Formation enthalpies of LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) interlanthanide perovskites - Publication - Bridge of Knowledge

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Formation enthalpies of LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) interlanthanide perovskites

Abstract

High-temperature oxide melt solution calorimetry using 3Na2O·MoO3 at 802 °C was performed for interlanthanide perovskites LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) and lanthanide oxides (La2O3, Ho2O3, Er2O3, Tm2O3 and Yb2O3). The enthalpies of formation of these interlanthanide perovskites from binary lanthanide oxides at room temperature (25 °C) were determined to be −8.3±3.4 kJ/mol for LaHoO3, −9.9±3.0 kJ/mol for LaErO3, −10.8±2.7 kJ/mol for LaTmO3 and −12.3±2.9 kJ/mol for LaYbO3. There is a roughly linear relationships between these enthalpy values and the tolerance factor for these and for other LaM3+O3 (M=In, Sc, Ga, Al, Fe and Cr) perovskites, confirming that the distortion of the perovskites as results from ionic radius difference of A-site and B-site cations, is the main factor determining the stability of these compounds.

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Authors (4)

  • Photo of  Jianqi Qi

    Jianqi Qi

    • Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, CA 95616 USA College of Physical Science and Technology, Sichuan University, Chengdu 610064, PR China
  • Photo of  Xiaofeng Guo

    Xiaofeng Guo

    • Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, CA 95616 USA Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, CA 95616 USA
  • Photo of  Alexandra Navrotsky

    Alexandra Navrotsky

    • Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, CA 95616 USA Peter A. Rock Thermochemistry Laboratory and NEAT ORU, University of California, Davis, CA 95616 USA

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Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF SOLID STATE CHEMISTRY no. 227, pages 150 - 154,
ISSN: 0022-4596
Language:
English
Publication year:
2015
Bibliographic description:
Qi J., Guo X., Mielewczyk-Gryń A., Navrotsky A.: Formation enthalpies of LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) interlanthanide perovskites// JOURNAL OF SOLID STATE CHEMISTRY. -Vol. 227, (2015), s.150-154
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jssc.2015.03.026
Verified by:
Gdańsk University of Technology

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