particles, i.e. untreated and thermo-mechanically reclaimed by using a co-rotating twin screw extruder. The foaming process as well as the structure and the physical, mechanical and thermal properties of the resulting foams were investigated. The presence of ground tire rubber decreased the velocity of polymerization....
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Study of the effect of thermally reduced graphene oxide on the physical and mechanical properties of flexible polyurethane foams
PublicationFlexible polyurethane foams were obtained from a two-component system via the one-step method. The foams were modified with thermally reduced graphene oxide added in the amount equal to 0.25, 0.5 and 0.75 wt%. The morphology, static and dynamic properties, and thermal stability of modified foams were determined. The application of carbon filler resulted in the visible increase in the cell size, apparent density and rigidity of...
Year 2014
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Cadmium complex possessing simultaneously silanethiolato- and dithiocarbamato-ligands. A novel single-source precursor of cadmium sulfide
PublicationThermal decomposition of suitable coordination compounds may be used as efficient route for fabrication of semiconducting layers. A new potential CdS precursor—a cadmium complex with all-sulfur Cd-coordination sphere [Cd{l-SSi(OBut)3}(S2CNC4H8)]2 (1) —has been prepared and its properties are investigated. The complex was obtained in the reaction between dimeric bis(tri-tert-butoxysilanethiolato) cadmium(II) [Cd{SSi(OBut)3}2]2 and...
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Dielectric properties of modified graphene oxide filled polyurethane nanocomposites and its correlation with rheology
PublicationThis study aims at investigating the dynamic mechanical, dielectric and rheological properties of reinforced polyurethane (PU) nanocomposites containing hydrophilic graphene oxide (GO) and/or hydrophobic modified graphene oxide (mGO) sheets. The organic modification of GO was performed with 4,4′-methylenebis (phenyl isocyanate) (MDI) and the samples were prepared by solvent mixing. We found that addition of mGO provides a more...
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Evaluation of the photoprotective effect of ˇ-cyclodextrin on the emission of volatile degradation products of ranitidine
PublicationThe process of the photo-excitation of ranitidine hydrochloride (RAN) in a solid state makes visible changes to its colour and generates an unpleasant odour. The purpose of the present study was to observe the protective effects of ˇ-cyclodextrin (CD) complexation as well as the effect of the mixture of two stoichiometries 1:1 and 1:2 (RAN:CD, IC) on the photostability of samples in a solid state. Sam- ples of inclusion complexes...
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Morfologia, w³aoeciwooeci mechaniczne i termiczne elastycznych pianek poliuretanowych modyfikowanych glinokrzemianami warstwowymi
PublicationWytwarzane z udzia³em poligliceryny elastyczne pianki poliuretanowe modyfikowano za pomoc¹ montmorylonitu sodowego (bentonitu, MMT), mieszaniny bentonitu i bezhalogenowego fosforoorganicznego zwi¹zku zmniejszaj¹cego palnooeæ (Fyrol PNX) oraz, stanowi¹cego nape³niacz hybrydowy, bentonitu modyfikowanego wykorzystywanym uniepalniaczem. Badano mikrostrukturê, w³aoeciwooeci mechaniczne i termiczne modyfikowanych pianek poliuretanowych....
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Nonlinear viscoelasticity in Three Dimensional filler reinforced rubber composites and nanocomposites
PublicationThis chapter describes the influence of three-dimensional nanofillers used in elastomers on the nonlinear viscoelastic properties. In particular, this part focuses and investigates the most important three-dimensional nanoparticles, which are used to produce rubber nanocomposites. The rheological and the dynamic mechanical properties of elastomeric polymers, reinforced with spherical nanoparticles, like POSS, titanium dioxide and...
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Rigid polyurethane foams from a polyglycerol-based polyol
PublicationRigid polyurethane foams (rPUs) were synthesized by replacing 35 and 70 wt.% of petrochemical polyol with polyglycerol. Two types of polyglycerol with different molecular weights and hydroxyl numbers were used to obtain new ‘‘green’’ polyurethane–polyglycerol foams. The foams were prepared by a single step method for the ratio of NCO/OH groups equal to 2. rPUs synthesized with polyglycerol showed regular cellular structure, with...
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Synthesis and thermal studies of flexible polyurethane nanocomposite foams obtained using nanoclay modified with flame retardant compound
PublicationThis work presents thermal studies of nanocomposites based on the flexible polyurethane (PU) matrix and filled using montmorillonite organically modified with organophosphorus flame retardant compound. Flexible PU nanocomposite foams were prepared in the reaction carried out between reactive alcoholic hydroxyl and isocyanate groups with the ratio of NCO to OH groups equal to 1.05. The amount of an organoclay ranging from 3 to 9...
