Search
Magnetic deep eutectic solvents for vortex-assisted liquid phase microextraction method for selective and green extraction of patulin from fruits and fruit juices
Abstract
In this study, a vortex assisted magnetic deep eutectic solvent based liquid phase microextraction (VA-MDES-LPME) technique was developed for the extraction of patulin prior to its determination by ultraviolet–visible spectrophotometry (UV–Vis). For this purpose, the use of a magnetic deep eutectic solvent (MDES) consisting of trihexyltetradecylphosphonium chloride, MnCl2, and octanoic acid (molar ratio 1:2:2) was tested to perform an efficient extraction. Important experimental parameters (MDES-3 vol, pH, vortex time, and ethanol volume) were optimized using Box-Behnken Design. Under optimum conditions (MDES-3 vol 560 µL, pH 3.5, vortex time 300 s, and ethanol volume 300 µL), the limits of detection for the model solution and matrix-matched solution were 0.06 ng mL−1 and 0.37 ng mL−1, and the calibration ranges were 0.2–400 ng mL−1 and 1.2–300 ng mL−1, respectively. Furthermore, the extraction recovery was calculated to be 96.3–97.4 % with a low relative standard deviation (2.1–2.5 %). The VA-MDES-LPME technique was successfully applied for the determination of patulin from fruit and juice samples with an enrichment factor between169 and 185.
Citations
-
0
CrossRef
-
0
Web of Science
-
0
Scopus
Authors (3)
-
Hameed Ul Haq
-
Nail Altunay
Cite as
Full text
full text is not available in portal
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
MICROCHEMICAL JOURNAL
no. 208,
ISSN: 0026-265X - Language:
- English
- Publication year:
- 2025
- Bibliographic description:
- Haq H. U., Boczkaj G., Altunay N.: Magnetic deep eutectic solvents for vortex-assisted liquid phase microextraction method for selective and green extraction of patulin from fruits and fruit juices// MICROCHEMICAL JOURNAL -Vol. 208, (2025), s.112472-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.microc.2024.112472
- Sources of funding:
- Verified by:
- Gdańsk University of Technology
seen 44 times
Recommended for you
Investigation of vortex assisted magnetic deep eutectic solvent based dispersive liquid–liquid microextraction for separation and determination of vanadium from water and food matrices: Multivariate analysis
- N. Altunay,
- M. Farooque Lanjwani,
- M. Tuzen
- + 1 authors