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An Empirical Model for the Polarisation Characteristics of Indoor Off-Body Channels
PublicationThis paper presents an analysis of the polarisation characteristics for the channel in dynamic off-body communications, and an empirical channel model, based on measurements performed at 2.45 GHz in an office environment. Body presence and propagation conditions have a strong influence on signal depolarisation. The model assumes three components for the total path loss: mean path loss, represented by a log-distance function with...
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Melody Harmonization with Interpolated Probabilistic Models
PublicationMost melody harmonization systems use the generative hidden Markov model (HMM), which model the relation between the hidden chords and the observed melody. Relations to other variables, such as the tonality or the metric structure, are handled by training multiple HMMs or are ignored. In this paper, we propose a discriminative means of combining multiple probabilistic models of various musical variables by means of model interpolation....
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Mechanisms of azole resistance among clinical isolates of Candida glabrata in Poland
PublicationCandida glabrata is currently ranked as the second most frequently isolated aetiological agent of human fungal infections, next only to Candida albicans. In comparison with C. albicans, C. glabrata shows lower susceptibility to azoles, the most common agents used in treatment of fungal infections. Interestingly, the mechanisms of resistance to azole agents in C. albicans have been much better investigated than those in C. glabrata....
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Load introduction to composite columns revisited—Significance of force allocation and shear connection stiffness
PublicationThe AISC 360-16 Specification recommends that the design shear force between parts of a composite column in the load introduction area shall be calculated based on the force allocation at ultimate limit state. Applicability of this straightforward method to the load levels that usually arise in slender composite columns is questionable, as this capacity-based force allocation is only true when the axial force is equal to the plastic...
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Advancing sustainable hybrid bitumen systems: A compatibilization solution by functionalized polyolefins for enhanced crumb rubber content in bitumen
PublicationPolymer waste pollution has a profound effect on the environment and, consequently, on the lifestyle of hu- mankind. The massive production and disposal of cross-linked polymers clearly exemplify the challenges of recycling. Increasing efforts are being undertaken to introduce recycled polymers, especially crumb rubber (CR), into asphalt formulations. Due to the rather poor processability and phase separation associated with CR- modified...
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Static magnetic multipole susceptibilities of the relativistic hydrogenlike atom in the ground state: Application of the Sturmian expansion of the generalized Dirac-Coulomb Green function
PublicationWe study far- and near-field magnetic and electric multipole moments induced in the ground state of the Dirac one-electron atom placed in a weak 2L-pole magnetostatic field. The analysis is carried out within the framework of the first-order Rayleigh-Schrödinger perturbation theory, with the use of the Sturmian expansion of the generalized Dirac-Coulomb Green function [Szmytkowski, J. Phys. B 30, 825 (1997);J. Phys. B 30, 2747(E)...
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Ground tire rubber thermo-mechanically devulcanized in the presence of waste engine oil as asphalt modifier
PublicationCross-linked elastomers network is main limitation for industrial usage of ground tire rubber (GTR) as asphalts’ and road pavements modifier. GTR was thermo-mechanically devulcanized via extrusion in the presence of waste engine oil (WEO) at temperature ranges from 150 to 280 °C. Combined impact of WEO content and extruder barrel temperature on the change of cross-linked structure of degraded GTR (DTGR) was investigated through...
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Charge Transfer, Complexes Formation and Furan Fragmentation Induced by Collisions with Low-Energy Helium Cations
PublicationThe present work focuses on unraveling the collisional processes leading to the fragmentation of the gas-phase furan molecules under the He+ and He2+ cations impact in the energy range 5–2000 eV. The presence of different mechanisms was identified by the analysis of the optical fragmentation spectra measured using the collision-induced emission spectroscopy (CIES) in conjunction with the ab initio calculations. The measurements of...
