Abstract
The controlled nanocrystallization of sodium-calcium-borophosphate glass (Na16.6Ca5.1B10.5Al0.8P10.5 O56.5 in at %) was conducted to investigate its influence on in vitro dissolution. Three temperatures (570 ◦C, 590 ◦C, and 610 ◦C) were selected based on thermal analysis and investigation of the morphology, structure, and in vitro dissolution of glass and glass-ceramics was conducted. The results of X-ray diffraction confirmed the presence of calcium phosphates nanocrystallites in glass-ceramics, with their contents increasing proportionally to the crystallization temperature. Infrared spectroscopy showed the presence of phosphate and borate network units, along with phosphates in a crystalline form. It was found that the target glass shows the highest mass loss in comparison to the glass-ceramics. Controlled nanocrystallization slowed down the dissolution of the materials (>10%), but did not adversely affect the deposition of hydroxyapatite layer. The presence of calcium phosphate nanocrystallites favors the process of B3+ release. The nanocrystallization of borophosphate glasses is a perspective tool for controlling the rate of dissolution of bioactive materials and enhancing their ability to deposit hydroxyapatite on their surface.
Citations
-
1
CrossRef
-
0
Web of Science
-
1
Scopus
Authors (4)
Cite as
Full text
full text is not available in portal
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
CERAMICS INTERNATIONAL
no. 49,
pages 27382 - 27390,
ISSN: 0272-8842 - Language:
- English
- Publication year:
- 2023
- Bibliographic description:
- Dziewanowska J., Karczewski J., Ali S., Wójcik N.: Nanocrystallization as a tool for controlling in vitro dissolution of borophosphate glass// CERAMICS INTERNATIONAL -Vol. 49,iss. 16 (2023), s.27382-27390
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.ceramint.2023.06.006
- Sources of funding:
-
- IDUB
- Verified by:
- Gdańsk University of Technology
seen 72 times
Recommended for you
Influence of synthesis conditions on glass formation, structure and thermal properties in the Na 2 O-CaO-P 2 O 5 system doped with Si 3 N 4 and Mg
- N. A. Wójcik,
- B. Jonson,
- D. Möncke
- + 6 authors