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Featuring Semitransparent p–i–n Perovskite Solar Cells for High-Efficiency Four-Terminal/Silicon Tandem Solar Cells

Abstract

Two issues need to be resolved when fabricating p–i–n semitransparent perovskite solar cells (ST-PVSCs) for four-terminal (4 T) perovskite/silicon tandem solar cells: 1) damage to the underlying absorber (MAPbI3), electron transporting layer ([6,6]-phenyl-C61-butyric acid methyl ester, PCBM), and work function (WF) modifier (polyethylenimine, PEI), resulting from the harsh sputtering conditions for the transparent electrodes (TEs) and 2) low average near-infrared transmittance (ANT) of TEs. Herein, a unique SnO2 layer to protect the MAPbI3 and PCBM layers is developed and functions as a WF modifier for a new TE (cerium-doped indium oxide, ICO), which exhibits an excellent ANT of 86.7% in the range of 800−1200 nm. Moreover, a MAPbI3-based p–i–n ST-PVSC is prepared, achieving an excellent power conversion efficiency (PCE) of 17.23%. When it is placed over the Si solar cell, a 4 T tandem solar cell with a PCE of 26.14% is obtained.

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DOI:
Digital Object Identifier (open in new tab) 10.1002/solr.202100891
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Copyright (2022 John Wiley & Sons, Inc)

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
Solar RRL no. 6,
ISSN: 2367-198X
Language:
English
Publication year:
2022
Bibliographic description:
Lee P., Wu T., Li C., Głowienka D., Huang Y., Huang S., Huang Y., Su W.: Featuring Semitransparent p–i–n Perovskite Solar Cells for High-Efficiency Four-Terminal/Silicon Tandem Solar Cells// Solar RRL -Vol. 6,iss. 4 (2022),
DOI:
Digital Object Identifier (open in new tab) 10.1002/solr.202100891
Verified by:
Gdańsk University of Technology

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