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One Year Evaluation of Material Properties Changes of Polylactide Parts in Various Hydrolytic Degradation Conditions
PublicationBiodegradable biocompatible materials are widely used in medical applications. Determining the possibility of using biodegradable materials depends on determining the changes in their parameters over time due to degradation. The current scientific research on biodegradable materials has presented results based on research methods characterized by the different geometry and cross-section size of the specimen, type of degradation...
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The electronic excited states of dichloromethane in the 5.8-10.8 eV energy range investigated by experimental and theoretical methods
PublicationWe present a comprehensive experimental high-resolution vacuum ultraviolet (VUV) photoabsorption spectrum of dichloromethane, CH 2 Cl 2 , with absolute cross sections determined for the full 5.8–10.8 eV energy-range. The calculations on the vertical excitation energies and oscillator strengths were performed using the equation-of-motion coupled cluster method, restricted to the single and double excitations level (EOM-CCSD), and...
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Preparation and characterisation of solution-cast Nafion membrane
PublicationNafion is a commercial name for a perfluorosulfonic polymer, which has been developed in 1962 by Dupont de Nemours. This polymer consists of a polytetrafluoroethylene backbone and regular spaced long perfluorovinyl ether pendant side chains terminated by a sulfonate ionic group. These sulfonate groups are responsible for cation-exchange properties of Nafion. Thanks to the ion-exchange properties, water permeability, good chemical,...
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Analytics of Surfactants in the Environment: Problems and Challenges
PublicationSurfactants (surface active agents = SAAs) are a group of compoundswith specific physicochemical properties (amphiphilicity,solubility in polar and nonpolar liquids, ability to form micelles,adsorption at phase boundaries).1,2 Because of their properties,surface-active compounds are widely applied in industry and thehousehold (e.g., in detergents, personal-care products, paints,pesticides, petroleum products). As their applications...
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Linear and nonlinear impedance in iron oxide glasses containing alkaline ions and alkali free
PublicationThe linear and nonlinear impedance spectra of oxide glasses were measured in the frequency range of 1 mHz to 1 MHz and in the temperature range of 153K to 483K. Two groups of iron oxide glass samples were prepared, the first one containing alkaline ions and the second one without alkali. In the first group, compositions of glasses were as follows: (in %mol) 50% SiO2 , 25% PbO, 15% Fe2O3 and 15% one of alkaline oxides: Na2O, K2O,...
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SrCe0.9In0.1O3-δ-based reversible symmetrical Protonic Ceramic Cell
PublicationIn-doped SrCe0.9In0.1O3-δ (SCI) perovskite-type oxide is utilized as the solid electrolyte, as well as a component, together with SrFe0.75Mo0.25O3-δ (SFM) compound, in the composite-type electrodes to construct symmetrical Protonic Ceramic Fuel Cells (PCFC). With good mutual stability of SCI and SFM at high temperatures in water vapor-containing reducing and oxidizing conditions, as well as sufficient ionic conductivity with high...
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Effect of choline chloride based natural deep eutectic solvents on aqueous solubility and thermodynamic properties of acetaminophen
PublicationIn this work, natural deep eutectic solvents (NADESs) containing choline chloride as hydrogen bond acceptor and 1,2-propanediol, malic acid and tartaric acid as hydrogen bond donors have been synthesized and applied to enhance the aqueous solubility of model sparingly water-soluble drug – acetaminophen. The results indicate that the greatest impact on the solubility of acetaminophen have deep eutectic solvents based on 1,2-propanediol...
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Morphology control through the synthesis of metal-organic frameworks
PublicationDesignable morphology and predictable properties are the most challenging goals in material engineering. Features such as shape, size, porosity, agglomeration ratio significantly affect the final properties of metal- organic frameworks (MOFs) and can be regulated throughout synthesis parameters but require a deep under- standing of the mechanisms of MOFs formation. Herein, we systematically summarize the effects of the indi- vidual...
