Corrosivity of environment and the current state of the steel elements at the former Auschwitz concentration camp
Abstract
The objective of this study was to assess corrosivity of the atmospheric environment in the former Auschwitz I and Auschwitz II-Birkenau concentration and extermination camp, and to identify the protective properties of existing corrosion products in order to estimate the actual corrosion rate of original steel elements located there. The current atmospheric corrosivity of the former Auschwitz camp, specified during one year of exposure of steel samples according to the EN ISO 12944-2 (1998) standard, was determined and it can be described as a boundary between the low C2 and medium C3. The steel corrosion rate in these conditions was in the range of 14–34 μm/year with the average rate of 27 μm/year. A layer of corrosion products formed on uncovered original reinforcement steel rods during ca. 70 years of atmospheric exposure was examined in terms of their protective properties with respect to steel. The microstructure, chemical composition, and elemental chemical state were analyzed by means of scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and X-ray diffraction. Potentiodynamic polarization and electrochemical impedance spectroscopy methods were employed to investigate the corrosion resistance of the carbon steel covered with a layer of corrosion products. It has been estimated that this layer slows down the corrosion rate of steel by about five times. Hence, it can be concluded that the corrosion rate of the original steel parts under the layer of corrosion products should not exceed 7 μm/year.
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
STUDIES IN CONSERVATION
no. 62,
pages 456 - 464,
ISSN: 0039-3630 - Language:
- English
- Publication year:
- 2017
- Bibliographic description:
- Miszczyk A., Szociński M., Darowicki K.: Corrosivity of environment and the current state of the steel elements at the former Auschwitz concentration camp// STUDIES IN CONSERVATION. -Vol. 62, nr. 8 (2017), s.456-464
- DOI:
- Digital Object Identifier (open in new tab) 10.1080/00393630.2016.1224149
- Bibliography: test
-
- Agbota, H., Young, C. & Strlic, M. 2013. Pollution Monitoring at Heritage Sites in Developing and Emerging Economies. Studies in Conservation, 58: 129-44. open in new tab
- Auschwitz Report. 2014. News dated 05-08-2015 [accessed 10 August 2016]. Available at: <http://auschwitz.org/en/museum/news/> Charlesworth, A. & Addis, M. 2002. Memorialization and the Ecological Landscapes of Holocaust Sites: The Cases of Płaszow and Auschwitz-Birkenau. Landscape Research, 27: 229-51.
- Chico, B., De la Fuente, D., Vega, J.M. & Morcillo, M. 2010. Corrosivity Maps of Spain for Zinc in Rural Atmospheres. Revista Metalurgia, 46: 485-92. open in new tab
- Crevello, G., Hudson, N. & Noyce, P. 2015. Corrosion Condition Evaluations of Historic Concrete Icons. Case Studies in Construction Materials, 2: 2-10. open in new tab
- De la Fuente, D., Díaz, I., Simancas, J., Chico, B. & Morcillo, M. 2011. Long-term Atmospheric Corrosion of Mild Steel. Corrosion Science, 53: 604-17. open in new tab
- De la Fuente, D., Vega, J.M., Viejo, F., Diaz, I. & Morcillo, M. 2013. Mapping Air Pollution Effects on Atmospheric Degradation of Cultural Heritage. Journal of Cultural Heritage, 14: 138-45. open in new tab
- European standard, EN ISO 12944-2. 1998. Paints and Varnishes - Corrosion Protection of Steel Structures by Protective Paint Systems -Part 2: Classification of Environments. Brussels: European Committee for Standardization. open in new tab
- Fereira, C.A.M., Ponciano, J.A.C., Vaitsman, D.S. & Perez, D.V. 2007. Evaluation of the Corrosivity of the soil through its chemical composition. Science of the Total Environment, 388: 250-55. open in new tab
- Gotkowski, P. & Jachym, R. 2014. Unpublished Report No. ZB/10/ 2014. Gliwice, Poland: Welding Institute (report available at the Auschwitz-Birkenau State Museum, Oswiecim, Poland).
