Limiting Partial Molar Volumes of Tetra-n-Alkylammonium Perchlorates in N,N-dimethylacetamide, Triethylphosphate and Dimethyl Sulfoxide at 298.15 K - Publication - Bridge of Knowledge

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Limiting Partial Molar Volumes of Tetra-n-Alkylammonium Perchlorates in N,N-dimethylacetamide, Triethylphosphate and Dimethyl Sulfoxide at 298.15 K

Abstract

The densities of tetraalkylammonium perchlorates R4NClO4(R  =  methyl, or ethyl, or propyl, or butyl) and ammonium perchlorate solutions in N, N - dimethylacetamide, dimethyl sulfoxide, and triethylphosphate have been measured over the whole composition range atT =  298.15 K. From these densities, apparent and limiting partial molar volumes of the electrolytes and ions have been evaluated and used to obtain the partial molar volume for theClO4 −  anion.

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Details

Category:
Magazine publication
Type:
Magazine publication
Published in:
JOURNAL OF CHEMICAL THERMODYNAMICS no. 33,
ISSN: 0021-9614
Publication year:
2001
DOI:
Digital Object Identifier (open in new tab) 10.1006/jcht.2000.0725
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