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Cytocompatibility of stabilized black phosphorus nanosheets tailored by directly conjugated polymeric micelles for human breast cancer therapy
PublicationThe novel procedure of few-layer black phosphorus (FLBP) stabilization and functionalisation was here proposed. The cationic polymer PLL and non-ionic PEG have been involved into encapsulation of FLBP to allow sufficient time for further nanofabrication process and overcome environmental degradation. Two different spacer chemistry was designed to bind polymers to tumor-homing peptides. The efficiency of functionalisation was examined...
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Multi-state multi-reference Møller-Plesset second-order perturbation theory for molecular calculations
PublicationThis work presents multi‐state multi‐reference Møller–Plesset second‐order perturbation theory as a variant of multi‐reference perturbation theory to treat electron correlation in molecules. An effective Hamiltonian is constructed from the first‐order wave operator to treat several strongly interacting electronic states simultaneously. The wave operator is obtained by solving the generalized Bloch equation within the first‐order...
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Electrical properties of Na2O-CaO-P2O5 glasses doped with SiO2 and Si3N4
PublicationSodium-calcium-phosphate glasses doped with SiO2 or Si3N4 having similar sodium ion concentrations were prepared by melt quenching. The conductivity was measured by impedance spectroscopy under nitrogen atmosphere in a wide frequency range (10 mHz–1 MHz) and wide temperature range (153–473 K). At 36.6 °C, DC conductivities of all glasses vary between 1.1 ∗ 10−12 and 8.9 ∗ 10−12 S cm−1 and have similar activation energies (between...
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Study of oxygen electrode reactions on symmetrical porous SrTi0.30Fe0.70O3-δ electrodes on Ce0.8Gd0.2O1.9 electrolyte at 800 °C–500 °C
PublicationIron doped strontium titanates (SrTi1-xFexO3-δ) are an interesting mixed ionic-electronic conductor model used to study basic oxygen reduction/oxidation reactions. In this work, we performed an impedance spectroscopy study on symmetrical porous SrTi0.30Fe0.70O3-δ (STF70) electrodes on a ceriabased electrolyte. The sample was measured in varying oxygen concentration: from 0.3% to 100% in 800 °C - 500 °C temperature range. Low polarisation...
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Monitoring of Odour Nuisance from Landfill Using Electronic Nose
PublicationThe paper presents the results of investigation on classification of atmospheric air samples collected in a vicinity of municipal landfill with respect to their odour nuisance. The research was conducted using a prototype of electronic nose instrument and a commercial electronic nose of Fast/Flash GC type –HERACLES II. The prototype was equipped with a set of six semiconductor sensors by FIGARO Co.. Classification of the air samples...
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Export Diversification and Development - Empirical Assessment
PublicationThis paper assesses the role played by country specific factors as determinants of exports' diversification process. Using a panel data-set for 60 countries and twenty years (1985-2004) we confirm that even after clearing out differences in income per capita, cross section variability in the degree of exports' diversification is significant. In general, apart from per capita income, variables influencing the size of accessible...
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RSVP-TE as a reservation protocol for optical networks
PublicationIn this paper, we consider the reservation of optical resources problem. We implement extensions for RSVP-TE (Resource ReSerVation Protocol with Traffic Engineering Extension) to achieve the new functionality for optical resources reservation. Based on ASON/GMPLS architecture we examine an open source implementation KOM RSVP-Engine and extend its functionality according to ITU-T and IETF recommendations. The transport plane consists...
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What determines export diversification in the development process? Empirical assessment.
PublicationThis paper assesses the role played by country-specific factors as determinants of relative export diversification. Using a panel data set for 60 countries and 20 years (1985–2004), we confirm that even after clearing out differences in income per capita, cross-country variability in the degree of export diversification is significant. In general, apart from per capita income, features influencing the size of accessible markets...
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Numerical modeling of GPR field in damage detection of a reinforced concrete footbridge
PublicationThe paper presents a study on the use of the ground penetrating radar (GPR) method in diagnostics of a footbridge. It contains experimental investigations and numerical analyses of the electromagnetic field propagation using the finite difference time domain method (FDTD). The object of research was a reinforced concrete footbridge over a railway line. The calculations of the GPR field propagation were performed on a selected cross-section...
