Apparent molar volumes and compressibilities of lanthanum, gadolinium, lutetium and sodium trifluoromethanesulfonates in N,N-dimethylformamide and N,N-dimethylacetamide - Publication - Bridge of Knowledge

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Apparent molar volumes and compressibilities of lanthanum, gadolinium, lutetium and sodium trifluoromethanesulfonates in N,N-dimethylformamide and N,N-dimethylacetamide

Abstract

Zmierzono gęstości roztworów trifluorometanosulfonianów lantanu, gadolinu i lutetu w N,N-dimetyloformamidzie i N,N-dimetyloacetamidzie w szerokim zakresie temperatur. W oparciu o uzyskane wartości gęstości wyznaczono pozorne objętości molowe, cząstkowe objętości molowe oraz rozszerzalności izobaryczne. Dodatkowo zmierzono szybkości rozchodzenia się dźwięku w badanych roztworach w 298,15 K i wyznaczono pozorne ściśliwości molowe trifluorometanosulfonianów lantanu, gadolinu i lutetu w DMF i DMA. Dokonano analizy uzyskanych wielkości i omówione je w kontekście oddziaływań jon - rozpuszczalnik.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF CHEMICAL THERMODYNAMICS no. 58, pages 46 - 54,
ISSN: 0021-9614
Language:
English
Publication year:
2013
Bibliographic description:
Warmińska D., Fuchs A., Lundberg D.: Apparent molar volumes and compressibilities of lanthanum, gadolinium, lutetium and sodium trifluoromethanesulfonates in N,N-dimethylformamide and N,N-dimethylacetamide// JOURNAL OF CHEMICAL THERMODYNAMICS. -Vol. 58, (2013), s.46-54
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.jct.2012.11.004
Verified by:
Gdańsk University of Technology

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