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Collision-induced luminescence spectra of pyridine bombarded by 1000 eV He+ cations

Abstract

Here we show collision-induced luminescence spectra measured for collisions of the He+cations with thearomatic six-membered ring of the pyridine molecule (C5H5N). Distinct emission bands due to the CH(A2Δ→X2Πr;B2Σ+→X2Πr;C2Σ+→X2Πr), CN(B2Σ+→X2Σ+), C2(d3Πg→a3Πu), and NH(A3Π→X3Σ−) transitions, aswell as atomic H, He, and C lines have been observed. Apart from the He atoms, all the emitters arise from thefragmentation of the pyridine ring. The identification of the helium lines indicates a single electron transferreaction from the pyridine molecule to the He+cations. The products’intensities relative to the Hβintensityhave also been obtained and compared with the intensity ratios determined for He++ furan collisions.

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Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
Results in Physics no. 18,
ISSN: 2211-3797
Language:
English
Publication year:
2020
Bibliographic description:
Wąsowicz T.: Collision-induced luminescence spectra of pyridine bombarded by 1000 eV He+ cations// Results in Physics -Vol. 18, (2020), s.103244-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.rinp.2020.103244
Sources of funding:
  • Statutory activity/subsidy
Verified by:
Gdańsk University of Technology

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