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Copper-based 2D-coordination polymer as catalyst for allylation of aldehydes

Abstract

A copper-tartrate, [Cu2(Tart)2(H2O)2]·4H2O, was synthesized at room temperature in aqueous media using copper chloride and D-tartaric acid. The compound crystallizes in the monoclinic system P21 space group and was characterized by infrared spectroscopy, thermogravimetry, X-ray powder diffraction and the results are in good agreement with the single crystal structure. Catalytic properties for allylation of aldehydes were investigated at different solvents, and the best conditions obtained were using a mixture of CH2Cl2:H2O. The copper-tartrate obtained showed good performance as catalyst for different substrates and yields were between 62% and 95%

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Authors (7)

  • Photo of Dr Gilson Da_silva

    Gilson Da_silva Dr

    • Universidade Federal de Pernambuco, Recife, Brazil Departamento de Química Fundamental
  • Photo of Paulo Menezes

    Paulo Menezes

    • Universidade Federal de Pernambuco, Recife, Brazil Departamento de Química Fundamental
  • Photo of Ivani Malvestiti

    Ivani Malvestiti

    • Universidade Federal de Pernambuco, Recife, Brazil Departamento de Química Fundamental
  • Photo of Eduardo H. L. Falcão

    Eduardo H. L. Falcão

    • Universidade Federal de Pernambuco, Recife, Brazil Departamento de Química Fundamental
  • Photo of Severino Alves Junior

    Severino Alves Junior

    • Universidade Federal de Pernambuco, Recife, Brazil Departamento de Química Fundamental
  • Photo of prof. dr hab. inż. Jarosław Chojnacki

    Jarosław Chojnacki prof. dr hab. inż.

  • Photo of Fausthon F. da Silva

    Fausthon F. da Silva

    • Universidade Federal da Paraíba, Jo~ao Pessoa, Brazil Departamento de Química

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Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
JOURNAL OF MOLECULAR STRUCTURE no. 1155, pages 530 - 535,
ISSN: 0022-2860
Language:
English
Publication year:
2018
Bibliographic description:
Da_silva G., Menezes P., Malvestiti I., Falcão E., Junior S., Chojnacki J., Da Silva F.: Copper-based 2D-coordination polymer as catalyst for allylation of aldehydes// JOURNAL OF MOLECULAR STRUCTURE. -Vol. 1155, (2018), s.530-535
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.molstruc.2017.10.096
Verified by:
Gdańsk University of Technology

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