Morphology, Mechanical and Thermal Properties of Thermoplastic Polyurethane Containing Reduced Graphene Oxide and Graphene Nanoplatelets - Publication - MOST Wiedzy

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Morphology, Mechanical and Thermal Properties of Thermoplastic Polyurethane Containing Reduced Graphene Oxide and Graphene Nanoplatelets

Abstract

Polyurethane/graphene nanocomposites were synthesized using commercial thermoplastic polyurethane (TPU, Apilon 52DE55), and two types of graphene derivatives: graphene nanoplatelets (GNP) and reduced graphene oxide (RGO). Fourier Transformation Infrared Spectroscopy Fourier Transformation Infrared Spectroscopy (FTIR) spectroscopy, TEM, and SEM microscopy and XRD techniques were used to chemically and structurally characterize GNP and RGO nanofillers. The properties of the new TPU nanocomposite materials were studied using thermal analysis techniques (Dynamical Mechanical Analysis (DMA), Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TG)) to describe the influence of graphene nanofillers on polyurethane matrix. Our investigation describes the comparison of two types of graphene derivatives, commercial one (GNP) and synthesized (RGO) on thermoplastic polyurethanes. These nanofillers provides opportunities to achieve compatibility with the TPU matrix. The property enhancements are attributed commonly to high aspect ratio of graphene nanoplatelets and filler–polymer interactions at the interface. The obtained nanocomposites exhibit higher thermal and mechanical properties due to the good dispersion of both nanofillers into TPU matrix. It was found that the addition of 2 wt % of the nanofiller could lead to a significant reinforcement effect on the TPU matrix. Also, with high content of nanofiller (GNP and RGO), the Payne effect was observed.

Citations

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Details

Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
Materials no. 11, pages 1 - 18,
ISSN: 1996-1944
Language:
Polish
Publication year:
2018
Bibliographic description:
Strankowski M., Korzeniewski P., Strankowska J., Anu A., Sabu T.: Morphology, Mechanical and Thermal Properties of Thermoplastic Polyurethane Containing Reduced Graphene Oxide and Graphene Nanoplatelets// Materials. -Vol. 11, nr. 1 (2018), s.1-18
DOI:
Digital Object Identifier (open in new tab) 10.3390/ma11010082
Bibliography: test
  1. Novoselov, K.S.; Geim, A.K.; Morozov, S.V.; Jiang, D.; Katsnelson, M.I.; Grigorieva, I.V.; Dubonos, S.V.; Firsov, A.A. Two-dimensional gas of massless Dirac fermions in graphene. Nature 2005, 438, 197-200. [CrossRef] [PubMed] open in new tab
  2. Novoselov, K.S.; Geim, A.K.; Morozov, S.V.; Jiang, D.; Zhang, Y.; Dubonos, S.V.; Grigorieva, I.V.; Firsov, A.A. Electric field effect in atomically thin carbon films. Science 2004, 306, 666-669. [CrossRef] [PubMed] open in new tab
  3. Castro Neto, A.H.; Peres, N.M.R.; Novoselov, K.S.; Geim, A.K.; Guinea, F. The electronic properties of graphene. Rev. Mod. Phys. 2009, 81, 109-162. [CrossRef] open in new tab
  4. Zhu, Y.; James, D.K.; Tour, J.M. New routes to graphene, graphene oxide and their related applications. Adv. Mater. 2012, 24, 4924-4955. [CrossRef] [PubMed] open in new tab
  5. Pei, S.; Cheng, H.-M. The reduction of graphene oxide. Carbon 2012, 50, 3210-3228. [CrossRef] open in new tab
  6. Berger, C.; Song, Z.; Li, X.; Wu, X.; Brown, N.; Naud, C.; Mayou, D.; Li, T.; Hass, J.; Marchenkov, A.N.; et al. Electronic Confinement and Coherence in Patterned Epitaxial Graphene. Science 2006, 312, 1191-1196. [CrossRef] [PubMed] open in new tab
  7. Instytut Technologii Materiałów Elektronicznych. Available online: http://www.itme.edu.pl/ (accessed on 29 December 2017).
