Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers

Paulina Parcheta-Szwindowska; Iwona Koltsov; Ewa Głowińska; Janusz Datta

doi:10.14314/polimery.2018.10.6

Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers

Abstract

Linear biobased polyester polyols were prepared with the use of succinic acid and 1,3-pro- panediol (both with natural origin). Tetraisopropyl orthotitanate (TPT) was used as a catalyst. In order to determine the effect of various synthesis temperature conditions on the thermal degradation kinet- ics, nine sequences of temperature conditions were used during two-step polycondensation reaction. Thermogravimetric analysis was conducted with the use of DSC-TG/QMS method (differential scanning calorimetry-coupled with thermogravimetry and quadrupole mass spectrometry). The results indicated high thermal stability of the obtained materials. They undergo a one-step thermal decomposition with the temperature of maximum rate of weight loss at ca. 405 °C. Moreover, the thermal degradation kinet- ics was determined with the use of Ozawa, Flynn and Wall as well as Kissinger methods. The highest thermal degradation activation energy was equal to 196.4 kJ/mol.

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Authors (4)

Paulina Parcheta-Szwindowska (formerly: Paulina Parcheta) dr inż.
Iwona Koltsov dr inż.
- Instytut Wysokich Ciśnień PAN Pracowania Analizy Termicznej
Ewa Głowińska dr inż.
Janusz Datta prof. dr hab. inż.

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Category:: Articles
Type:: artykuł w czasopiśmie wyróżnionym w JCR
Published in:: Polimery no. 10, pages 44 - 52,
ISSN: 0032-2725
Language:: English
Publication year:: 2018
Bibliographic description:: Parcheta P., Koltsov I., Głowińska E., Datta J.: Thermal degradation kinetics of poly(propylene succinate) prepared with the use of natural origin monomers// Polimery. -Vol. 10, nr. 63 (2018), s.44-52
DOI:: Digital Object Identifier (open in new tab) 10.14314/polimery.2018.10.6
Verified by:: Gdańsk University of Technology