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Abstract
New diazo macrocycles linked by hydrocarbon chain bearing imidazole or 4-methylimidazole residue have been synthetized with satisfactory yield (24–55%). The structure of macrocycles was confirmed by X-ray analysis and spectroscopic methods (1H NMR, MS, FTIR). Metal cation complexation studies were carried out in acetonitrile and acetonitrile-water system. It was found that azomacrocyles form triple-decker complexes with lead(II). The highest values of stability constant were found for lead(II) complexes of 21-membered derivatives. For the first time azomacrocycles bearing imidazole residue were immobilized on a porous glass. Obtained materials can act as lead(II) or copper(II) colorimetric optical sensors with color digital analysis as detection using simple portable devices.
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.dyepig.2023.111610
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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DYES AND PIGMENTS
no. 219,
ISSN: 0143-7208 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Galiński B., Chojnacki J., Szwarc-Karabyka K., Małkowski A., Sopel D., Zwolińska A., Wagner-Wysiecka E.: Chromogenic azomacrocycles with imidazole residue: Structure vs. properties// DYES AND PIGMENTS -Vol. 219, (2023), s.111610-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.dyepig.2023.111610
- Sources of funding:
-
- COST_FREE
- Verified by:
- Gdańsk University of Technology
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