  8. Li, X.; Zhu, H.; Wang, K.; Cao, A.; Wei, J.; Li, C.; Jia, Y.; Li, Z.; Li, X.; Wu, D. Graphene-on-silicon schottky junction solar cells. Adv. Mater. 2010, 22, 2743-2748. [CrossRef] [PubMed] open in new tab
  9. Schwierz, F. Graphene transistors. Nat. Nanotechnol. 2010, 5, 487-496. [CrossRef] [PubMed] open in new tab
  10. Bian, J.; Lin, H.L.; He, F.X.; Wei, X.W.; Chang, I.T.; Sancaktar, E. Fabrication of microwave exfoliated graphite oxide reinforced thermoplastic polyurethane nanocomposites: Effects of filler on morphology, mechanical, thermal and conductive properties. Compos. Part A Appl. Sci. Manuf. 2013, 47, 72-82. [CrossRef] open in new tab
  11. Strankowski, M.; Piszczyk, Ł.; Kosmela, P.; Korzeniewski, P. Morphology and the physical and thermal properties of thermoplastic polyurethane reinforced with thermally reduced graphene oxide. Pol. J. Chem. Technol. 2015, 17, 88-94. [CrossRef] open in new tab
  12. Canales, J.; Muñoz, M.E.; Fernández, M.; Santamaría, A. Rheology, electrical conductivity and crystallinity of a polyurethane/graphene composite: Implications for its use as a hot-melt adhesive. Compos. Part A Appl. Sci. Manuf. 2016, 84, 9-16. [CrossRef] open in new tab
  13. Cai, D.; Jin, J.; Yusoh, K.; Rafiq, R.; Song, M. High performance polyurethane/functionalized graphene nanocomposites with improved mechanical and thermal properties. Compos. Sci. Technol. 2012, 72, 702-707. [CrossRef] open in new tab
  14. Pokharel, P.; Choi, S.; Lee, D.S. The effect of hard segment length on the thermal and mechanical properties of polyurethane/graphene oxide nanocomposites. Compos. Part A Appl. Sci. Manuf. 2015, 69, 168-177. [CrossRef] open in new tab
  15. Park, J.H.; Kim, B.K. Infrared light actuated shape memory effects in crystalline polyurethane/graphene chemical hybrids. Smart Mater. Struct. 2014, 23, 025038. [CrossRef] open in new tab
  16. Nguyen, D.A.; Lee, Y.R.; Raghu, A.V.; Jeong, H.M.; Shin, C.M.; Kim, B.K. Morphological and physical properties of a thermoplastic polyurethane reinforced with functionalized graphene sheet. Polym. Int. 2009, 58, 412-417. [CrossRef] open in new tab
  17. Nawaz, K.; Khan, U.; Ul-Haq, N.; May, P. Observation of mechanical percolation in functionalized graphene oxide/elastomer composites. Carbon 2012, 50, 4489-4494. [CrossRef] open in new tab
  18. Liao, K.H.; Park, Y.T.; Abdala, A.; Macosko, C. Aqueous reduced graphene/thermoplastic polyurethane nanocomposites. Polymer 2013, 54, 4555-4559. [CrossRef] open in new tab
  19. Kim, H.; Miura, Y.; Macosko, C.W. Graphene/Polyurethane Nanocomposites for Improved Gas Barrier and Electrical Conductivity. Chem. Mater. 2010, 22, 3441-3450. [CrossRef] open in new tab
  20. Kim, J.T.; Kim, B.K.; Kim, E.Y.; Kwon, S.H.; Jeong, H.M. Synthesis and properties of near IR induced self-healable polyurethane/graphene nanocomposites. Eur. Polym. J. 2013, 49, 3889-3896. [CrossRef] open in new tab
  21. Han, S.; Chun, B.C. Preparation of polyurethane nanocomposites via covalent incorporation of functionalized graphene and its shape memory effect. Compos. Part A Appl. Sci. Manuf. 2014, 58, 65-72. [CrossRef] open in new tab
  22. Khan, U.; May, P.; O'Neill, A.; Coleman, J.N. Development of stiff, strong, yet tough composites by the addition of solvent exfoliated graphene to polyurethane. Carbon 2010, 48, 4035-4041. [CrossRef] open in new tab
