Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects

Justyna Ignaczak; Lunjie Zeng; Dario Ferreira Sanchez; Małgorzata Makowska; Karolina Górnicka; Krystian Lankauf; Jakub Karczewski; Piotr Jasiński; Sebastian Molin

doi:10.1016/j.ijhydene.2023.06.041

Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects

Abstract

The current state of the art steel interconnect coating materials are based on critical raw material - Co-oxide spinels. Replacing Co-oxide spinels with alternative, abundant materials can reduce the dependence on the critical raw materials. Cobalt-free coatings with the general formula Mn2-xCuFexO4, where x = 0, 0.1, 0.3, were electrophoretically deposited on a ferritic stainless-steel support and evaluated. Prior to deposition, the powders were prepared by a soft chemistry process and studied in terms of crystallographic phase analysis, electrical conductivity, thermal expansion, and sinterability behaviour. Coated steel samples were oxidised in an air atmosphere at 750 °C for 3000 h. In parallel, a state-of-the-art MnCo2O4 spinel oxide was tested as a reference. The coatings and oxide scale microstructures of the surfaces and cross-sections were examined by XRD, and SEM-EDX. TEM-EDX, XRF, and micro-XRD were also performed on the cross-section lamellae. The electrical properties of the steel-coating system were evaluated by Area Specific Resistance measurement. The results confirm that Mn–Cu–Fe oxides exhibit higher conductivity and lower TEC than Mn–Co oxide. Based on the obtained results, it might be concluded that the proposed coatings are a promising alternative to coatings that contain cobalt.

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Authors (9)

Justyna Ignaczak mgr inż.
Lunjie Zeng
- Chalmers University of Technology
Dario Ferreira Sanchez Dr.
- Paul Scherrer Institute
Małgorzata Makowska Dr.
- Paul Scherrer Institute
Karolina Górnicka dr inż.
Krystian Lankauf
Jakub Karczewski dr hab. inż.
Piotr Jasiński prof. dr hab. inż.
Sebastian Molin dr hab. inż.

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Articles

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artykuły w czasopismach

Published in:

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY no. 48, pages 36076 - 36093,
ISSN: 0360-3199

Language:

English

Publication year:

2023

Bibliographic description:

Ignaczak J., Zeng L., Sanchez D. F., Makowska M., Górnicka K., Lankauf K., Karczewski J., Jasiński P., Molin S.: Fe-modified Mn2CuO4 spinel oxides: coatings based on abundant elements for solid oxide cell interconnects// INTERNATIONAL JOURNAL OF HYDROGEN ENERGY -Vol. 48,iss. 92 (2023), s.36076-36093

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