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The influence of anchoring group position in ruthenium dye molecule on performance of dye-sensitized solar cells
Abstract
The effect of anchoring group position and, in consequence, the orientation of the ruthenium dye molecule on titania surface on the performance of dye-sensitized solar cells has been studied intensively. Three model ruthenium sensitizing dyes bearing carboxylic anchoring group in ortho, meta or para position were synthesized and well characterized by spectroscopic, electrochemical, photophysical and photochemical measurements. The results were confronted with the quantum-mechanical calculations and discussed. The para derivative has been found as the most effective sensitizer with the cells efficiency twice higher than the meta and four times higher than the ortho derivatives.
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Authors (9)
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Maciej Zals dr hab.
- UNIWERSYTET IM. ADAMA MICKIEWICZA ZAKŁAD CHEMII SUPRAMOLEKULARNEJ
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Błażej Gierczyk dr hab.
- UNIWERSYTET IM. ADAMA MICKIEWICZA ZAKŁAD CHEMII SUPRAMOLEKULARNEJ
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Alberto Bossi dr
- CNR Istituto di Scienze e Tecnologie Molecolari
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Patrizia Romana Mussini dr
- Department of Chemistry, University of Milan
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Radosław Pankiewicz dr hab.
- UNIWERSYTET IM. ADAMA MICKIEWICZA
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Małgorzata Makowska-janusik dr hab.
- Faculty of Mathematics and Natural Science, Jan Długosz University Institute of Physics
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Łukasz Popenda dr
- UNIWERSYTET IM. ADAMA MICKIEWICZA Centrum NanoBioMedyczne
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Details
- Category:
- Articles
- Type:
- artykuł w czasopiśmie wyróżnionym w JCR
- Published in:
-
DYES AND PIGMENTS
pages 335 - 346,
ISSN: 0143-7208 - Language:
- English
- Publication year:
- 2018
- Bibliographic description:
- Zals M., Gierczyk B., Bossi A., Mussini P., Klein M., Pankiewicz R., Makowska-Janusik M., Popenda Ł., Stampor W.: The influence of anchoring group position in ruthenium dye molecule on performance of dye-sensitized solar cells// DYES AND PIGMENTS. -, nr. 150 (2018), s.335-346
- DOI:
- Digital Object Identifier (open in new tab) 10.1016/j.dyepig.2017.12.029
- Verified by:
- Gdańsk University of Technology
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