Search
Ultrahigh Quantum Efficiency Near-Infrared-II Emission Achieved by Cr3+ Clusters to Ni2+ Energy Transfer
Abstract
Increasing demand for near-infrared-II (NIR-II) light sources requires improved NIR-II phosphors. We present a series of phosphors codoped with Cr3+ and Ni2+ that possess NIRII emission with an unprecedented internal quantum efficiency (IQE) of 97.4%. Our study reveals an energy transfer mechanism involving clusters of Cr3+ where luminescent centers are closely matched in energy and where the Ni2+ emission intensity can be tuned through sintering temperature. The profound electron paramagnetic resonance (EPR) studies disclose the interaction between Cr3+ clusters and Cr3+−Ni2+ pairs, further proving the cause of such a high IQE and the significance of Cr3+ clusters. This work provides promising pathways for the development of NIR-II light-emitting diodes with outstanding efficiency by suggesting a new energy transfer source of Cr3+.
Citations
-
7
CrossRef
-
0
Web of Science
-
7
Scopus
Authors (15)
-
Chih-Yu Chang
-
Ming-Hsuan Huang
-
Kuan-Chun Chen
-
Wen-Tse Huang
-
Mikołaj Kamiński
-
Natalia Majewska mgr inż.
-
Jia-Hao Chen
-
Ding-Hua Cherng
-
Kuang-Mao Lu
-
Wei Kong Pang
-
Vanessa K. Peterson
-
Sebastian Mahlik
-
Grzegorz Leniec dr inż.
-
Ru-Shi Liu
Cite as
Full text
full text is not available in portal
Keywords
Details
- Category:
- Articles
- Type:
- artykuły w czasopismach
- Published in:
-
CHEMISTRY OF MATERIALS
no. 36,
pages 3941 - 3948,
ISSN: 0897-4756 - Language:
- English
- Publication year:
- 2024
- Bibliographic description:
- Chang C., Huang M., Chen K., Huang W., Kamiński M., Majewska N., Klimczuk T., Chen J., Cherng D., Lu K., Pang W. K., Peterson V. K., Mahlik S., Leniec G., Liu R.: Ultrahigh Quantum Efficiency Near-Infrared-II Emission Achieved by Cr3+ Clusters to Ni2+ Energy Transfer// CHEMISTRY OF MATERIALS -Vol. 36,iss. 8 (2024), s.3941-3948
- DOI:
- Digital Object Identifier (open in new tab) 10.1021/acs.chemmater.4c00438
- Sources of funding:
-
- Free publication
- Verified by:
- Gdańsk University of Technology
seen 1 times
Recommended for you
Local Dye Concentration and Spectroscopic Properties of Monomer−Aggregate Systems in Hybrid Porous Nanolayers
- A. Synak,
- B. Grobelna,
- L. Kułak
- + 2 authors
Modelling of heat transfer in supercritical pressure recuperators
- D. Mikielewicz,
- J. Mikielewicz
Multi-Option Model of Railway Traffic Organization Including the Energy Recuperation
- M. Jacyna,
- P. Gołębiowski,
- M. Urbaniak