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Lanthanide-organic-frameworks modified ZnIn2S4 for boosting hydrogen generation under UV–Vis and visible light
Abstract
Novel Ln-MOF with microrods shape were successfully combined with ZnIn2S4 (ZIS) microsphere and used for photocatalytic hydrogen generation under UV–Vis and visible light. The Ln-MOFs/ZIS system comprises lanthanide-carboxylate coordination networks (Tm and Gd as metal ions, and 1,3,5-benzenetricarboxylic acid (BTC) as the organic linker) deposited on ZnIn2S4 microspheres. Effect of the amount of ((Tm,Gd)-BTC) (1, 5, 10 wt%) on the optical properties and photocatalytic hydrogen evolution performance was investigated. ZIS microsphere shows the marigold flower-like morphology and hexagonal polytopic crystal form. Our results proved that the combination of ZIS microsphere, Ln-MOF and Pt nanoparticles (NPs) caused significant enhancement in hydrogen generation. Amount of formed hydrogen was raised from 196.3 to 7782.1 μmol g−1 for pristine ZIS and ZIS decorated with 1% (Tm, Gd)-BTC/Pt under UV–Vis light, respectively.
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Authors (8)
-
Jakub Sowik
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Tomasz Grzyb
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Grzegorz Trykowski doktor
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Kostiantyn Nikiforow
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Onur Cavdar
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Adriana Zaleska-Medynska Prof. dr hab. inż.
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Anna Malankowska
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Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
no. 47,
pages 16065 - 16079,
ISSN: 0360-3199 - Language:
- English
- Publication year:
- 2022
- Bibliographic description:
- Sowik J., Grzyb T., Trykowski G., Klimczuk T., Nikiforow K., Cavdar O., Zaleska-Medynska A., Malankowska A.: Lanthanide-organic-frameworks modified ZnIn2S4 for boosting hydrogen generation under UV–Vis and visible light// INTERNATIONAL JOURNAL OF HYDROGEN ENERGY -Vol. 47,iss. 36 (2022), s.16065-16079
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.ijhydene.2022.03.111
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
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