Abstract
High-temperature oxide melt solution calorimetry using 3Na2O·MoO3 at 802 °C was performed for interlanthanide perovskites LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) and lanthanide oxides (La2O3, Ho2O3, Er2O3, Tm2O3 and Yb2O3). The enthalpies of formation of these interlanthanide perovskites from binary lanthanide oxides at room temperature (25 °C) were determined to be −8.3±3.4 kJ/mol for LaHoO3, −9.9±3.0 kJ/mol for LaErO3, −10.8±2.7 kJ/mol for LaTmO3 and −12.3±2.9 kJ/mol for LaYbO3. There is a roughly linear relationships between these enthalpy values and the tolerance factor for these and for other LaM3+O3 (M=In, Sc, Ga, Al, Fe and Cr) perovskites, confirming that the distortion of the perovskites as results from ionic radius difference of A-site and B-site cations, is the main factor determining the stability of these compounds.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
JOURNAL OF SOLID STATE CHEMISTRY
no. 227,
pages 150 - 154,
ISSN: 0022-4596 - Language:
- English
- Publication year:
- 2015
- Bibliographic description:
- Qi J., Guo X., Mielewczyk-Gryń A., Navrotsky A.: Formation enthalpies of LaLn׳O3 (Ln׳=Ho, Er, Tm and Yb) interlanthanide perovskites// JOURNAL OF SOLID STATE CHEMISTRY. -Vol. 227, (2015), s.150-154
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.jssc.2015.03.026
- Verified by:
- Gdańsk University of Technology
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