  23. Choi, J.T.; Kim, D.H.; Ryu, K.S.; Lee, H.; Jeong, H.M.; Shin, C.M.; Kim, J.H.; Kim, B.K. Functionalized graphene sheet/polyurethane nanocomposites: Effect of particle size on physical properties. Macromol. Res. 2011, 19, 809-814. [CrossRef] open in new tab
  24. Ponnamma, D.; Sadasivuni, K.K.; Strankowski, M.; Moldenaers, P.; Thomas, S.; Grohens, Y. Interrelated shape memory and Payne effect in polyurethane/graphene oxide nanocomposites. RSC Adv. 2013, 3, 16068-16079. [CrossRef] open in new tab
  25. Choi, J.T.; Dao, T.D.; Oh, K.M.; Lee, H.; Jeong, H.M.; Kim, B.K. Shape memory polyurethane nanocomposites with functionalized graphene. Smart Mater. Struct. 2012, 21, 075017. [CrossRef] open in new tab
  26. Oh, S.M.; Oh, K.M.; Dao, T.D.; Lee, H.I.; Jeong, H.M.; Kim, B.K. The modification of graphene with alcohols and its use in shape memory polyurethane composites. Polym. Int. 2013, 62, 54-63. [CrossRef] open in new tab
  27. Lorenzetti, A.; Roso, M.; Bruschetta, A.; Boaretti, C.; Modesti, M. Polyurethane-graphene nanocomposite foams with enhanced thermal insulating properties. Polym. Adv. Technol. 2016, 27, 303-307. [CrossRef] open in new tab
  28. Kumar, M.; Chung, J.S.; Kong, B.S.; Kim, E.J.; Hur, S.H. Synthesis of graphene-polyurethane nanocomposite using highly functionalized graphene oxide as pseudo-crosslinker. Mater. Lett. 2013, 106, 319-321. [CrossRef] open in new tab
  29. Kim, J.T.; Kim, B.K.; Kim, E.Y.; Park, H.C.; Jeong, H.M. Synthesis and shape memory performance of polyurethane/graphene nanocomposites. React. Funct. Polym. 2014, 74, 16-21. [CrossRef] open in new tab
  30. Liang, J.; Xu, Y.; Huang, Y.; Zhang, L.; Wang, Y.; Ma, Y.; Li, F.; Guo, T.; Chen, Y. Infrared-Triggered Actuators from Graphene-Based Nanocomposites. J. Phys. Chem. C 2009, 113, 9921-9927. [CrossRef] open in new tab
  31. Feng, Y.; Qin, M.; Guo, H.; Yoshino, K.; Feng, W. Infrared-actuated recovery of polyurethane filled by reduced graphene oxide/carbon nanotube hybrids with high energy density. ACS Appl. Mater. Interfaces 2013, 5, 10882-10888. [CrossRef] [PubMed] open in new tab
  32. Wang, X.; Hu, Y.; Song, L.; Yang, H.; Xing, W.; Lu, H. In situ polymerization of graphene nanosheets and polyurethane with enhanced mechanical and thermal properties. J. Mater. Chem. 2011, 21, 4222. [CrossRef] open in new tab
  33. Wang, T.; Zhao, L.; Shen, J.; Wu, L.; Van der Bruggen, B. Enhanced Performance of Polyurethane Hybrid Membranes for CO 2 Separation by Incorporating Graphene Oxide: The Relationship between Membrane Performance and Morphology of Graphene Oxide. Environ. Sci. Technol. 2015, 49, 8004-8011. [CrossRef] [PubMed] open in new tab
  34. Yao, H.B.; Ge, J.; Wang, C.F.; Wang, X.; Hu, W.; Zheng, Z.J.; Ni, Y.; Yu, S.H. A flexible and highly pressure-sensitive graphene-polyurethane sponge based on fractured microstructure design. Adv. Mater. 2013, 25, 6692-6698. [CrossRef] [PubMed] open in new tab
  35. Tung, T.T.; Robert, C.; Castro, M.; Feller, J.F.; Kim, T.Y.; Suh, K.S. Enhancing the sensitivity of graphene/ polyurethane nanocomposite flexible piezo-resistive pressure sensors with magnetite nano-spacers. Carbon 2016, 108, 450-460. [CrossRef] open in new tab
  36. Muralidharan, M.N.; Ansari, S. Thermally reduced graphene oxide/thermoplastic polyurethane nanocomposites as photomechanical actuators. Adv. Mater. Lett. 2013, 4, 927-932. [CrossRef] open in new tab