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VERSATILE SPACE OF PERSIAN COURT HOUSE IN ISFAHAN USED AS POLISH CHILDREN HABITAT DURING THE WW2
PublicationDuring WW2 thousands of Polish citizens were deported to Siberia and Kazakhstan in the USSRdoomed to exterminating labour. The Polish army was also detained there. The Iranian Shahallowed Polish soldiers and civilians to cross from Russia to Iran. In Isfahan Polish fugitives, mainlychildren, were accommodated in Persian traditional court houses which were converted into theirtemporary habitat, where new...
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3D POINT-CLOUD SPATIAL EXPANSION BY TOTAL LEAST-SQUARES LINE FITTING
PublicationPoint-cloud spatial expansion (PCSE) allows the creation of a new pointcloud form that presents an alternative geometry of an entire object in a single spatial view. Spatial expansion facilitates the analysis process and introduces an additional spatial parameter describing the point cloud. An important element of the PCSE method is determining the position of the axis of symmetry of a symmetrical object: the procedure for determining...
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Influence of water soaking on the ultimate tensile strength of polyester-based coated woven fabrics
PublicationThis research aims to determine the influence of water-soaking on polyester-based coated woven fabrics for ultimate tensile strength and elongation at break under uniaxial tensile tests. The paper begins with a short survey of literature concerning the investigation of the determination of coated woven fabric properties. The authors carried out the uniaxial tensile tests with an application of a flat grip to establish the values...
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COMPUTER ANALYSIS OF HYDRAULIC CONDITIONS IN A SANITARY CHAMBER
PublicationThis paper presents analysis of hydraulic conditions of sewage flow down the slipway (ramp) in the collecting sanitary chamber connecting 3 collectors on the inlet: ⌀600, ⌀800 and ⌀1400 and one on the outlet ⌀1600 mm, with a maximum difference of elevation 5 m. The mathematical model has been made and hydraulic calculations were carried out in steady flow conditions. Then wastewater surface elevation, energy grade line elevation,...
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Dissociative electron attachment and anion-induced dimerization in pyruvic acid
PublicationWe report partial cross sections for the dissociative electron attachment to pyruvic acid. A rich fragmentation dynamics is observed. Electronic structure calculations facilitate the identification of complex rearrangement reactions that occur during the dissociation. Furthermore, a number of fragment anions produced at electron energies close to 0 eV are observed, that cannot originate from single electron-molecule collisions....
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Effect of the inclination angle of the condenser on the heat transfer coefficient value – experimental study
PublicationWhen considering problem of the condensation of the refrigerant in a flow inside channel, one needs to pay attention to the shape of its cross-section, the hydraulic diameter, the channel length as well as the orientation of the channel axis in space (horizontal, vertical, inclined). This paper presents an experimental study concerning the effect of the inclination angle of the condenser with a single coil pipe on the heat transfer...
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Wpływ przechyłki na zjawisko postępowania zużycia bocznego szyn kolejowych w łukach poziomych
PublicationDegradacja elementów nawierzchni kolejowej jest zagadnieniem bardzo złożonym, w które uwikłane jest wiele czynników związanych między innymi z układem geometrycznym toru kolejowego, właściwościami trybologicznymi poszczególnych elementów nawierzchni, jak również z parametrami podłoża gruntowego, a także z właściwościami samych pojazdów szynowych. W artykule omówiono jeden z powyższych problemów, tj. wpływ ukształtowania toru kolejowego...
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Comparison of different types of electronic nose instruments for evaluation of odour nuisance from landfill
PublicationThe paper presents and compares the results of investigation on classification of atmospheric air samples collected in a vicinity of municipal landfill with respect to their odour nuisance. The research was conducted using a prototype of electronic nose instrument and a commercial electronic nose of Fast/Flash GC type – HERACLES II. The prototype was equipped with six semiconductor sensors of TGS type. Classification of the air...
