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Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2

Abstract

The monomeric diaminophosphinoboranes readily react with CO2 under mild conditions to cleanly form products of the general formula R2P-C(=O)-O-B(NR2)2 in the absence of a catalyst. The isolated products from the CO2-phosphinoboration were fully characterized by NMR spectroscopy, IR spectroscopy, and X-ray diffraction. The mechanism of CO2 phosphinoboration with diaminophosphinoboranes was elucidated by DFT calculations.

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Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
RSC Advances no. 9, pages 27749 - 27753,
ISSN: 2046-2069
Language:
English
Publication year:
2019
Bibliographic description:
Szynkiewicz N., Ordyszewska A., Chojnacki J., Grubba R.: Diaminophosphinoboranes: effective reagents for phosphinoboration of CO2// RSC Advances -Vol. 9,iss. 48 (2019), s.27749-27753
DOI:
Digital Object Identifier (open in new tab) 10.1039/c9ra06638a
Bibliography: test
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Verified by:
Gdańsk University of Technology

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