  37. Li, J.; Zhang, G.; Deng, L.; Zhao, S.; Gao, Y.; Jiang, K.; Sun, R.; Wong, C. In situ polymerization of mechanically reinforced, thermally healable graphene oxide/polyurethane composites based on Diels-Alder chemistry. J. Mater. Chem. A 2014, 2, 20642-20649. [CrossRef] open in new tab
  38. Huang, L.; Yi, N.; Wu, Y.; Zhang, Y.; Zhang, Q.; Huang, Y.; Ma, Y.; Chen, Y. Multichannel and repeatable self-healing of mechanical enhanced graphene-thermoplastic polyurethane composites. Adv. Mater. 2013, 25, 2224-2228. [CrossRef] [PubMed] open in new tab
  39. Khudyakov, I.V.; Zopf, D.R.; Turro, N.J. Polyurethane Nanocomposites. Des. Monomers Polym. 2009, 12, 279-290. [CrossRef] open in new tab
  40. Ponnamma, D.; Sadasivuni, K.K.; Grohens, Y.; Guo, Q.; Thomas, S. Carbon nanotube based elastomer composites-An approach towards multifunctional materials. J. Mater. Chem. C 2014, 2, 8446-8485. [CrossRef] open in new tab
  41. Yaragalla, S.; Meera, A.P.; Kalarikkal, N.; Thomas, S. Chemistry associated with natural rubber-graphene nanocomposites and its effect on physical and structural properties. Ind. Crops Prod. 2015, 74, 792-802. [CrossRef] open in new tab
  42. Bhattacharya, M. Polymer nanocomposites-A comparison between carbon nanotubes, graphene, and clay as nanofillers. Materials (Basel) 2016, 9, 1-35. [CrossRef] [PubMed] open in new tab
  43. Bera, M.; Maji, P.K. Effect of structural disparity of graphene-based materials on thermo-mechanical and surface properties of thermoplastic polyurethane nanocomposites. Polymer 2017, 119, 118-133. [CrossRef] open in new tab
  44. Yadav, S.K.; Cho, J.W. Functionalized graphene nanoplatelets for enhanced mechanical and thermal properties of polyurethane nanocomposites. Appl. Surf. Sci. 2013, 266, 360-367. [CrossRef] open in new tab
  45. Cruz, S.M.; Viana, J.C. Structure-Properties Relationships in Thermoplastic Polyurethane Elastomer Nanocomposites: Interactions between Polymer Phases and Nanofillers. Macromol. Mater. Eng. 2015, 300, 1153-1162. [CrossRef] open in new tab
  46. Barick, A.K.; Tripathy, D.K. Effect of organically modified layered silicate nanoclay on the dynamic viscoelastic properties of thermoplastic polyurethane nanocomposites. Appl. Clay Sci. 2011, 52, 312-321. [CrossRef] open in new tab
  47. Strankowski, M.; Strankowska, J.; Gazda, M.; Piszczyk, Ł.; Nowaczyk, G.; Jurga, S. Thermoplastic polyurethane/(organically modified montmorillonite) nanocomposites produced by in situ polymerization. Express Polym. Lett. 2012, 6, 610-619. [CrossRef] open in new tab
  48. Kwon, J.; Kim, H. Comparison of the properties of waterborne polyurethane/multiwalled carbon nanotube and acid-treated multiwalled carbon nanotube composites prepared by in situ polymerization. J. Polym. Sci. Part A Polym. Chem. 2005, 43, 3973-3985. [CrossRef] open in new tab
  49. Xia, H.; Song, M. Preparation and characterization of polyurethane-carbon nanotube composites. Soft Matter 2005, 1, 386. [CrossRef] open in new tab
  50. Benedito, A.; Buezas, I.; Gimenez, E.; Galindo, B.; Ortega, A. Dispersion and Characterization of Thermoplastic Polyurethane/Multiwalled Carbon Nanotubes by Melt Mixing. J. Appl. Polym. Sci. 2011, 122, 3744-3750. [CrossRef] open in new tab
  51. Quan, H.; Zhang, B.; Zhao, Q.; Yuen, R.K.K.; Li, R.K.Y. Facile preparation and thermal degradation studies of graphite nanoplatelets (GNPs) filled thermoplastic polyurethane (TPU) nanocomposites. Compos. Part A 2009, 40, 1506-1513. [CrossRef] open in new tab
