Search results for: R&D SECTOR - Bridge of Knowledge

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Search results for: R&D SECTOR

Search results for: R&D SECTOR

  • Jerzy Proficz dr hab. inż.

    Jerzy Proficz, Ph.D. is the director of the Centre of Informatics – Tricity Academic Supercomputer & networK (CI TASK) at Gdansk University of Technology, Poland. He earned his Ph.D. (2012) in HPC (High Performance Computing) in the subject of supercomputer resource provisioning and management for on-line data processing D.Sc. (2022) in the discipline: Information and Communication Technology. Author and co-author of over 50...

  • Metodologia badania zaworów hamulcowych

    Artykuł opisuje metodologię statycznego i dynamicznego badania zaworów hamulcowych. Stanowisko badawcze zaprojektowano i zbudowano na Politechnice Gdańskiej jako część projektu badawczo-rozwojowego pt.: „Zaprojektowanie i zbadanie innowacyjnych podsystemów ładowarek kołowych firmy Hydro-Metal”, dofinansowanego przez PARP w ramach programu „Bon na innowacje”. Ponadto przedstawiono szczegóły konstrukcyjne i funkcje najczęściej spotykanych zaworów...

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  • Paweł Lubomski dr inż.

    People

    Paweł Lubomski is the director of the IT Services Centre at the Gdańsk University of Technology. He is responsible for developing and maintaining the central information systems of the university. He is also in charge of the R&D team and works on new approaches to IT systems’ protection. He also acts as the project manager of two big innovative IT projects co-financed by the European Funds. He received a PhD degree in computer...

  • Janusz Nieznański prof. dr hab. inż.

    Janusz Nieznański born in 1957 in Gdańsk. He received the M.Sc. degree in 1981, the Ph.D. degree in 1990, and the D.Sc. (‘habilitation’) degree in 1999, all from the Gdańsk University of Technology. Since 1981 he has been with the above university, where he is currently Professor of Electrical Engineering. His research and teaching interests include control, diagnostics, modeling and simulation of power electronic converters and...

  • Mind the Gender Wage Gap – the Impact of Trade and Competition on Sectoral Wage Difference

    Publication

    This article examines differences between women’s and men’s wages in 18 selected OECD countries in the period 1970-2005. The study is based on 12 manufacturing sector- and skill-specific sets of panel data on the gender wage gap. We apply a system GMM estimator to the extended version of the conditional gender wage gap convergence equation, controlling for sector concentration and industry-specific measures of openness using a...

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  • Surface and Trapping Energies as Predictors for the Photocatalytic Degradation of Aromatic Organic Pollutants

    Publication

    - Journal of Physical Chemistry C - Year 2022

    In this study, anatase samples enclosed by the majority of three different crystal facets {0 0 1}, {1 0 0}, and {1 0 1} were successfully synthesized. These materials were further studied toward photocatalytic degradation of phenol and toluene as model organic pollutants in water and gas phases. The obtained results were analyzed concerning their surface structure, reaction type, and surface development. Moreover, the regression...

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  • New kagome prototype materials: discovery of KV3Sb5, RbV3Sb5, and CsV3Sb5

    Publication
    • B. R. Ortiz
    • L. C. Gomes
    • J. R. Morey
    • M. J. Winiarski
    • M. Bordelon
    • J. S. Mangum
    • I. W. H. Oswald
    • J. A. Rodriguez-Rivera
    • J. R. Neilson
    • S. D. Wilson... and 3 others

    - Physical Review Materials - Year 2019

    In this work, we present our discovery and characterization of a new kagome prototype structure, KV3Sb5. We also present the discovery of the isostructural compounds RbV3Sb5 and CsV3Sb5. All materials exhibit a structurally perfect two-dimensional kagome net of vanadium. Density-functional theory calculations indicate that the materials are metallic, with the Fermi level in close proximity to several Dirac points. Powder and single-crystal...