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Wpływ bezhalogenowych związków zmniejszających palność na strukturę oraz właściwości mechaniczne i termiczne elastycznych pianek poliuretanowych otrzymanych z poliglicerolu
PublicationElastyczne pianki poliuretanowe zostały przygotowane metodą jednostopniową z układu dwukomponentowego o stosunku grup NCO/OH wynoszącym 0.9:1. Pianki poliuretanowe poddano modyfikacji grafitem ekspandowanym oraz jego mieszaniną z fosforowym, bezhalogenowym związkiem zmniejszającym palność o nazwie handlowej Fyrol PNX. Scharakteryzowano statyczne i dynamiczne właściwości mechaniczne, morfologię, właściwości termiczne oraz palność...
Year 2013
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Interrelated shape memory and Payne effect in polyurethane/graphene oxide nanocomposites
PublicationWe report the fabrication of graphene oxide (GO) based polyurethane (PU) nanocomposites by a simple method of mixing and their shape memory properties at different temperatures. Both the polymer and the filler were synthesized in the laboratory by simple and easy methods – PU by pre-polymer method and GO by improved graphene oxide synthesis method. High molecular level dispersion of GO platelets within the PU matrix and thus good...
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Molecular dynamics studies of polyurethane nanocomposite hydrogels
PublicationPolyurethane PEO-based hydrogels have a broad range of biomedical applicability. They are attractive for drug-controlled delivery systems, surgical implants and wound healing dressings. In this study, a PEO based polyurethane hydrogels containing Cloisite R 30B, an organically modified clay mineral, was synthesized. Structure of nanocomposite hydrogels was determined using XRD technique. Its molecular dynamics was studied by means...
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Rigid polyurethane foams modified with selected layered silicate nanofillers
PublicationThe aim of this study was to investigate the effect of three different nanofillers on the properties of rigid polyurethane foams, which were prepared by a one-step, laboratory-scale method from a two-component system at the ratio of NCO groups to OH groups equaled to 2. The reaction mixture consisted of the proper amounts of the commercial oligoether polyol, catalysts, water, nanoclays, and polymeric diphenylmethane diisocyanate....
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Synergistic effect of multi walled carbon nanotubes and reduced graphene oxides in natural rubber for sensing application
PublicationUtilizing the electrical properties of polymer nanocomposites is an important strategy to develop high performance solvent sensors. Here we report the synergistic effect of multi walled carbon nanotubes (MWCNTs) and reduced graphene oxide (RGO) in regulating the sensitivity of the naturally occurring elastomer, natural rubber (NR). Composites were fabricated by dispersing CNTs alone and together with exfoliated RGO sheets (thermally...
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Thermal decomposition of [Cd{SSi(OBut)3}(S2CNC4H8)]2 to CdS “micro-noodles”
PublicationThis work presents studies on thermal degradation of novel heteroleptic complex possessing mixed S-donor ligands, [Cd{SSi(OBut)3}(S2CNC4H8)]2 using TGA, DSC, TGA-IR, SEM and XRD methods.
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Thermal treatment of montmorillonite modified with Cd[SC(NH2)2]42+ from two polymorphic salts
PublicationMontmorillonite(MMT)/CdS nanocomposites can be obtained using simple ionic exchange between Na(I)-MMT and Cd[SC(NH2)2]42+∙2NO3. The resulting products may be annealed to give (MMT)/CdS nanocomposites as it was proved by XRD analysis.
Year 2012
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Experimental examination of an elastomeric polymer
PublicationA new method of repairing damaged structures by filling the cracks with a specially prepared elastomeric polymer mass has been recently proposed. This new and innovative technique, known as the Flexible Joint Method (FJM), is mainly dedicated to masonries and historical objects, where minimum intervention is permitted. The flexible joint bonds the disrupted elements and ensures further safe exploitation of a damaged structure....
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Mechanical, structural and diffusion studies of hydrogel polyurethane nanocomposites containing modified montmorillonite
PublicationW pracy zaprezentowano wyniki badań hydrożeli poliuretanowych zawierających poli(tlenek etylenu) oraz montmorylonit. Otrzymane układy scharakteryzowano z użyciem technik XRD, DMA, badań mechanicznych oraz wyznaczono chłonność wody i parametry dyfuzji.
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Preparation and characterization of rigid polyurethane -polyglycerol nanocomposite foams
PublicationThis work reports on the preparation of polyurethane–polyisocyanurate (PUR–PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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Preparation and characterization of rigid polyurethane-polyglycerolnanocomposite foams
PublicationThis work reports on the preparation of polyurethane-polyisocyanurate (PUR-PIR) foams containing different polyglycerols and layered silicate nanoclays. The rigid polyurethane foams were obtained in a laboratory scale, in a single step method, from a two-component system with a NCO to OH groups ratio equal to two. The reaction mixture consisted of the proper amounts of a commercial oligoetherpolyol, polyglycerol, catalysts, water,...
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