Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase - Publication - Bridge of Knowledge

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Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase

Abstract

Przeprowadzono syntezę trzech kompleksów: [Co{SSi(OBut)3}2(NH3)(L-pic)],[Co{SSi(OBut)3}2(NH3)2]xMeCN i [Co{SSi(OBut)3}3(H2O)][NHEt3]. Kompleksy są monomeryczne, dla nich wyznaczono strukturę krystalograficzną. Kompleks [Co{SSi(OBut)3(NH3)(L-pic)] o rdzeniu CoN2OS2 posiada dwa różne ligandy azotowe, zaś [Co{SSi(OBut)3(L-pic)] stanowi substrat do syntezy związku modelującego centrum katalityczne LADH.

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Category:
Articles
Type:
artykuł w czasopiśmie z listy filadelfijskiej
Published in:
APPLIED ORGANOMETALLIC CHEMISTRY no. 16, pages 517 - 524,
ISSN: 0268-2605
Language:
English
Publication year:
2002
Bibliographic description:
Becker B., Pladzyk A., Konitz A., Wojnowski W.: Cobalt(II) tri-tert-butoxysilanethiolates: in search of models for catalytic metal site of liver alcohol dehydrogenase// APPLIED ORGANOMETALLIC CHEMISTRY. -Vol. 16., (2002), s.517-524
DOI:
Digital Object Identifier (open in new tab) 10.1002/aoc.332
Verified by:
Gdańsk University of Technology

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