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Abstract
We present the synthesis of an oligomer with carboxy and methacrylic groups based on Epidian 6. The effect of the catalyst nature and amount, solvent nature and process temperature on the rate of the reaction between Epidian6 monomethacrylate and adipic acid was examined at 313, 323 and 333 K in the presence of 4-dimethylaminopyridine, 1,4-diazobicyclo[2.2.2]octane, and benzyltriammonium chloride. The synthesized oligomer was characterized using chemical and IR-spectroscopic analyses. We suggest the use of the synthesized product as an active additive to epoxy-oligoesteric blends based on Epidian 5. The chemistry of the film forming process has been determined using IR-spectroscopy.
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Authors (5)
-
Mykhailo Bratychak
- Lviv Polytechnic National University Department of Petroleum Chemistry and Technology
-
Ostap Iatsyshyn
- Lviv Polytechnic National University Department of Petroleum Chemistry and Technology
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O. Shyshchak
- Lviv Polytechnic National University Department of Petroleum Chemistry and Technology
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- Accepted or Published Version
- DOI:
- Digital Object Identifier (open in new tab) 10.14314/polimery.2016.766
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- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
Polimery
no. 61,
pages 766 - 772,
ISSN: 0032-2725 - Language:
- English
- Publication year:
- 2016
- Bibliographic description:
- Bratyczak M., Iatsyshyn, O., Bruździak P., Namieśnik J., Shyshchak O.: Synthesis and properties of carboxy derivative of Epidian 6 monomethacrylate (in English)// Polimery. -Vol. 61, nr. 11-12 (2016), s.766-772
- DOI:
- Digital Object Identifier (open in new tab) 10.14314/polimery.2016.766
- Verified by:
- Gdańsk University of Technology
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