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Functional phase bistability in a nanocrystalline RbMn[Fe(CN)6] thin film fabricated by matrix-assisted laser evaporation
Abstract
One of the main barriers hindering applications of Prussian blue metal assemblies is their poor processability, which makes the fabrication of intact thin films very difficult. In this work, a nanocrystalline RbMn[Fe(CN)6]·xH2O film on silicon substrate was obtained for the first time via laser-stimulated deposition and investigated. Temperature-induced phase transition and bistability within broad hysteresis loop (120 K), along with transition temperatures up to 317 K, which is the highest in the RbMnFe series, were observed using variable-temperature Raman spectroscopy. This study thus proposes a reliable deposition approach for preparing a functional magnetic materials that operate at room temperature.
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Authors (8)
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Dominik Maskowicz mgr inż.
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Mirosław Sawczak dr hab. inż.
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Rafał Jendrzejewski
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Hiroko Tokoro
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Shin-ichi Ohkoshi
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Yann Garcia
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Gerard Śliwiński prof.
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
SCRIPTA MATERIALIA
no. 183,
pages 50 - 54,
ISSN: 1359-6462 - Language:
- English
- Publication year:
- 2020
- Bibliographic description:
- Maskowicz D., Sawczak M., Jendrzejewski R., Gazda M., Tokoro H., Ohkoshi S., Garcia Y., Śliwiński G.: Functional phase bistability in a nanocrystalline RbMn[Fe(CN)6] thin film fabricated by matrix-assisted laser evaporation// SCRIPTA MATERIALIA -Vol. 183, (2020), s.50-54
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.scriptamat.2020.03.019
- Sources of funding:
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- FNRS-PAN/CDR 33694457 and WBI-MNiSW/CDR 33694457 DM acknowledges support from project 2018/31/N/ST8/01797- NCN/Poland, and HT and S-IO via grants 15H05697 and KAKENHI 16H06521 of JSPS.
- Verified by:
- Gdańsk University of Technology
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