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Development of an asymmetric cellulose acetate-ionic liquid P6,6,6,14[PHOS] gel membrane for the perstraction of succinic acid from a model fermentation solution of yarrovia lipolytica
Abstract
This study introduces a novel approach to separate succinic acid (SA) from fermentation mixtures using an asymmetric membrane based on the gelation of the ionic liquid [P6,6,6,14][PHOS] coated with two layers of cellulose acetate. The membrane was designed to explore the synergistic effect of polymer-ionic liquid interfaces according to the solution-diffusion theory. The gelation of the ionic liquid was achieved using 12-hydroxystearic acid at a concentration of 1.5%, allowing the use of ionic liquid gels as new materials for the generation of membranes. The perstraction performance of the membrane was evaluated over 5 h at two different temperatures (25°C and 37°C), with an initial feed solution concentration of 50 kg m−3 for SA and glycerol and pure water as a receiving phase., Several flow rates and phase-volume ratios were studied anda mass transfer model based on the resistance-in-series theory was assessed to understand the behavior of each mass transfer stage considering the distribution in each interphase. Interestingly, optimal perstraction results were obtained at 37°C, with an average transmembrane flux of 0.22 kg m-2h−1 for SA, an extraction percentage of 43.1% for SA and 0.7% for glycerol, and a SA/glycerol selectivity of 54.98. Besides presenting a novel composite membrane, this study reports pioneering perstraction outcomes, highlighting its potential as an innovative SA separation strategy and structured new materials for selective extractions.
Citations
Authors (6)
-
Elsie Zurob
-
Esteban Quijada-Maldonado
-
Julio Romero
-
Andrea Plaza
-
René Cabezas
Cite as
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
SEPARATION AND PURIFICATION TECHNOLOGY
no. 354,
ISSN: 1383-5866 - Language:
- English
- Publication year:
- 2025
- Bibliographic description:
- Zurob E., Quijada-Maldonado E., Castro Munoz R., Romero J., Plaza A., Cabezas R.: Development of an asymmetric cellulose acetate-ionic liquid P6,6,6,14[PHOS] gel membrane for the perstraction of succinic acid from a model fermentation solution of yarrovia lipolytica// SEPARATION AND PURIFICATION TECHNOLOGY -,iss. 354 (2025), s.129199-
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.seppur.2024.129199
- Sources of funding:
-
- COST_FREE
- Verified by:
- Gdańsk University of Technology
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