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  • Karol Daliga dr inż.

    In 2005, he graduated from a mathematics and physics class and passed his secondary school-leaving examination at 1st Secondary School named after Władysław Gebik, former Polish grammar school in Kwidzyn. In the years 2005-2010 he completed master's studies at Faculty of Applied Physics and  Mathematics of Gdańsk University of Technology, and in 2008-2012 he completed engineering studies at Faculty of Civil and Environmental Engineering...

  • Hanna Obracht-Prondzyńska dr inż. arch.

    People

    Hanna Obracht-Prondzyńska, PhD MArch, Eng. Assistant Professor at the University of Gdańsk, Department of Spatial Management, academic teacher of urban design and spatial data analyses. Architect and urban planner experienced in data driven urban design and planning. She defended her PhD with distinction in engineering and technical sciences in the discipline of architecture and urban planning in 2020 at the Faculty of Architecture...

  • Marcin Wekwejt dr inż.

    Marcin Wekwejt holds a bachelor’s degree in Biomedical Engineering (2016; J. and J. Śniadecki Bydgoszcz University of Technology & L. Rydygier Collegium Medicum), a master’s degree in Mechanical-Medical Engineering (2018; Gdańsk University of Technology & Gdańsk Medical University), and a PhD in Materials Engineering (2021; Gdańsk University of Technology). He was awarded the title of Doctor of Engineering and Technical...

  • Surface Dielectric Barrier Discharge Plasma Actuators

    Publication
    • E. Moreau
    • A. Debien
    • N. Benard
    • T. N. Jukes
    • R. D. Whalley
    • K. Choi
    • A. Berendt
    • J. Podliński
    • J. Mizeraczyk

    - ERCOFTAC Bulletin - Year 2013

    This paper presents a part of the works conducted in the Plasmaero European project (task 1.1) on surface dielectric barrier discharge actuators applied to airflow control. The study is divided into several parts. In the first part, the goal is to enhance the electric wind produced by a typical single DBD actuator by optimization of the active electrode shape. For instance, the use of a thin wire instead of a plate air-exposed...

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  • Trailing-Edge Separation Control of a NACA 0015 Airfoil Using Dielectric-Barrier-Discharge Plasma Actuators

    Publication
    • R. D. Whalley
    • A. Debien
    • J. Podliński
    • T. N. Jukes
    • K. Choi
    • N. Benard
    • E. Moreau
    • A. Berendt
    • J. Mizeraczyk

    - ERCOFTAC Bulletin - Year 2013

    This paper presents a part of the works conducted in the Plasmaero European project (task 3.1), where the trailing-edge flow separation of a NACA 0015 airfoil has been controlled using four different dielectric barrier discharge (DBD) actuator types at three institutions across Europe. The results show that it is possible to enhance the aerodynamic performance of aircraft at speeds up to 40 m/s. Dielectric-barrier-discharge vortex...

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  • Human Factors in designing the Instrumentation and Control Systems Important to Safety

    This work addresses selected aspects of human factors in designing the instrumentation and control (I&C) systems important to safety as a part of the functional safety management of industrial hazardous plants, in particular nuclear power plants. As it is known in such plants a concept of “defence in depth” (D-in-D) is widely applied and some layers of protection are designed with regard to functional safety (FS) concept given...

  • The possibilities for application of new comminution circuits in order to improve technological indexes of KGHM Polska Miedź S.A. copper ore concentrators = Możliwości zastosowania nowych układów rozdrabniania w aspekcie wskaźników technologicznych w warunkach O/ZWR

    Publication

    - Year 2015

    Artykuł opisuje zagadnienia związane z efektywnością procesu przygotowania urobku do wzbogacania. Przeanalizowano w nim aktualne układy rozdrabniające, oparte o kruszarki młotkowe i młyny prętowe, jak również warianty układów rozdrabniania z aplikacjami najnowszych rozwiązań techniczno – technologicznych tj. wysokociśnieniowej kruszarki walcowej oraz kruszarki stożkowej. Omawiane aspekty oparte są na badaniach prowadzonych...

