Search
Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites
Abstract
The effect of several concentrations of carboxylated nitrile butadiene rubber (XNBR) functionalized halloysite nanotubes (XHNTs) on the vulcanization and degradation kinetics of XNBR/epoxy compounds were evaluated using experimental and theoretical methods. The isothermal vulcanization kinetics were studied at various temperatures by rheometry and differential scanning calorimetry (DSC). The results obtained indicated that the nth order model could not accurately predict the curing performance. However, the autocatalytic approach can be used to estimate the vulcanization reaction mechanism of XNBR/epoxy/XHNTs nanocomposites. The kinetic parameters related to the degradation of XNBR/epoxy/XHNTs nanocomposites were also assessed using thermogravimetric analysis (TGA). TGA measurements suggested that the grafted nanotubes strongly enhanced the thermal stability of the nanocomposite.
Citations
-
1 2
CrossRef
-
0
Web of Science
-
1 2
Scopus
Authors (8)
-
Seyed Paran
- Department of Polymer Processing, Iran Polymer and Petrochemical Institute, Tehran P.O. Box 14965/115, Iran
-
Ghasem Naderi
- Department of Polymer Processing, Iran Polymer and Petrochemical Institute, Tehran P.O. Box 14965/115, Iran
-
Elnaz Movahedifar
- Department of Polymer Processing, Iran Polymer and Petrochemical Institute, Tehran P.O. Box 14965/115, Iran
-
Maryam Jouyandeh
- Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran P.O. Code 14176/14411, Iran
-
Xavier Colom
- Department of Chemical Engineering, Universitat Politècnica de Catalunya Barcelona Tech., Terrassa, 08222 Barcelona, Spain
-
Javier Cañavate
- Department of Chemical Engineering, Universitat Politècnica de Catalunya Barcelona Tech., Terrassa, 08222 Barcelona, Spain
-
Mohammad Saeb
- Center of Excellence in Electrochemistry, School of Chemistry, College of Science, University of Tehran, Tehran P.O. Code 14176/14411, Iran
Cite as
Full text
- Publication version
- Accepted or Published Version
- License
-
open in new tab
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
Materials
no. 14,
ISSN: 1996-1944 - Language:
- English
- Publication year:
- 2021
- Bibliographic description:
- Paran S., Naderi G., Movahedifar E., Jouyandeh M., Formela K., Colom X., Cañavate J., Saeb M.: Isothermal Vulcanization and Non-Isothermal Degradation Kinetics of XNBR/Epoxy/XNBR-g-Halloysite Nanotubes (HNT) Nanocomposites// Materials -Vol. 14,iss. 11 (2021), s.2872-
- DOI:
- Digital Object Identifier (open in new tab) 10.3390/ma14112872
- Verified by:
- Gdańsk University of Technology
seen 119 times
Recommended for you
Microstructure and Mechanical Properties of Carboxylated Nitrile Butadiene Rubber/Epoxy/XNBR-grafted Halloysite Nanotubes Nanocomposites
- S. Paran,
- G. Naderi,
- H. Mosallanezhad
- + 3 authors
Effect of Surface Treatment of Halloysite Nanotubes (HNTs) on the Kinetics of Epoxy Resin Cure with Amines
- V. Akbari,
- M. Jouyandeh,
- S. Paran
- + 9 authors
Epoxy/Ionic Liquid-Modified Mica Nanocomposites: Network Formation–Network Degradation Correlation
- M. Jouyandeh,
- V. Akbari,
- S. M. R. Paran
- + 4 authors
In-Out Surface Modification of Halloysite Nanotubes (HNTs) for Excellent Cure of Epoxy: Chemistry and Kinetics Modeling
- S. Moghari,
- S. H. Jafari,
- M. K. Yazdi
- + 4 authors