  52. Pokharel, P.; Lee, D.S. High performance polyurethane nanocomposite films prepared from a masterbatch of graphene oxide in polyether polyol. Chem. Eng. J. 2014, 253, 356-365. [CrossRef] open in new tab
  53. Bagdi, K.; Molnar, K.; Sajo, I.; Pukanszky, B. Specific interactions, structure and properties in segmented polyurethane elastomers. Express Polym. Lett. 2011, 5, 417-427. [CrossRef] open in new tab
  54. Marcano, D.C.; Kosynkin, D.V.; Berlin, J.M.; Sinitskii, A.; Sun, Z.; Slesarev, A.; Alemany, L.B.; Lu, W.; Tour, J.M. Improved synthesis of graphene oxide. ACS Nano 2010, 4, 4806-4814. [CrossRef] [PubMed] open in new tab
  55. Strankowski, M.; Włodarczyk, D.; Piszczyk, Ł.; Strankowska, J. Polyurethane Nanocomposites Containing Reduced Graphene Oxide, FTIR, Raman, and XRD Studies. J. Spectrosc. 2016, 2016, 7520741. [CrossRef] open in new tab
  56. Urban, M.; Strankowski, M. Shape Memory Polyurethane Materials Containing Ferromagnetic Iron Oxide and Graphene Nanoplatelets. Materials 2017, 10, 1-23. [CrossRef] [PubMed] open in new tab
  57. Piszczyk, Ł.; Kosmela, P.; Strankowski, M. Elastic polyurethane foams containing graphene nanoplatelets. Adv. Polym. Technol. 2017, 1-10. [CrossRef] open in new tab
  58. Kucińska-Lipka, J.; Gubańska, I.; Strankowski, M.; Cieśliński, H.; Filipowicz, N.; Janik, H. Synthesis and characterization of cycloaliphatic hydrophilic polyurethanes, modified with L-ascorbic acid, as materials for soft tissue regeneration. Mater. Sci. Eng. C 2017, 75, 671-681. [CrossRef] [PubMed] open in new tab
  59. Potts, J.R.; Dreyer, D.R.; Bielawski, C.W.; Ruoff, R.S. Graphene-based polymer nanocomposites. Polymer 2011, 52, 5-25. [CrossRef] open in new tab
  60. Mittal, V. Functional Polymer Nanocomposites with Graphene: A Review. Macromol. Mater. Eng. 2014, 299, 906-931. [CrossRef] open in new tab
  61. Mai, Y.W.; Yu, Z.Z. Polymer Nanocomposites; Woodhead Publishing Limited: Sawston, UK, 2006; ISBN 978-1-85573-969-7.
  62. Du, N.; Zhao, C.; Chen, Q.; Wu, G.; Lu, R. Preparation and characterization of nylon 6/graphite composite. Mater. Chem. Phys. 2010, 120, 167-171. [CrossRef] open in new tab
  63. Chatterjee, K.; Naskar, K. Study on Characterization and Properties of Nanosilica-Filled Thermoplastic Vulcanizates. Polym. Eng. Sci. 2008, 48, 1077-1084. [CrossRef] open in new tab
  64. Bokobza, L. Multiwall carbon nanotube-filled natural rubber: Electrical and mechanical properties. Express Polym. Lett. 2012, 6, 213-223. [CrossRef] open in new tab
  65. Quan, Y.; Lu, M.; Tian, M.; Yan, S.; Yu, Z.; Zhang, L. Functional and mechanical properties of acrylate elastomer/expanded graphite nanocomposites. J. Appl. Polym. Sci. 2013, 130, 680-686. [CrossRef] open in new tab
  66. Leblanc, J.L. Nonlinear viscoelastic properties of molten thermoplastic vulcanisates: An insight on their morphology. J. Appl. Polym. Sci. 2006, 101, 4193-4205. [CrossRef] open in new tab
  67. Li, X.; Deng, H.; Li, Z.; Xiu, H.; Qi, X.; Zhang, Q.; Wang, K.; Chen, F.; Fu, Q. Graphene/thermoplastic polyurethane nanocomposites: Surface modification of graphene through oxidation, polyvinyl pyrrolidone coating and reduction. Compos. Part A Appl. Sci. Manuf. 2015, 68, 264-275. [CrossRef] open in new tab
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