Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples - Publication - Bridge of Knowledge

Your account

login

Search

Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples

Abstract

Developed and validated analytical methods for the determination of a wide spectrum of pesticide residues in honey and honeybee samples after the modification of QuEChERS extraction in combination with gas chromatography–tandem quadrupole mass spectrometry (GC-MS/MS) and liquid chromatography–tandem quadrupole mass spectrometry (LC-MS/MS) were discussed and compared. The developed methods were evaluated regarding the utilized equipment and reagents using Eco-Scale and compared in terms of extraction time, accuracy, precision, sensitivity and versatility, with similar procedures. The results proved that the QuEChERS protocol in combination with LC and GC techniques fulfills the requirements of green analytical chemistry, so it can be used as a tool in environmental monitoring. The recovery was 85–116% for honey and 85.5–103.5% for honeybee samples. The developed methods were successfully applied in monitoring real samples collected from three districts of Pomerania in Poland. Analysis of real samples revealed the presence of the following pesticides: bifenthrin, fenpyroximate, methidathione, spinosad, thiamethoxam, triazophos, metconazole and cypermethrin at levels higher than the MRLs established by the EU.

Citations

  • 1 7

    CrossRef

  • 0

    Web of Science

  • 1 9

    Scopus

Authors (3)

Cite as

Full text

download paper
downloaded 174 times
Publication version
Accepted or Published Version
License
Creative Commons: CC-BY open in new tab

Keywords

Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
MOLECULES no. 23, edition 10, pages 2582 - 2595,
ISSN: 1420-3049
Language:
English
Publication year:
2018
Bibliographic description:
Bargańska Ż., Konieczka P., Namieśnik J.: Comparison of Two Methods for the Determination of Selected Pesticides in Honey and Honeybee Samples// MOLECULES. -Vol. 23, iss. 10 (2018), s.2582-2595
DOI:
Digital Object Identifier (open in new tab) 10.3390/molecules23102582
Verified by:
Gdańsk University of Technology

seen 215 times

Recommended for you

Development of gas chromatography - tandem mass spectrometry procedure for development of pesticide residues in honey and honeybee samples

2015

Determination of Pesticide Residues in Honey using the GC×GC-TOFMS Technique

2014

Pesticide residues levels in honey from apiaries located of Northern Poland

2013

Determination of Pesticide Residues in Honeybees using Modified QUEChERS Sample Work-Up and Liquid Chromatography-Tandem Mass Spectrometry

2014
Meta Tags