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Quasirelativistic potential energy curves and transition dipole moments of NaRb

Abstract

We report on extensive calculations of quasi-relativistic potential energy curves and, for the first time, transition dipole moments including spin-orbit and scalar-relativistic effects of the NaRb molecule. The calculated curves of the 0+, 0-, 1, 2 and 3 molecular states correlate for large internuclear separation with the fourteen lowest atomic energies up to the Na(3s ^2S_{1/2}) + Rb(7s ^2S_{1/2}) atomic limit. Several new features of the potential energy curves have been found.

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Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
CHEMICAL PHYSICS no. 500, pages 80 - 87,
ISSN: 0301-0104
Language:
English
Publication year:
2018
Bibliographic description:
Wiatr M., Jasik P., Kilich T., Sienkiewicz J., Stoll H.: Quasirelativistic potential energy curves and transition dipole moments of NaRb// CHEMICAL PHYSICS. -Vol. 500, (2018), s.80-87
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.chemphys.2017.10.005
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