Micellar Route of the Synthesis of Alkyl Xylosides: An Unexpected Effect of Amphiphilic Imidazolium Ionic Liquids

Janusz Nowicki; Julia Woch; Justyna Łuczak; Magdalena Zarębska; Ewa Nowakowska-bogdan; Małgorzata Mościpan

doi:10.1002/slct.201800125

Micellar Route of the Synthesis of Alkyl Xylosides: An Unexpected Effect of Amphiphilic Imidazolium Ionic Liquids

Abstract

This manuscript presents results from the investigation on the synthesis of alkyl xylosides by the novel, very efficient and promising protocol of the Fischer synthesis from unprotected xylose and aliphatic alcohol. The use of 1-alkyl-3-methylimidazolium hydrogen sulfate ionic liquids as the catalysts with dual functionality (surfactant + acid catalyst) and micellar reaction system are the main novelty of described method. It has been found that in developed method of the synthesis of alkyl xylosides the reaction of unprotected xylose with aliphatic alcohols carried out in mild reaction conditions and leads to alkyl xylosides with high yields. In progress analyses by Dynamic Light Scattering (DLS), High Performance Liquid Chromatography (HPLC) and Gas Chromatography (GC/MS) confirm the general postulated pathway of developed method.

Citations

9

CrossRef
0

Web of Science
1 2

Scopus

Authors (6)

Janusz Nowicki
- Instytut Ciężkiej Syntezy Organicznej "Blachownia"
Julia Woch
- Instytut Ciężkiej Syntezy Organicznej "Blachownia"
Justyna Łuczak dr hab. inż.
Magdalena Zarębska
- Instytut Ciężkiej Syntezy Organicznej "Blachownia"
Ewa Nowakowska-bogdan
- Instytut Ciężkiej Syntezy Organicznej "Blachownia"
Małgorzata Mościpan
- Instytut Ciężkiej Syntezy Organicznej "Blachownia"

Cite as

Full text

full text is not available in portal

full content of the article see on external site open in new tab

Keywords

Details

Category:: Articles
Type:: publikacja w in. zagranicznym czasopiśmie naukowym (tylko język obcy)
Published in:: ChemistrySelect no. 3, pages 5254 - 5262,
ISSN: 2365-6549
Language:: English
Publication year:: 2018
Bibliographic description:: Nowicki J., Woch J., Łuczak J., Zarębska M., Nowakowska-Bogdan E., Mościpan M.. Micellar Route of the Synthesis of Alkyl Xylosides: An Unexpected Effect of Amphiphilic Imidazolium Ionic Liquids. ChemicalSelect Online, 2018, Vol. 3, , s.5254-5262
DOI:: Digital Object Identifier (open in new tab) 10.1002/slct.201800125
Verified by:: Gdańsk University of Technology