Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid - Publication - Bridge of Knowledge

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Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid

Abstract

The first example of CO2 diphosphination is described. Reactions of unsymmetrical diphosphanes with CE2 (E = O, S) catalyzed by BPh3 insert a CE2 molecule into the P-P bond with formation of the products of the general formula R2P-E-C(=E)-PR2. The obtained CO2 adducts arise from synergistic interaction of diphosphane and borane with CO2 molecule.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
CHEMICAL COMMUNICATIONS no. 55, pages 2928 - 2931,
ISSN: 1359-7345
Language:
English
Publication year:
2019
Bibliographic description:
Szynkiewicz N., Ponikiewski Ł., Grubba R.: Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid// CHEMICAL COMMUNICATIONS. -Vol. 55, iss. 20 (2019), s.2928-2931
DOI:
Digital Object Identifier (open in new tab) 10.1039/c9cc00621d
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Gdańsk University of Technology

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