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Joanna Brzoska
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- PhD student at Department of Polymer Technology
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total: 6
Catalog Publications
Year 2024
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A green route for high-performance bio-based polyurethanes synthesized from modified bio-based isocyanates
PublicationThe need for sustainability and a circular economy leads to the development of innovative greener materials and technologies. This paper is focused on a novel class of bio-based polyurethanes (PUs) synthesized with the use of bio-monomers including bio-based isocyanates. The novelty of this work is related to the usage of bio-based modified isocyanate via a two-step solvent-free synthesis of novel cast bio-based poly(ester-urethanes)...
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Structure versus hydrolytic and thermal stability of bio-based thermoplastic polyurethane elastomers composed of hard and soft building blocks with high content of green carbon
PublicationNowadays, sustainability plays a key role in the design and synthesis of new materials. One of the methods for the preparation of green materials is incorporation into their structure the monomers with a high content of green carbon. Therefore, the aim of this work was to investigate the influence of the type and molecular mass of two bio-based polyester polyols and bio-glycol on the properties of aliphatic partially bio-based...
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Synteza i charakterystyka „zielonych” mieszanin polimerowych na bazie biopochodnego termoplastycznego poliuretanu i octanomaślanu celulozy
PublicationOtrzymano mieszaniny polimerowe z biopochodnego termoplastycznego poliuretanu (TPU) i dostępnego handlowo octanomaślanu celulozy (CAB), stosowanego w ilości 0–20%. TPU syntezowano metodą prepolimerową z wykorzystaniem biopoliolu, glikolu 1,3-propylenowego i diizocyjanianu heksametylenu. Materiały poddano analizie pod kątem struktury chemicznej (FTIR), właściwości termicznych (TGA, DSC) i właściwości termomechanicznych (DMTA).
Year 2023
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Challenges and recent advances in bio-based isocyanate production.
PublicationPolyurethanes (PUs) are key players in the plastics industry. According to the Global Polyurethane Market (2019–2023), their value in the global market reached $95.13 billion in 2019 and is expected to grow at a compound annual growth rate of 12%. This is in line with the increase in the number of research papers and patents on the synthesis and application of petroleum-based PUs (P-PUs) and biomass or green PUs (G-PUs) (from 67 657...
Year 2021
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Eco-Friendly Ether and Ester-Urethane Prepolymer: Structure, Processing and Properties
PublicationThis study concerns bio-based urethane prepolymers. The relationship between the chemical structure and the thermal and processing parameters of bio-based isocyanate-terminated ether and ester-urethane prepolymers was investigated. Bio-based prepolymers were obtained with the use of bio-monomers such as bio-based diisocyanate, bio-based polyether polyol or polyester polyols. In addition to their composition, the bio-based prepolymers...
Year 2020
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Termoplastyczne elastomery poli(estro-uretanowe) otrzymywane z udziałem bio-glikolu poddane dwukrotnemu przetwórstwu
PublicationRecykling materiałów polimerowych w istotny sposób wpływa na zmniejszenie ilości odpadów z tworzyw sztucznych składowanych na wysypiskach śmieci. Jedną z metod recyklingu jest recykling mechaniczny, stosowany szczególnie w przypadku materiałów o właściwościach termoplastycznych. W pracy zbadano wpływ dwukrotnego przetwórstwa termoplastycznych elastomerów poli(estro-uretanowych), TPU, otrzymywanych z udziałem bio-glikolu na strukturę...
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