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Search results for: fragmentation

  • Dissociative multi-photon ionization of isolated uracil and uracil-adenine complexes

    Publication
    • M. Ryszka
    • R. Pandey
    • C. Rizk
    • J. Tabet
    • B. Barc
    • M. Dampc
    • N. Mason
    • S. Eden

    - INTERNATIONAL JOURNAL OF MASS SPECTROMETRY - Year 2016

    Recent multi-photon ionization (MPI) experiments on uracil revealed a fragment ion at m/z 84 that was proposed as a potential marker for ring opening in the electronically excited neutral molecule. The present MPI measurements on deuterated uracil identify the fragment as C3H4N2O+ (uracil+ less CO), a plausible dissociative ionization product from the theoretically predicted open-ring isomer. Equivalent measurements on thymine...

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  • Anionic states of C6Cl6 probed in electron transfer experiments

    Publication

    - PHYSICAL CHEMISTRY CHEMICAL PHYSICS - Year 2022

    This is the first comprehensive investigation on the anionic species formed in collisions of fast neutral potassium (K) atoms with neutral hexachlorobenzene (C6Cl6) molecules in the laboratory frame range from 10 up to 100 eV. In such ion-pair formation experiments, we also report a novel K+ energy loss spectrum obtained in the forward scattering giving evidence of the most accessible electronic states. The vertical electron affinity...

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