Additive manufacturing technology of electroactive three-dimensional structures from diamond reinforced polylactide composites

The project focuses on the development of 3D printing technology using polylactide reinforced with diamond powder, enabling the development of 4D materials for the construction of free-standing sensory systems and actuators with characteristics modifiable by environmental factors. As part of the project, the authors intend to study the micromechanical and rheological interactions of composites, and the mechanisms of charge transfer in the volume of the material and on its surface. The main goal of the study concerns the determination and design of the stability of nanomechanical and electrochemical parameters of the composite, in terms of its use in accordance with the concept of intelligent 4D materials, including microelectrode matrix systems and flow sensors. The generated structures will be tested for the detection of selected organic compounds - anti-inflammatory drugs and antibiotics. The project will contribute to the expansion of the laboratory for the study of electrochemical and physicochemical phenomena of the Gdańsk University of Technology, and will result in numerous publications in Q1 ISI journals. Materials of high application and implementation importance will be produced and improved, which will be the basis for further grant projects, patents and cooperation. New experimental tools and modeling procedures will be developed. The research will be conducted in cooperation with the Faculty of Chemistry of the University of Gdańsk. The project closely matches the topics implemented within Advanced Materials and BioTechMed Centres, contributing the development of GUT's main research areas as part of the IDUB project.

Details

Project's acronym:

DIP-4D

Financial Program Name:

SONATA_BIS

Organization:

Narodowe Centrum Nauki (NCN) (National Science Centre)

Agreement:

UMO-2020/38/E/ST8/00409 z dnia 2021-03-25

Realisation period:

2021-03-25 - 2024-09-24

Project manager:

dr hab. inż. Jacek Ryl

Realised in:

Institute of Nanotechnology and Materials Engineering

External institutions participating in project:

Uniwersytet Gdański (Poland)

Project's value:

1 982 560.00 PLN

Request type:

National Research Programmes

Domestic:

Domestic project

Verified by:

Gdańsk University of Technology

Papers associated with that project

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total: 10

Year 2024

Microwave-Induced Processing of Free-Standing 3D Printouts: An Effortless Route to High-Redox Kinetics in Electroanalysis
Publication
- K. Kozłowska
- M. Cieślik
- A. Koterwa
- K. Formela
- J. Ryl
- P. Niedziałkowski
- Materials - Year 2024
3D-printable composites have become an attractive option used for the design and manufacture of electrochemical sensors. However, to ensure proper charge-transfer kinetics at the electrode/electrolyte interface, activation is often required, with this step consisting of polymer removal to reveal the conductive nanofiller. In this work, we present a novel effective method for the activation of composites consisting of poly(lactic...

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Unlocking the electrochemical performance of glassy carbon electrodes by surface engineered, sustainable chitosan membranes
Publication
- A. Smułka
- M. Cieślik
- A. Olejnik
- A. Zieliński
- J. Ryl
- T. Ossowski
- BIOELECTROCHEMISTRY - Year 2024
Chitosan coatings, derived from crustacean shell waste, possess inherent biocompatibility and biodegradability, rendering them suitable for various biomedical and environmental applications, including electrochemical biosensing. Its amine and hydroxyl functional groups offer abundant sites for chemical modifications to boost the charge transfer kinetics and provide excellent adhesion, enabling the construction of robust electrode-coating...

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Year 2023

Boron-doped diamond nanosheet volume-enriched screen-printed carbon electrodes: a platform for electroanalytical and impedimetric biosensor applications
Publication
- M. Ficek
- M. Cieślik
- M. Janik
- M. Brodowski
- S. Mirosław
- R. Bogdanowicz
- J. Ryl
- MICROCHIMICA ACTA - Year 2023
This paper focuses on the development of a novel electrode based on boron-doped diamond nanosheet full-volume-enriched screen-printed carbon electrodes (BDDPE) for use as an impedimetric biosensor. Impedimetric biosensors offer high sensitivity and selectivity for virus detection, but their use as point-of-care devices is limited by the complexity of nanomaterials’ architecture and the receptor immobilisation procedures. The study...

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Multiple Reprocessing of Conductive PLA 3D-Printing Filament: Rheology, Morphology, Thermal and Electrochemical Properties Assessment
Publication
- Materials - Year 2023
Additive manufacturing technologies are gaining more and more attention, resulting in the development or modification of 3D printing techniques and dedicated materials. On the other hand, economic and ecological aspects force the industry to develop material recycling strategies. In this work, the multiple reprocessing of a commercially available PLA conductive composite with carbon black filler, dedicated to 3D printing, was investigated....