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  • The selective salinity and hydrazine parameters for the start-up of non-anammox-specific biomass SBR

    Publication
    • I. Zekker
    • E. Rikmann
    • J. Oja
    • S. Anslan
    • A. F. Borzyszkowska
    • A. Zielińska-Jurek
    • R. Kumar
    • L. A. Shah
    • M. Naeem
    • M. Zahoor... and 5 others

    - International Journal of Environmental Science and Technology - Year 2023

    The presence of ammonium (NH 4+ ) in wastewater above the permissible limits leads to undesirable ecological impact and public health concerns. In this study, the anaerobic ammonium oxidizing (anammox) bacteria-mediated nitrogen removal was investigated using a sequential batch reactor (SBR). Effects of different salinity levels were evaluated on the bacterial activity at: mild (below 0.2 g NaCl/L), elevated (18.2 g NaCl/L) and...

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  • Oxygen deficient YBa2Cu3O7-r: two superconducting phases

    Publication

    - ACTA PHYSICA POLONICA A - Year 2004

    Zestaw próbek ceramiki YBa2Cu3O7-r w postaci pudru i granulatupoddawano stopniowemu odtlenianiu i badano za pomocątermograwimetrii oraz absorbcji mikrofalowej. Stosowanie tychmetod pokazało, że występująca faza $Trm_c=60$~K w związkuYBa2Cu3O7-r, powstała poprzez odtlenianie jest niestabilna.

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  • Evaluation of Sicilian landraces of broccoli (B. oleracea var. italica Plenck) for quality traits

    Publication

    - Year 2022

    Brassica oleracea L. var. italica Plenck is one of the most popular vegetables which belong to Brassicaceae family. It is getting attention as an important source of bioactive compounds such as glucosinolates, and many other phytochemicals. In the frame of the H2020 BRESOV project, we evaluated three landraces (‘Broccolo nero', ‘Ramoso calabrese' and ‘Sparaceddu') and two commercial F1 hybrid cultivars (‘Marathon' and ‘Naxos')....

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  • Jan Cudzik dr inż. arch.

    Jan Cudzik (Ph.D. Eng. Arch.) is an assistant professor at the Department of Urban Architecture and Waterside Spaces at the Faculty of Architecture of the Gdańsk University of Technology and the head of the Laboratory of Digital Technologies and Materials of the Future. He is researching kinematic architecture, digital techniques in architectural design, digital fabrication, and forms of artificial intelligence in architecture...

  • Mechanical exfoliation and layer number identification of single crystal monoclinic CrCl3

    Publication
    • S. Kazim
    • M. Alì
    • S. Palleschi
    • G. D’Olimpio
    • D. Mastrippolito
    • A. Politano
    • R. Gunnella
    • A. DiCicco
    • M. Renzelli
    • G. Moccia... and 6 others

    - NANOTECHNOLOGY - Year 2020

    After the recent finding that CrI3, displays ferromagnetic order down to its monolayer, extensive studies have followed to pursue new two-dimensional (2D) magnetic materials. In this article, we report on the growth of single crystal CrCl3 in the layered monoclinic phase. The system after mechanical exfoliation exhibits stability in ambient air (the degradation occurs on a time scale at least four orders of magnitude longer than...

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  • Joanna Raczek dr inż.

    Employment 2003 -- 2019: Faculty of Applied Physics and Mathematics, Gdańsk University of Technology. 2019 - present: Faculty of Electronic, Informatics and Telecominications, Gdańsk University of Technology. Education May 2007: Doctor of Philosophy in Mathematics, University of Gdańsk. Doctoral dissertation: "Paired domination and doubly domination in graphs". Supervisor: dr hab. Jerzy Topp. 2000 -- 2004 Bachelor of Science...

