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Abstract
The monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula R2P-C(=O)-O-B(NR2)2 in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.
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- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
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RSC Advances
no. 9,
pages 27749 - 27753,
ISSN: 2046-2069 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Szynkiewicz N., Ordyszewska A., Chojnacki J., Grubba R.: Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2// RSC Advances -Vol. 9,iss. 48 (2019), s.27749-27753
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/c9ra06638a
- Sources of funding:
- Verified by:
- Gdańsk University of Technology
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