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Tailoring diamondised nanocarbon-loaded poly(lactic acid) composites for highly electroactive surfaces: extrusion and characterisation of filaments for improved 3D-printed surfaces
Publication
- MICROCHIMICA ACTA - Year 2023
A new 3D-printable composite has been developed dedicated to electroanalytical applications. Two types of diamondised nanocarbons - detonation nanodiamonds (DNDs) and boron-doped carbon nanowalls (BCNWs) - were added as fillers in poly(lactic acid) (PLA)-based composites to extrude 3D filaments. Carbon black served as a primary filler to reach high composite conductivity at low diamondised nanocarbon concentrations (0.01 to 0.2...

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Year 2022

Locally sculptured modification of the electrochemical response of conductive poly(lactic acid) 3D prints by femtosecond laser processing
Publication
- M. Cieślik
- M. Sawczak
- R. Jendrzejewski
- J. Celej
- W. Nogala
- J. Ryl
- ELECTROCHIMICA ACTA - Year 2022
This manuscript presents an approach to sculpture high electrochemical activity of the 3D printed electrodes with poly(lactic acid) (PLA) matrix and carbon black (CB) filler by femtosecond laser (FSL) ablation. CB-PLA utility for electrochemical applications depends on a surface modification aiming to remove the PLA and uncover the conductive CB. We have discussed how laser pulse energy is critical for such an activation process....

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Structural and electrochemical heterogeneities of boron-doped diamond surfaces
Publication
- R. Bogdanowicz (formerly: S. Bogdanowicz)
- J. Ryl
- Current Opinion in Electrochemistry - Year 2022
This brief review is focussed on the recent progress in studies of the heterogeneous electrochemical behaviour of various boron-doped materials extending from zero-dimensional particles through polycrystalline or nanostructured three-dimensional surfaces. A boron-doped diamond reveals large heterogeneities induced by numerous factors, inter alia multi-faceted crystallinity, inhomogeneous boron concentration, sp2/sp3-carbon ratio,...

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The role of electrolysis and enzymatic hydrolysis treatment in the enhancement of the electrochemical properties of 3D-printed carbon black/poly(lactic acid) structures
Publication
- A. Koterwa
- I. Kaczmarzyk
- S. Mania
- M. Cieślik
- R. Tylingo
- T. Ossowski
- R. Bogdanowicz
- P. Niedzialkowski
- J. Ryl
- APPLIED SURFACE SCIENCE - Year 2022
Additive manufacturing, also known as 3D printing, is beginning to play an unprecedented role in developing many applications for industrial or personalized products. The conductive composite structures require additional treatment to achieve an electroactive surface useful for electrochemical devices. In this paper, the surfaces of carbon black/poly(lactic acid) CB-PLA printouts were activated by electrolysis or enzymatic digestion...

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Tuning the Laser-Induced Processing of 3D Porous Graphenic Nanostructures by Boron-Doped Diamond Particles for Flexible Microsupercapacitors
Publication
- S. Deshmukh
- P. Jakóbczyk
- M. Ficek
- J. Ryl
- D. Geng
- R. Bogdanowicz
- ADVANCED FUNCTIONAL MATERIALS - Year 2022
Carbon (sp3)-on-carbon (sp2) materials have the potential to revolutionize fields such as energy storage and microelectronics. However, the rational engineering and printing of carbon-on-carbon materials on flexible substrates remains a challenge in wearable electronics technology. This study demon-strates the scalable fabrication of flexible laser-induced graphene (LIG)-boron doped diamond nanowall (BDNW) hybrid nanostructures...

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Year 2021

Helium-assisted, solvent-free electro-activation of 3D printed conductive carbon-polylactide electrodes
Publication
- M. J. Głowacki
- M. Cieślik
- M. Sawczak
- A. Koterwa
- I. Kaczmarzyk
- R. Jendrzejewski
- Ł. Szynkiewicz
- T. Ossowski
- R. Bogdanowicz
- P. Niedziałkowski
- J. Ryl
- APPLIED SURFACE SCIENCE - Year 2021
Fused filament fabrication is one of the most rapidly developing 3D printing techniques, with numerous applications, including in the field of applied electrochemistry. Here, the utilisation of conductive carbon black polylactic acid (CB-PLA) for 3D printouts is the most promising. To use CB-PLA as an electrode material, an activation process must be performed, removing the polymer matrix and uncovering the electrically conductive...

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