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Preparation and characterization of bis‐phosphonated polycarbohydrates

Abstract

A simple, cost-effective, one-pot method was proposed to introduce bis-phosphonic groups onto alginic acid and carboxymethyl cellulose (CMC). New derivatives were characterized by means of nuclear magnetic resonance, X-ray photoelectron, and attenuated total reflectance Fourier transform infrared spectroscopy. These analyses confirmed the successful transformation of carboxylic groups present in alginic acid and CMC into bis-phosphonic groups. Additionally, thermogravimetric analysis coupled with differential scanning calorimetry was employed to investigate the thermal properties of the bis-phosphonic derivatives of alginate and CMC. The results clearly demonstrate the char-forming ability of both studied bis-phosphonated polycarbohydrates, suggesting their potential as intumescent materials.

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
BIOPOLYMERS no. 115,
ISSN: 0006-3525
Language:
English
Publication year:
2024
Bibliographic description:
Sadowska K., Prześniak-Welenc M., Łapiński M.: Preparation and characterization of bis‐phosphonated polycarbohydrates// BIOPOLYMERS -Vol. 115,iss. 5 (2024), s.1-8
DOI:
Digital Object Identifier (open in new tab) 10.1002/bip.23607
Sources of funding:
  • Free publication
Verified by:
Gdańsk University of Technology

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