Search
Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)
Abstract
tBu2P-PLi-PtBu2·2THF reacts with [(R3P)2MCl2] (M = Pt, Pd, Ni; R3P = Et3P, pTol3P, Ph2EtP, iPr3P) to yield isomers of [(1,2-η-tBu2P=P-PtBu2)M(PR3)Cl], in which the tBu2P-P-PtBu2 ligand adopts the arrangement of a side-on bonded 1,1-di-tert-butyl-2-(di-tert-butylphosphanyl)diphosphenium cation. tBu2P-PLi-P(NEt2)2·2THF reacts with [(R3P)2MCl2] but does not form complexes with a tBu2P-P-P(NEt2)2 moiety, however, splitting of a P-P(NEt2)2 bond of the parent triphosphane takes place.
Authors (5)
Cite as
Full text
full text is not available in portal
Keywords
Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
no. 636,
ISSN: 0044-2313 - Language:
- English
- Publication year:
- 2010
- Bibliographic description:
- Wiśniewska A., Kazimierczuk K., Grubba R., Matern E., Pikies J.: Reactions of Lithium Salts of Triphosphanes tBu2P-PLi-PtBu2 and tBu2P-PLi-P(NEt2)2 with Metal Complexes [(R3P)2MCl2] (M = Ni, Pd, Pt, R3P = Et3P, pTol3P, Ph2EtP, iPr3P)// ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. -Vol. 636, nr. iss. 8 (2010),
- Verified by:
- Gdańsk University of Technology
seen 97 times
Recommended for you
Reactions of tBu2P-PLi-P(tBu)2 with [(Et3P)2MCl2] (M = Ni, Pd, Pt). Synthesis and properties of [(1,2-h-tBu2P=P-P(tBu)2)M(PEt3)Cl] (M=Ni, Pd)
- E. Baum,
- E. Matern,
- A. Robaszkiewicz
- + 1 authors
2006
From phosphanylphosphaalkenes to coordination copper and silver polymers containing P–P bonds
- A. Ziółkowska,
- M. Prześniak-Welenc,
- T. Kruczyński
- + 2 authors
2024