Search
Abstract
In this work, glass-ceramics in the xBeO–20Fe2O3–(80-x)TeO2 system with x = 0–25 mol% were synthesized by the traditional melt quenching route and studied by inductively coupled plasma optical emission spectroscopy, X-ray diffraction, confocal microscopy, infrared and Raman spectroscopy. BeO addition was found to support the crystallization process of Fe2O3 during melting, and an increased BeO content was associated with an increased fraction of the crystalline Fe2O3 phase and an increased size of these crystallites. Furthermore, samples doped with BeO exhibit an increasing polymerization of the residual tellurite glass network compared to the undoped sample. The magnetic properties and specific heat of all synthesized materials were measured, and the results show that all studied samples behave as spin-glasses. Also, the Morin transition of hematite was observed at 260 K with intensity depending on the material content in Fe2O3 crystalline phase, the formation of which correlates with the amount of added BeO.
Citations
-
1 9
CrossRef
-
0
Web of Science
-
2 0
Scopus
Authors (9)
-
N Tagiara
-
Sharafat Ali profesor
-
H Segawa
-
B Jonson
-
Doris Möncke profesor
-
Efstratios Kamitsos profesor
Cite as
Full text
- Publication version
- Accepted or Published Version
- License
-
open in new tab
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
no. 41,
pages 5214 - 5222,
ISSN: 0955-2219 - Language:
- English
- Publication year:
- 2021
- Bibliographic description:
- Wójcik N., Tagiara N., Ali S., Górnicka K., Segawa H., Klimczuk T., Jonson B., Möncke D., Kamitsos E.: Structure and magnetic properties of BeO-Fe2O3-Al2O3-TeO2 glass-ceramic composites// JOURNAL OF THE EUROPEAN CERAMIC SOCIETY -Vol. 41,iss. 10 (2021), s.5214-5222
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.jeurceramsoc.2021.04.005
- Verified by:
- Gdańsk University of Technology
seen 140 times
Recommended for you
Influence of synthesis conditions on glass formation, structure and thermal properties in the Na 2 O-CaO-P 2 O 5 system doped with Si 3 N 4 and Mg
- N. A. Wójcik,
- B. Jonson,
- D. Möncke
- + 6 authors
Investigation of the structural and thermal properties of aluminum-rich Ca–Al–Si–O–N glasses
- S. Ali,
- J. Ryl,
- A. S. Hakeem
- + 2 authors
The effect of nitrogen on the structure and thermal properties of beryllium-containing Na-(Li)-Si-O-N glasses
- N. Wójcik,
- B. Jonson,
- D. Möncke
- + 4 authors