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Transition dipole moments of the lithium dimer

Abstract

In addition to knowledge of interatomic adiabatic potential energy curves of diatomic systems, it is essential to know electronic transition dipole moments. They are needed in understanding processes like photodissociation, photoassociation, cooling, and trapping. Here, we present electronic transition dipole moments calculated for 74 allowed transitions between 26 states of Li2 [P. Jasik, J.E. Sienkiewicz, Chem. Phys. 323 (2006) 563]. In the asymptotic internuclear region our results reasonably agree with previously calculated and measured results.

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Category:
Articles
Type:
artykuł w czasopiśmie wyróżnionym w JCR
Published in:
ATOMIC DATA AND NUCLEAR DATA TABLES no. 99, edition 2, pages 115 - 155,
ISSN: 0092-640X
Language:
English
Publication year:
2013
Bibliographic description:
Jasik P., Sienkiewicz J. E.: Transition dipole moments of the lithium dimer// ATOMIC DATA AND NUCLEAR DATA TABLES. -Vol. 99, iss. 2 (2013), s.115-155
DOI:
Digital Object Identifier (open in new tab) 10.1016/j.adt.2011.06.003
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