  • Metoda prognozowania mocy skrawania przy przecinaniu piłami polskiego drewna sosnowego z uwzględnieniem wiązkości materiału obrabianego

    Publication

    - Year 2016

    W pracy zostały przedstawione wartości właściwości materiałowych tj.: wiązkość R oraz naprężenia tnące w strefie skrawania τy, dla drewna sosnowego (Pinus sylvestris L.). Badane próbki drewna pochodziły z czterech Krain Przyrodniczo - Leśnych Polski: Bałtyckiej Krainy Przyrodniczo - Leśnej (kraina A), Karpackiej Krainy Przyrodniczo - Leśnej (kraina B), Małopolskiej Krainy Przyrodniczo - Leśnej (kraina C) oraz Wielkopolsko - Pomorskiej...

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  • Krzysztof Smykała mgr inż.

    People

  • Polylysine for Skin Regeneration: A Review of Recent Advances and Perspectives

    Publication
    • P. Zarrintaj
    • S. Ghorbani
    • M. Barani
    • N. P. Singh Chauhan
    • M. Khodadadi Yazdi
    • M. Saeb
    • J. D. Ramsey
    • M. R. Hamblin
    • M. Mozafari
    • E. Mostafavi

    - Bioengineering & Translational Medicine - Year 2022

    There have been several attempts to find promising biomaterials for skin regeneration, among which polylysine (a homopolypeptide) has shown benefits in the regeneration and treatment of skin disorders. This class of biomaterials has shown exceptional abilities due to their macromolecular structure. Polylysine-based biomaterials can not only be used as tissue engineering scaffolds for skin regeneration, but also as drug carriers...

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  • Mirosław Andrusiewicz prof. dr hab. n. med. i n. o zdr.

    People

    Diplomas, degrees conferred in specific areas  ̶    Post-doctoral degree in medical sciences (doctor habilitated) (discipline: medical biology) December 4, 2017; Title of academic achievement: "Analysis of selected genes involved in the control of pathological changes in cells derived from internal female reproductive organs"; Poznan University of Medical Sciences, Faculty of Medicine II; re-viewers: Prof. Katarzyna Ziemnicka,...

  • The Conference Report of Why R? Turkey 2022: The First R Conference with Call For Papers in Turkey

    Publication
    • M. Cavus
    • O. Aydin
    • O. Evkaya
    • D. Turfan
    • F. Karadag
    • O. Ozdemir
    • U. Dar
    • D. Bezer

    - R Journal - Year 2022

    Why R? Turkey 2022 was a non-profit conference that aimed to bring Turkish R users together and encourage them to attend the R conferences. The targeted audience of the conference consisted of, data scientists, data analysts, and all R users from academia and industry. The three-day conference, which consisted of several events such as workshops, regular talks, lightning talks, short tutorials, and panels, was free of charge and...

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  • Degree of T-equivariant maps in R^n

    W pracy przedstawiona jest konstrukcja niezmienniczego stopnia topologicznego dla odwzorowań z symetriami działających na przestrzeni euklidesowej z inwolucją. Udowodnione jest twierdzenie, że dwa dopuszczalne i gradientowe odwzorowania niezmiennicze są niezmienniczo homotopijne wtedy i tylko wtedy, gdy są one homotopijne niezmienniczo i gradientowo.

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  • Fixed point indices of iterations of C^1 maps in R^3

    Publication

    - DISCRETE AND CONTINUOUS DYNAMICAL SYSTEMS - Year 2006

    W przypadku gładkiego odwzorowania w R^3 dowiedziona została hipoteza Chowa, Malleta-Pareta i Yorka dotycząca postaci ciągów indeksow iteracji oraz podano kompletny opis możliwych ciągów indeksow.

