A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties - Publication - MOST Wiedzy

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A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties

Abstract

Mononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone and field induced slow magnetic relaxation, which is a very rare phenomenon among Cu(II) complexes.

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Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
DALTON TRANSACTIONS
ISSN: 1477-9226
Language:
English
Publication year:
2019
Bibliographic description:
Mielcarek A., Bieńko A., Saramak P., Jezierska J., Dołęga A.: A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties// DALTON TRANSACTIONS -,iss. 48 (2019),
DOI:
Digital Object Identifier (open in new tab) 10.1039/c9dt03304a
Verified by:
Gdańsk University of Technology

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