Search
Characteristic of Morpholinium Ionic Liquids as Gas Chromatography Stationary Phases with McReynolds Constants and Activity Coefficients at Infinite Dilution
Abstract
In this work, four ionic liquids based on N-alkyl-N-methylmorpholinium cation ([Mor1,R] where R= 2, 4, 8, 10) and bis(trifluoromethanesulfonyl)imide anion [TFSI] were synthesized. Using gas-liquid chromatography a number of parameters describing the sorption properties of the investigated ionic liquids were determined. The values of Kovats indices, McReynolds constants, and activity coefficients at infinite dilution were the basis for the evaluation of intermolecular interactions. The effect of the chain length of the alkyl substituent in the cation, which was used for modification of their polarity has been discussed.
Authors (4)
Cite as
Full text
download paper
downloaded 49 times
- Publication version
- Accepted or Published Version
- License
- Copyright (Charles University in Prague, Faculty of Science, 2017.)
Keywords
Details
- Category:
- Conference activity
- Type:
- publikacja w wydawnictwie zbiorowym recenzowanym (także w materiałach konferencyjnych)
- Title of issue:
- Proceedings of the13th International Students Conference "Modern Analytical Chemistry" strony 75 - 81
- Language:
- English
- Publication year:
- 2017
- Bibliographic description:
- Yavir K., Marcinkowski Ł., Kloskowski A., Namieśnik J.: Characteristic of Morpholinium Ionic Liquids as Gas Chromatography Stationary Phases with McReynolds Constants and Activity Coefficients at Infinite Dilution// Proceedings of the13th International Students Conference "Modern Analytical Chemistry"/ ed. Karel Nesmerak Prague: , 2017, s.75-81
- Bibliography: test
-
show (23) hide
- R : Ferraz F. ., Branco L.C., Prudencio C., Noronha J.P., Petrovski Zƽ . ChemMedChem (2011), 6 975 985. -
- Tao G.H., He L., Sun N., Kou Y. (2005), 3562 3564. : - Chem. Commun. 28 open in new tab
- Seddon K. (2004) 19 22. : , - Chemical Technology-Bedfordview
- Plechkova N.V., Seddon K.R. (2008), 123 150. : - Chem. Soc. Rev. 37 open in new tab
- Pandey S. (2006), 38 45. : - Anal. Chim. Acta 556 open in new tab
- Watanabe M., Thomas M.L., Zhang S., Ueno K., Yasuda T., Dokko K.: (2017), Chem. Rev. 117 7190-7239. open in new tab
- Barber D.W., Phillips C.S G., Tusa G.F., Verdin A. (1959) 18 24. . : , - J. Chem. Soc. open in new tab
- Anderson J.L., Armstrong D.W. (2003), 4851 4858. : - Anal. Chem. 75 open in new tab
- Poole C.F., Poole S.K. (2011), 888 900. : - J. Sep. Sci. 34 open in new tab
- Poole C.F., Lence N. (2014), 87 109. : - J. Chromatogr. A 1357 open in new tab
- Armstrong D.W., He L., Liu Y. S. (1999), 3873 3876. : - Anal. Chem. 71 open in new tab
- Reichardt C. (2005), 339 351. : - Green Chem. 7 open in new tab
- Dzyuba S.V., Bartsch R.A. (2002), 4657 4659. : - Tetrahedron Lett. 43 open in new tab
- Muldoon M.J., Gordon C.M., Dunkin I.R. (2001), 433 435. : - J. Chem. Soc., Perkin Trans 2 . 4 open in new tab
- Carmichael A.J., Seddon K.R.: - J. Phys. Org. Chem. (2000), 591 595. 13 open in new tab
- Aki S.N., Brennecke J.F., Samanta A. (2001), 413 414. : - Chem. Commun. 5 open in new tab
- Abraham, M.H. - Chem. Soc. Rev. (1993), 73 83. 22 open in new tab
- Abraham M.H., Zissimos A.M., Huddleston J.G., Willauer H.D., Rogers R.D., Acree W.E.: Ind. Eng. Chem. Res. (2003), 413 418. 42 - open in new tab
- Abraham M.H., Acree W.E. (2006), 906 915. : - Green Chem. 8 open in new tab
- Marcinkowski , Olszewska T., Kloskowski A., Warmińska D. (2014), : Ł. J. Chem. Eng. Data 59 718-725. open in new tab
- Marcinkowski , Kloskowski A., Namiesńik J.: Ł. (2014), 84-90.
- J. Chem. Thermodyn. 71 open in new tab
- Supelco© materials https://www.sigmaaldrich.com/content/dam/sigma-aldrich/docs/Su- pelco/Posters/1/ionic_liquid_gc_columns.pdf (accessed 2012) open in new tab
- Verified by:
- Gdańsk University of Technology
seen 147 times