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  • Structure-activity relationship studies on the antimicrobial activity of novel edeine a and d analogues

    Opisano syntezę 4 nowych analogów peptydowego antybiotyku, edeiny a i d z wykorzystaniem klasycznej syntezy w roztworze. Stosowano metodę estrów aktywnych oraz metodę azydową do tworzenia wiązań peptydowych. Zbadano także aktywność przeciwgrzybową i przeciwbakteryjną opisanych połączeń.

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  • Characterization of d-xylose reductase, XyrB, from Aspergillus niger

    Publication
    • A. Terebieniec
    • T. Chroumpi
    • A. Dilokpimol
    • M. V. Aguilar-Pontes
    • M. R. Mäkelä
    • R. de Vries

    - Biotechnology Reports - Year 2021

    D-xylose reductase is a member of the aldo-keto reductase family, and is involved in D-xylose and L-arabinose conversion through the Pentose Catabolic Pathway (PCP) in fungi. In this study, we biochemically characterized a newly identified second D-xylose reductase (XyrB) from Aspergillus niger. This NADPH-dependent reductase is able to efficiently convert D-xylose and L-arabinose, and it has the highest affinity for these sugars...

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  • Energy policy and the role of bioenergy in Poland

    Publication

    - ENERGY POLICY - Year 2006

    Przedstawiono sytuacje energetyczną kraju. Omówiono poszczególne sektory wytwarzania energii oraz zapotrzebowania na energię i paliwa. Omówiono przekształcenia sektorów energetycznych w Polsce na przestrzeni lat 1990-2002. Na tym tle przedstawiono techniczne, ekonomiczne, społeczne i prawne aspekty rozwoju energetyki źródeł odnawialnych a w szczególności opartych o bioenergię. Przedstawiono wnioski dla Polski płynące z dotychczasowych...

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  • Iwona Nowakowska dr

    People

    Assistant Professor at The Maria Grzegorzewska University Institute of Psychology. Graduate of Psychology (University of Warsaw, 2019), and PhD in this field (Maria Grzegorzewska University, 2022). Conducted research in the fields of: social and clinical psychology and individual differences. Her current research activity concentrates on prosociality (volunteering, philanthropy, socially responsible behaviors) and their correlates. She...

  • Jakub Kruszyński mgr. inż

    People

    Motivated and focused to steady discovering amazing chemistry of polymer and cooperating with fascinating people. Currently PhD student in cooperation between SABIC B.V and Gdansk University of Technology. I have 3 year industrial experience. Mainly as a R&D Junior Specialist in Synthos S.A and intern in SABIC Technology&Innovation Center, Geleen. Graduate of Gdansk University of Technology in Polymer Specialization on...

  • Emilia Miszewska dr inż.

    Emilia Miszewska was born in 1986 in Gdańsk. She graduated from Primary School No. 17 in Gdańsk with sports classes specializing in swimming and Janusz Kusociński Sports Secondary School No. 11 in Gdańsk. In 2005, she started uniform master's studies at the Faculty of Civil and Environmental Engineering, which she completed in 2011, defending her diploma thesis entitled "Analysis and development of fire protection guidelines and...

  • Sklepy typu pop-up – od Guerilla Stores marki Comme de Garcons przez unikalne doświadczenie zakupowe Bikini Berlin do ... ?

    Obiekty, sklepy typu pop- up pojawiały się w miastach ponad dziesięć lat temu. Otwierane są na krótki okres czasu w celu promocji marki i nawiązania bezp o- średniego kontaktu z odbiorcą. Pop -up’y różnią się od tradycyjnych, stacjona r- nych sklepów rodzajem prowadzonej w nich działalności, mającym na celu przede wszystkim promocję marki. Pierwsze tymczasowe obiekty, tzw. Guerilla stores , stworzone zostały w 2004 roku...