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Comparison of Quality Evaluation of Agricultural Distillates Using Prototype of Electronic Nose and Fast/Flash GC
PublicationThe paper presents the results of investigation on quality evaluation of agricultural distillates using a prototype of electronic nose instrument and a commercial electronic nose of Fast/Flash GC type – HERACLES II. The prototype was equipped with a set of six semiconductor sensors by FIGARO Co.. In case of the prototype volatile fraction of the agricultural distillate was prepared via barbotage process. HERACLES II analysed the...
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PHOTON LUMINESCENCE STUDIES OF TETRAHYDROFURAN FOLLOWING TRIHYDROGEN CATIONS IMPACT IN THE 20–1000 EV ENERGY RANGE
PublicationPhoton emission arising during tetrahydrofuran (C4H8O, THF) fragmentation initiated by H3 + ion impact has been studied experimentally. Luminescence fragmentation spectra and the relative emission cross-sections of the excited fragments have been measured using collision-induced emission spectroscopy in the 20–1000 eV energy range. The main features in the spectra are the H Balmer series lines, whose intensities decrease with increasing...
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Torsional buckling and post-buckling of columns made of aluminium alloy
PublicationThe paper concerns torsional buckling and the initial post-buckling of axially compressed thin-walled aluminium alloy columns with bisymmetrical cross-section. It is assumed that the column material behaviour is described by the Ramberg–Osgood constitutive equation in non-linear elastic range. The stationary total energy principle is used to derive the governing non-linear differential equation. An approximate solution of the equation...
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Evaluation of the structures size in the liquid-gas flow by gamma-ray absorption
PublicationThe rapid development of tomography methods particularly electrical, X and gamma rays allows for a wide range of the information about flow structure. However, all of such methods are quite complicated. At the same time much simpler systems as the measuring system of gamma rays absorption, allows to obtain a all key flow information which describe the two-phase flow. In the article the results of analyzes of radiometric signal...
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Selected studies of flow maldistribution in a minichannel plate heat exchanger
PublicationAnalysis of the state of-the-art in research of minichannel heat exchangers, especially on the topic of flow maldistribution in multiple channels, has been accomplished. Studies on minichannel plate heat exchanger with 51 parallel minichannels with four hydraulic diameters, i.e., 461 μm, 574 μm, 667 μm, and 750 μm have been presented. Flow at the instance of filling the microchannel with water at low flow rates has been visualized. The...
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The effects of selected factors on pedestrian crossings in urban areas
PublicationPedestrian crossings are designed to help pedestrians cross a road. There are at-grade pedestrian crossings with or without traffic lights and grade separated crossings such as subways and footbridges. Pedestrian crossings may be located next to a junction or on road sections between junctions. Where at-grade crossings are involved, pedestrians and motorists interact, which may lead to dangerous situations and road traffic conflicts....
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Sensitivity analysis in design process of sandwich U-shaped composite footbridge
PublicationThe structure of the sandwich composite footbridge of a 14 metre span length and U-shaped cross-section was analysed. Sensitivity analysis was performed to support the design process of this innovative object. Linear discrete sensitivity analysis was performed by means of finite element method. The influence of vari-ation of several design variables i.e. thicknesses of inner and outer laminates on the mid-span deflection, as-sumed...
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Diagnosing marine turbine engines through energy characteristics of their flow section
PublicationThe aim of the performed research was to develop of diagnostic method of the flow section of a marine turbine combustion engine based on the level of delamination of its energy characteristics. The here adopted diagnostic model provides for a formulation of the evaluation of the technical conditions based on the measurements of the parameters of the thermodynamic medium in the characteristic control cross-sections of the engine...
