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The Effect of Polyurethane Glycolysate on the Structure and Properties of Natural Rubber/Carbon Black Composites

Abstract

In this work the use of polyurethane chemical recycling product (i.e. glycolysis of polyurethane waste realized with the mass excess of polymer) as a plasticizer for natural rubber-based composites was proposed. The effect of plasticizer type (napthenic oil and polyurethane foam glycolysate) and amount (2, 4, 6 or 8 parts per 100 parts of natural rubber) on the processing properties of rubber mixtures and chemical structure, swelling, mechanical and thermo-mechanical properties of natural rubber/carbon black composites was investigated. The effect of applied plasticizer was studied in the context of accelerated thermal aging (thermo-oxidative aging) which was applied for the prepared natural rubber-based composites. The obtained results confirm that the polyurethane foam glycolysate can be successfully used as a plasticizer for the preparation of natural rubber composites. Moreover, it was found that glycolysate acts as a vulcanization accelerator and reduces decreasing of mechanical properties during the accelerated thermal aging.

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Authors (3)

Keywords

Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF POLYMERS AND THE ENVIRONMENT no. 27, pages 1367 - 1378,
ISSN: 1566-2543
Language:
English
Publication year:
2019
Bibliographic description:
Włoch M., Ostaszewska U., Datta J.: The Effect of Polyurethane Glycolysate on the Structure and Properties of Natural Rubber/Carbon Black Composites// JOURNAL OF POLYMERS AND THE ENVIRONMENT. -Vol. 27, iss. 6 (2019), s.1367-1378
DOI:
Digital Object Identifier (open in new tab) 10.1007/s10924-019-01437-8
Verified by:
Gdańsk University of Technology

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