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Mixed ionic-electronic conductivity and structural properties of strontium-borate glass containing nanocrystallites of Bi2 VO5.5
Abstract
Samples of strontium borate glass containing bismuth vanadate nanocrystallites were prepared. Nanocomposites containing up to 45mol% of the Bi2VO5.5 phase exhibit electrical properties closer to the strontium-borate glass than to the ferroelectric Bi2VO5.5 ceramic. The glass matrix still may contain some part of bismuth and vanadium ions even after crystallization process and there is too little of crystalline phase to observe its ferroelectric properties. The glass-ceramic nanocomposite containing 50mol% of Bi2VO5.5 phase exhibits electrical properties closer to the Bi2VO5.5 ferroelectric. The electric parameters of conduction processes in the Bi2VO5.5 nanocrystallites, glass matrix and phases boundaries are discussed. The conduction process mechanism in all nanocomposites for the low temperatures is mixed ionic–electronic and in the higher temperatures the oxygen ion hopping starts to dominate.
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- Accepted or Published Version
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- Copyright (2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS
no. 254,
edition 9,
pages 1 - 10,
ISSN: 0370-1972 - Language:
- English
- Publication year:
- 2017
- Bibliographic description:
- Wójcik N., Prześniak-Welenc M., Kupracz P., Karczewski J., Gazda M., Barczyński R.: Mixed ionic-electronic conductivity and structural properties of strontium-borate glass containing nanocrystallites of Bi2 VO5.5// PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS. -Vol. 254, iss. 9 (2017), s.1-10
- DOI:
- Digital Object Identifier (open in new tab) 10.1002/pssb.201700093
- Verified by:
- Gdańsk University of Technology
Referenced datasets
- dataset Nonlinear impedance as a function of A.C. voltage for glass 40Bi2VO5.5-60SrB4O7 annealed at 473 K for 3h and next fully crystallized measured with impedance spectroscopy method at high temperature region
- dataset The topography of strontium–borate glasses and glass-ceramics containing nanocrystallites of Bi2VO5.5. measured with SEM method
- dataset The topography of as-quenched and heat treated 50(2Bi2O3-V2O5)-50SrB4O7 and 50Bi2VO5.5-50SrB4O7 glasses measured with confocal microscope
- dataset The topography of as-quenched and heat treated 50(2Bi2O3-V2O5)-50SrB4O7 and 50Bi2VO5.5-50SrB4O7 glasses measured with AFM
- dataset The structure of strontium–borate glass-ceramics containing crystalites of Bi2VO5.5. measured with X-ray diffraction and SEM methods
- dataset The structure of strontium–borate glasses and glass-ceramics containing nanocrystallites of Bi2VO5.5. measured with X-ray diffraction method
- dataset Nonlinear impedance as a function of A.C. voltage for fully crystallized 35Bi2VO5.5-65SrB4O7 glass measured with impedance spectroscopy method at high temperature region
- dataset Nonlinear impedance of 45Bi2VO5.5-55SrB4O7 fully crystallized glass measured with impedance spectroscopy method at high temperature region
- dataset Nonlinear impedance as a function of A.C. voltage for annealed and next fully crystallized 50Bi2VO5.5-50SrB4O7 glass measured with impedance spectroscopy method at high temperature region
- dataset Linear impedance of as-quenched 40Bi2VO5.5-60SrB4O7 glass measured with impedance spectroscopy method at low temperature region
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