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Miniaturized dual‐band branch‐line coupler with enhanced bandwidth
PublicationIn this letter, a miniaturized hybrid dual-band branch-line coupler (BLC) with enhanced fractional bandwidths is proposed. Compact size and bandwidth enhancement are obtained using meandered transmission line sections with broken symmetry between cross-coupling branches. The circuit is designed at a low numerical cost using surrogate-assisted techniques. The optimized design features small size of only 0.25λg×0.19λg(28% miniaturization...
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FE analysis of a coupled energetic-statistical size effect in plain concrete beams with varying material properties.
PublicationThe numerical FE investigations of a coupled energetic-statistical size effect in unnotched concrete beams of similar geometry under quasi-static three point bending were performed within elasto-plasticity with non-local softening. The stochastic FE analyses were carried out with three different beam sizes. Deterministic calculations were performed with the uniform distribution of a uniaxial tensile strength. In statistical calculations...
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O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission
PublicationOxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon-photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core-valence double excitations, while shape resonances are suppressed. In contrast,...
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Anion–water interactions of weakly hydrated anions: molecular dynamics simulations of aqueous NaBF4 and NaPF6
PublicationIn aqueous ionic solutions, both the structure and the dynamics of water are altered dramatically with respect to the pure solvent. The emergence of novel experimental techniques makes these changes accessible to detailed investigations. At the same time, computational studies deliver unique possibilities for the interpretation of the experimental data at the molecular level. Here, using molecular dynamics simulations, we demonstrate...
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Enhanced Mechanical and Electromechanical Properties of Compositionally Complex Zirconia Zr1–x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2−δ Ceramics
PublicationCompositionally complex oxides (CCOs) or high-entropy oxides (HEOs) are new multi-element oxides with unexplored physical and functional properties. In this work, we report fluorite structure derived compositionally complex zirconia with composition Zr1- x(Gd1/5Pr1/5Nd1/5Sm1/5Y1/5)xO2-δ (x = 0.1 and 0.2) synthesized in solid-state reaction route and sintered via hot pressing at 1350 °C. We explore the evolution of these oxides'...
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Collision Strengths of Astrophysical Interest for Multiply Charged Ions
PublicationThe electron impact excitation and ionization processes are crucial for modeling the spectra of different astrophysical objects, from atmospheres of late-type stars to remnants of supernovae and up to the light emission from neutron star mergers, to name just a few. Despite their signifi- cance, however, little is known quantitatively about these processes for low- and medium-impact energies of, say, Ekin . 5000 eV of the free...
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INNOVATIVE THERMODYNAMICAL CYCLES BASED ON ENHANCEMENT MASS, MOMENTUM, ENTROPY AND ELECTRICITY TRANSPORT DUE TO SLIP, MOBILITY, TRANSPIRATION, ENTROPY AND ELECTRIC JUMPS AS WELL AS OTHER NANO-FLOWS PHENOMENA
PublicationIn our work, a further development of the authors model of thermo-chemical flow of fuel, air, oxygen, steam water, species, ionic and electron currents within nano channels and nano-structures of novel devices is presented. Different transport enhancement models are taken into account -among them the most important are: the velocity slip connected with complex external friction, the Darcy mobility and the Reynolds transpiration....
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Pedestrian Safety at Midblock Crossings on Dual Carriageway Roads in Polish Cities
PublicationRoad crossings across two or more lanes in one direction are particularly dangerous due to limited sight distance and high vehicle speeds. To improve their safety, road authorities should provide safety treatments. These may include additional measures to reduce speed and narrow the road cross-section and the introduction of active pedestrian crossings. Equipped with flashing lights activated automatically when a pedestrian is...
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Functional fluorine-doped tin oxide coating for opto-electrochemical label-free biosensors
PublicationSensors operating in multiple domains, such as optical and electrochemical, offer properties making biosensing more effective than those working in a single domain. To combine such domains in one sensing device, materials offering a certain set of properties are required. Fluorine-doped tin oxide (FTO) thin film is discussed in this work as functional optically for guiding lossy modes and simultaneously electrochemically, i.e....