Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures - Publication - Bridge of Knowledge

Search

Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures

Abstract

Deep eutectic solvents have quickly attracted the attention of researchers because they better meet the requirements of green chemistry and thus have the potential to replace conventional hazardous organic solvents in some areas. To better understand the nature of these mixtures, as well as expand the possibilities of their use in different industries, a detailed examination of their physical properties, such as density, viscosity, the nature of the interactions between their constituents, the phase diagrams, depression of their melting point, and interpretation of these results is necessary. In this work, the mixtures of tetrabutylammonium bromide (TBAB) and nonanoic acid (NA) in different molar ratios are theoretically and experimentally investigated by applying a phase diagram constructed on the basis of differential scanning calorimetry measurements and COSMO-RS model. Spectral properties are investigated based on Fourier transform infrared spectroscopy and density functional theory. The observed eutectic point indicates the formation of a DES in the TBAB−NA system in a 1:2 molar ratio. This is due to the presence of hydrogen bonds between the carboxyl group from the NA molecule and the bromine atom from the TBAB molecule. Other eutectic mixtures are most likely the solutions of TBAB in NA, in which hydrogen bonds predominate between acid molecules.

Citations

  • 4 3

    CrossRef

  • 0

    Web of Science

  • 3 7

    Scopus

Keywords

Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
JOURNAL OF PHYSICAL CHEMISTRY B no. 126, pages 3889 - 3896,
ISSN: 1520-6106
Language:
English
Publication year:
2022
Bibliographic description:
Shishov A., Makoś-Chełstowska P., Bulatov A., Andruch V.: Deep Eutectic Solvents or Eutectic Mixtures? Characterization of Tetrabutylammonium Bromide and Nonanoic Acid Mixtures// JOURNAL OF PHYSICAL CHEMISTRY B -Vol. 126,iss. 21 (2022), s.3889-3896
DOI:
Digital Object Identifier (open in new tab) 10.1021/acs.jpcb.2c00858
Sources of funding:
  • IDUB
Verified by:
Gdańsk University of Technology

seen 132 times

Recommended for you

Meta Tags