Jakub Bruniecki - Publications - Bridge of Knowledge

Jakub Bruniecki

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Year 2021

The Reactivity of the Imine Bond within Polynuclear Nickel(II) Complexes
Publication
- M. Siedzielnik
- D. A. Pantazis
- J. Bruniecki
- K. Kaniewska-Laskowska
- A. Dołęga
- Crystals - Year 2021
Three novel Ni complexes with the Schiff base ligand 2-methoxy-6-(E-2-pyridyliminomethyl)-phenol (L1) are described. In comparison with the similar 2-(pyridine-2-ylimino-methyl)phenol (pymp), the mode of coordination of L1 is altered due to the presence of methoxy substituent introducing the sterical hindrance. During the synthesis of the complexes, partial hydrolysis of the ligand was observed. Since such immediate hydrolysis...

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