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  • A novel nucleotide found in human erythrocytes, 4-pyridone-3-carboxamide-1-beta-D-ribonucleoside triphosphate

    Publication
    • E. M. Słomińska
    • E. A. Carrey
    • H. Foks
    • C. Orlewska
    • E. Wieczerzak
    • P. Sowiński
    • M. H. Yacoub
    • A. M. Marinaki
    • A. H. Simmonds
    • R. T. Smoleński

    - JOURNAL OF BIOLOGICAL CHEMISTRY - Year 2006

    Zidentyfikowano nowy, nieznany nukleotyd, występujący w erytrocytach osób chorych na przewlekłą niewydolność nerek, w stężeniu porównywalnym do zawartości ATP. Nukleotyd ten wyizolowano chromatograficznie, a jego strukturę określono jako trójfosforan 4-piridono-3-karboksyamido-1-b-D-rybonukleozydu, na podstawie danych spektralnych UV, MS, IR i NMR.

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  • Andrzej Czyżewski prof. dr hab. inż.

    Prof. zw. dr hab. inż. Andrzej Czyżewski jest absolwentem Wydziału Elektroniki PG (studia magisterskie ukończył w 1982 r.). Pracę doktorską na temat związany z dźwiękiem cyfrowym obronił z wyróżnieniem na Wydziale Elektroniki PG w roku 1987. W 1992 r. przedstawił rozprawę habilitacyjną pt.: „Cyfrowe operacje na sygnałach fonicznych”. Jego kolokwium habilitacyjne zostało przyjęte jednomyślnie w czerwcu 1992 r. w Akademii Górniczo-Hutniczej...

  • Cybersecurity in the Electricity Sector

    Publication

    - Year 2019

    This book offers a systematic explanation of cybersecurity protection of electricity supply facilities, including discussion of related costs, relevant standards, and recent solutions. The author explains the current state of cybersecurity in the electricity market, and cybersecurity standards that apply in that sector. He then offers a systematic approach to cybersecurity management, including new methods of cybersecurity assessment,...

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  • Bartosz Rybacki

    People

    A scientist, engineer, graduate of molecular biotechnology, R&D of the Stardust project, coordinator of the AMBER rocket project, member of the Polish Astrobiological Society, Polish Rocketry Association, Innspace Team and PTAstrobio Working Group. Employee of the Blirt S.A..  Ad Astra!

  • PROMARC Promoting Maritime Research Careers

    Projects

    Project manager: dr inż. Tadeusz Borzęcki   Financial Program Name: 7 PROGRAM RAMOWY UE

    Project realized in Faculty of Ocean Engineering and Ship Technology according to 218590 agreement from 2008-12-18

  • Third sector characteristics and importance

    This article aims to present a brief overview of existing definitions and specific characteristics of the third sector. It also highlights the basic functions of NGOs as an important institutional and organizational actor in the global political and economic landscape.

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  • Statistics with R A Handbook for Statistical Analysis with R and R-Studio

    Publication

    - Year 2022

    If you are to perform any kind of data (statistical) analysis and use tools in the data science ecosystem, you may have seen a variety of tutorials, handbooks online (I’m not mentioning traditional bibles of statistics). Unfortunately most of them is written intentionally for specific purposes and/or target group of people and does not include many aspects, data types, difficult aspects, usually hiding them trying to solve theoretical...

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  • The Third Sector in the Universities’ Third Mission

    Publication

    - Year 2017

    The interactions between the today’s university and its environment, as part of the university’s social responsibility, have been subject to many scientific papers. Their authors typically focus on interdependencies between universities, the state and the market. What is lacking are publications related to the interactions between universities and third sector organisations, and more broadly – a civil society, that may play an...

  • A sector-an industry? Definitional challenges in economic sciences

    Publication

    - Year 2010

    the aim of our paper is to present definitional challenges that we as scholars and teachers face while attempting to relate to a sector and an industry terms in economic analyses and from strategic management perspective. we employ secondary research and analyse the state of the academic discourse and common usages of the above terms. we argue that for an economic statistician classifications should be consistent and highlight...

