Abstract
A combinatorial route has been applied in cure kinetics study of epoxy nanocomposites containing multi-walled carbon nanotubes (MWCNTs) based on differential scanning calorimetry and rheokinetic analyses under isothermal conditions. Pristine and amine-modified MWCNTs bearing primary and secondary amines were used at very low concentrations (0.1 and 0.3 wt.% based on epoxy weight). Model-free and model-fitting methods were applied on calorimetric data, and Kamal autocatalytic model revealed good agreement with the experimental data. In case of epoxy filled with amine-modified MWCNTs, activation energy took a value lower than that obtained for sample containing pristine MWCNTs at an identical loading because of less hindrance brought about by curing. Isothermal rheokinetic studies supported formation of a filler network during processing, which hindered epoxy-anhydride cure reaction at higher MWCNTs loadings leading to a highly crosslinked epoxy network.
Citations
-
6 3
CrossRef
-
0
Web of Science
-
5 7
Scopus
Authors (6)
Cite as
Full text
full text is not available in portal
Keywords
Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
PROGRESS IN ORGANIC COATINGS
no. 108,
pages 75 - 83,
ISSN: 0300-9440 - Language:
- English
- Publication year:
- 2017
- Bibliographic description:
- Vijayan P., Puglia D., Rastin H., Saeb M., Shojaei B., Formela K.: Cure kinetics of epoxy/MWCNTs nanocomposites: Isothermal calorimetric and rheological analyses// PROGRESS IN ORGANIC COATINGS. -Vol. 108, (2017), s.75-83
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.porgcoat.2017.04.005
- Verified by:
- Gdańsk University of Technology
seen 144 times
Recommended for you
Cure kinetics of epoxy/MWCNTs nanocomposites: Nonisothermal calorimetric and rheokinetic techniques
- M. Saeb,
- H. Rastin,
- M. Nonahal
- + 3 authors
Epoxy/Ionic Liquid-Modified Mica Nanocomposites: Network Formation–Network Degradation Correlation
- M. Jouyandeh,
- V. Akbari,
- S. M. R. Paran
- + 4 authors
Biowaste chicken eggshell powder as a potential cure modifier for epoxy/anhydride systems: competitiveness with terpolymer-modified calcium carbonate at low loading levels
- M. Saeb,
- M. Ghaffari,
- H. Rastin
- + 8 authors
Curing behavior of epoxy/Fe 3 O 4 nanocomposites: A comparison between the effects of bare Fe 3 O 4 , Fe 3 O 4 /SiO 2 /chitosan and Fe 3 O 4 /SiO 2 /chitosan/imide/phenylalanine-modified nanofillers
- M. Jouyandeh,
- S. Paran,
- M. Shabanian
- + 6 authors