- Hiller, J.-E. 1966. Phasenumwandlungen im Rost. Werkstoffe und Korrosion, 17: 943-95. open in new tab
- Karaca, F. 2013. Mapping the Corrosion Impact of Air pollution on the Historical Peninsula of Istanbul. Journal of Cultural Heritage, 14: 129-37. open in new tab
- Karman, F.H., Felhosi, I., Kalman, E., Cserny, I. & Kover, L. 1998. The Role of Oxide Layer Formation during Corrosion Inhibition of Mild Steel in Neutral Aqueous Media. Electrochimica Acta, 43: 69-75.
- Kibblewhite, M., Gergely, T. & Hermann, T. 2015. Predicting the Preservation of Cultural Artefacts and Buried Materials in Soil. Science of the Total Environment, 529: 249-63. open in new tab
- Kumar, P. & Imam, B. 2013. Footprints of Air Pollution and Changing Environment on the Sustainability of Built Infrastructure. Science of the Total Environment, 444: 85-101. open in new tab
- Lvovich, F. 2012. Impedance Spectroscopy. Applications to Electrochemical and Dielectric Phenomena. Hoboken, NJ: Wiley. open in new tab
- Miszczyk, A. & Darowicki, K. 2014. Multivariate Analysis of Impedance Data Obtained for Coating Systems of Varying Thickness Applied on Steel. Progress in Organic Coatings, 77: 2000-06. open in new tab
- Miszczyk, A., Szocinski, M. & Darowicki, K. 2007. Interlayer Defect Evolution in an Organic Coating System on Steel under Hydromechanical Loading. Journal of Applied Electrochemistry, 37: 353-58. open in new tab
- Natesan, M. & Palaniswamy, N. 2009. Atmospheric Corrosivity and Durability Maps of India. Corrosion Reviews, 27 (Supplement): 61-112. open in new tab
- Nowicka-Krawczyk, P., Zelazna-Wieczorek, J., Otlewska, A., Kozirog, A., Rajkowska, K., Piotrowska, M., Gutarowska, B. & Zydzik-Bialek, A. 2014. Diversity of an Aerial Phototrophic Coating of Historic Buildings in the Former Auschwitz II-Birkenau Concentration Camp. Science of the Total Environment, 493: 116-23. open in new tab
- Pascoal, P., Borsoi, G., Veiga, R., Faria, P. & Silva, A.S. 2015. Consolidation and Chromatic Reintegration of Historical Renders with Lime-based Pozzolanic Products. Studies in Conservation, 60: 321-32. open in new tab
- Rajkowska, K., Otlewska, A., Koziróg, A., Piotrowska, M., Nowicka-Krawczyk, P., Hachulka, M., Wolski, G.J., Kunicka-Styczynska, A., Gutarowska, B. & Zydzik-Bialek, A. 2014. Assessment of Biological Colonization of Historic Buildings in the Former Auschwitz II-Birkenau Concentration Camp. Annals of Microbiology, 64: 799-808. open in new tab
- Rincon, A., De Rincon, A.I., Fernandez, M. & Loaiza, E. 2000. Measurement of Pollution Atmospheres in a Tropical Region and its Atmospheric Corrosivity Maps. Corrosion Reviews, 18: 473-87. open in new tab
- Scott, D.A. 2015. Conservation and Authenticity: Interaction and Enquiries. Studies in Conservation, 60: 291-305. open in new tab
- Singh, D.D.N., Yadav, S. & Saha, J.K. 2008. Role of Climatic Conditions on Corrosion Characteristics of Structural Steels. Corrosion Science, 50: 93-110. open in new tab
- Surnam, B.Y.R. 2015. Three Years Outdoor Exposure of Low Carbon Steel in Mauritius. Anti-Corrosion Methods and Materials, 62: 246-52. open in new tab
- Taylor, J. 2015. Embodiment Unbound: Moving Beyond Divisions in the Understanding and Practice of Heritage Conservation. Studies in Conservation, 60: 65-77. open in new tab
- Vera, R., Puentes, M., Araya, R., Rojas, P. & Carvajal, A. 2011. Atmospheric Corrosion Map of Chile: Results after One Year of Exposure. Revista Construction, 11: 61-72. open in new tab
- Weissberg, L. 1999. Memory Confined. In: D. Ben-Amos & L. Weissberg, eds. Cultural Memory and the Construction of Identity. Detroit: Wayne State University Press, pp. 45-76. open in new tab
- Verified by:
- Gdańsk University of Technology
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