  • EUROPEAN PHYSICAL JOURNAL D

    Journals

    ISSN: 1434-6060 , eISSN: 1434-6079

  • A new B-D-galactosidase with a low temperature optimum isolated from the Antarctic Arthrobacter sp. 20B: gene cloning, purification and characterization.

    Publication

    - ARCHIVES OF MICROBIOLOGY - Year 2009

    A psychrotrophic bacterium producing a coldadaptedB-galactosidase upon growth at low temperatureswas classiWed as Arthrobacter sp. 20B. A genomic DNAlibrary of strain 20B introduced into Escherichia coliTOP10F' and screening on X-Gal (5-bromo-4-chloro-3-indolyl-B-D-galactopyranoside)-containing agar plates ledto the isolation of B-galactosidase gene. The B-galactosidasegene (bgaS) encoding a protein of 1,053 amino acids,with a...

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  • The dynamics of the total output of the fishery sector: The case of Indonesia

    Publication

    - Year 2016

    The purpose of this study is to analyze the dynamics of the total output of the Indonesian fishery industry when the changes of the final demand occur. This study employs a demand-pull Input-Output (IO) quantity model, one of the calculation tools in the IO analysis, as an analysis instrument. Two conditions are noticed in calculation and analysis parts, namely (1) “whole sector change”, and (2) “pure change”. An initial period...

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  • Romanika Okraszewska dr inż. arch.

    Romanika Okraszewska, Ph.D., Eng. Arch., is an Assistant Professor at the Faculty of Civil and Environmental Engineering of Gdańsk University of Technology (GUT). Graduated from the mathematical and informatical class at the National Education Commission High School in Gdańsk. Graduated from two faculties of Gdańsk University of Technology, Architecture and Urban Planning (2002) and Management and Economics (2004). Participant...

  • Stefan Niewitecki dr inż. arch.

    People

    W dniu 29.07.1977 r. ukończenie Studium Podyplomowego Kształcenia Pedagogicznego Nauczycieli Akademickich (świadectwo Nr 301, wynik dobry). Dnia 29.04.1982 r. nagroda III stopnia Rektora Politechniki  Gdańskiej, zespołowa za ''Studium wpływu ujęcia wody Gdańsk-Lipce na stateczność obiektów budowlanych w rejonie leja depresyjnego.'' W 1986 r. nagroda Rektora Politechniki Gdańskiej za ''Orzeczenie i projekt techniczny wzmocnienia...

  • The stereostructure of candicidin D.

    The candicidin D stereostructure was established based on NMR studies including DQF-COSY, ROESY, HSQC and HMBC experiments. The relative configurations of the candicidin D stereogenic centers were assigned as the following: 9R*, 11S*, 13S*, 15R*, 17S*, 18R*, 19S*, 21R*, 36S*, 37R*, 38S*, 40S* and 41S*. The geometry of the heptaene chromophore was defined as 22E, 24E, 26Z, 28Z, 30E, 32E and 34E.

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  • Syntheses and crystal structures of lithium derivatives of diphosphanes R2P-P(SiMe3)Li·3L, R = Ph, iPr and iPr2N, L = THF or DME

    Publication

    - POLYHEDRON - Year 2007

    W wyniku reakcji R2P-P(SiMe3)2 z BuLi w THF lub DME powstają pochodne litowe difosfanów R2P-P(SiMe3)Li·3L. Dla R = iPr oraz iPr2N powstają sole R2P-P(SiMe3)Li·3THF, w których atom litu jest czterokrotnie koordynowany a dla R = Ph powstaje sól [Li·3DME]+[Ph2P-PSiMe3]-, która posiada budowę jonową. W reakcji BuLi z Ph2P-P(SiMe3)2 powstają znaczne ilości produktów ubocznych: Ph2P-PPh2 i LiP(SiMe3)2.

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