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Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid
Abstract
The first example of CO2 diphosphination is described. Reactions of unsymmetrical diphosphanes with CE2 (E = O, S) catalyzed by BPh3 insert a CE2 molecule into the P-P bond with formation of the products of the general formula R2P-E-C(=E)-PR2. The obtained CO2 adducts arise from synergistic interaction of diphosphane and borane with CO2 molecule.
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- Copyright (The Royal Society of Chemistry 2019)
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
CHEMICAL COMMUNICATIONS
no. 55,
pages 2928 - 2931,
ISSN: 1359-7345 - Language:
- English
- Publication year:
- 2019
- Bibliographic description:
- Szynkiewicz N., Ponikiewski Ł., Grubba R.: Diphosphination of CO2 and CS2 mediated by frustrated Lewis pairs - catalytic route to phosphanyl derivatives of formic and dithioformic acid// CHEMICAL COMMUNICATIONS. -Vol. 55, iss. 20 (2019), s.2928-2931
- DOI:
- Digital Object Identifier (open in new tab) 10.1039/c9cc00621d
- Sources of funding:
- Verified by:
- Gdańsk University of Technology
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