Search results for: THIOPHENECARBOXYLATES - Bridge of Knowledge

Search results for: THIOPHENECARBOXYLATES

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A comparison of structural and luminescence properties of lead(II) coordination polymers with isomeric thiophenecarboxylate ligands
Publication
- M. Kowalik
- J. Masternak
- K. Kazimierczuk
- B. Kupcewicz
- O. Khavryuchenko
- B. Barszcz
- INORGANICA CHIMICA ACTA - Year 2018
Two new lead(II) coordination polymers with isomeric thiophenecarboxylates, namely [Pb(2tpCOO)2]n (1) and [Pb(3tpCOO)2(H2O)]n (2) (2tpCOO− = thiophene-2-carboxylate, 3tpCOO− = thiophene-3-carboxylate), were synthesized and characterized. Single crystal X-ray crystallography revealed a distorted pentagonal pyramidal geometry {PbO6} around Pb in 1 and a distorted dodecahedral geometry {PbO8} in 2. The distortion derived from the...

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