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Side-on phosphinoboryl platinum(ii) complexes

Abstract

The oxidative addition of bromo(phosphino)boranes to platinum(0) compounds enabled the formation of platinum(II) complexes with unprecedented side-on coordination of the boryl ligand. The resulting complex underwent a reaction with carbon dioxide, leading to the insertion of a CO2 molecule into the B–P bond of the phosphinoboryl ligand.

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Details

Category:
Articles
Type:
artykuły w czasopismach
Published in:
CHEMICAL COMMUNICATIONS no. 61, pages 3728 - 3731,
ISSN: 1359-7345
Language:
English
Publication year:
2025
Bibliographic description:
Ordyszewska A., Czaplewski A., Wojnowski T., Anusiewicz I., Chojnacki J., Grubba R.: Side-on phosphinoboryl platinum(ii) complexes// CHEMICAL COMMUNICATIONS -Vol. 61,iss. 18 (2025), s.3728-3731
DOI:
Digital Object Identifier (open in new tab) 10.1039/d4cc06268j
Sources of funding:
  • Statutory activity/subsidy
Verified by:
Gdańsk University of Technology

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