Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions - Publication - Bridge of Knowledge

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Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions

Abstract

Corrosion properties of aluminium alloy AA6063-T5 were investigated in molybdate-containing NaCl solutions. Electrochemical, microscopic, and spectroscopic experiments were utilized to examine the mechanism of corrosion inhibition by molybdates. SEM-EDX, magnetic force, and intermodulation electrostatic force microscopy data suggested that the inhibition initiation preferentially occurred over Fe-rich cathodic IMPs. Spectroscopic measurements demonstrated that the formed surface layer consists of mixed Mo(VI, V, IV) species. This layer provided inhibition with an efficiency of ∼90% after 4 h of exposure. High efficacy of ∼70% was achieved even after one week of exposure. A two-step oxidation-reduction mechanism of corrosion inhibition by aqueous molybdates was proposed

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Category:
Articles
Type:
artykuły w czasopismach
Published in:
CORROSION SCIENCE no. 171,
ISSN: 0010-938X
Language:
English
Publication year:
2020
Bibliographic description:
Kharitonov D., Dobryden I., Sefer B., Ryl J., Wrzesińska A., Makarova I., Bobowska I., Kurilo I., Claesson P.: Surface and Corrosion Properties of AA6063-T5 Aluminium Alloy in Molybdate-containing Sodium Chloride Solutions// CORROSION SCIENCE -Vol. 171, (2020), s.108658-
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.corsci.2020.108658
Verified by:
Gdańsk University of Technology

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