Search results for: chromatography
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Three-step stacking by field-enhanced sample injection, sweeping, and micelle to solvent stacking in capillary electrophoresis: Anionic analytes
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Three-step stacking of cationic analytes by field-enhanced sample injection, sweeping, and micelle to solvent stacking in capillary electrophoresis
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Chromatographic behaviour of ionic liquid cations in view of quantitative structure-retention relationship
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Determination of pyridine and adenine nucleotide metabolites in Bacillus subtilis cell extract by sweeping borate complexation capillary electrophoresis
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Analysis of carboxylic acid metabolites from the tricarboxylic acid cycle in Bacillus subtilis cell extract by capillary electrophoresis using an indirect photometric detection method
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Preparation and evaluation of solid-phase microextraction fibres based on functionalized latex nanoparticle coatings for trace analysis of inorganic anions
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Sputtered silicon solid phase microextraction fibers with a polydimethylsiloxane stationary phase with negligible carry-over and phase bleed
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Open tubular trapping - present and future prospects
PublicationOtwarte pułapki kapilarne posiadają pewne unikalne właściwości, które ułatwiają ich zastosowanie zarówno w analizie próbek gazowych jak i wodnych - na przykład niskie opory przepływu umożliwiają ich bezpośrednie połączenie z większością technik rozdzielania chromatograficznego. W pracy opisano etapu rozwoju OTT na przestrzeni ostatnich kilkunastu lat, ze szczególnym uwzględnieniem aspektów technologii ich wytwarzania oraz sposobów...
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Matrix effects and recovery calculations in analyses of pharmaceuticals based on the determination of β-blockers and β-agonists in environmental samples
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Recent developments and future trends in solid phase microextraction techniques towards green analytical chemistry
PublicationSolid phase microextraction find increasing applications in the sample preparation step before chromatographic determination of analytes in samples with a complex composition. These techniques allow for integrating several operations, such as sample collection, extraction, analyte enrichment above the detection limit of a given measuring instrument and the isolation of analytes from sample matrix. In this work the information about...
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Coacervative extraction as a green technique for sample preparation for the analysis of organic compounds
PublicationOne of the present trends in analytical chemistry is miniaturization, which is one of the methods of green analytical chemistry application. A particular emphasis is placed on the elimination of the use of large amounts of organic solvents which are toxic and harmful to the environment, maintaining high efficiency of the extraction process, high recovery values and low values of quantification (LOQ) and detection (LOD) limits....
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Multicriteria decision analysis in ranking of analytical procedures for aldrin determination in water
PublicationThe study presents the possibility of multi-criteria decision analysis (MCDA) application when choosing analytical procedures with low environmental impact. A type of MCDA, Preference Ranking Organization Method for Enrichment Evaluations (PROMETHEE), was chosen as versatile tool that meets all the analytical chemists – decision makers requirements. Twenty five analytical procedures for aldrin determination in water samples (as...
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Application of multicriteria decision analysis in solvent type optimization for chlorophenols determination with a dispersive liquid–liquid microextraction
PublicationThis study presents a novel support tool for the optimization and development of analytical methods. The tool is based on multi-criteria decision analysis (MCDA), namely the Technique for Order of Preference by Similarity to the Ideal Solution (TOPSIS), that allows users to rank possible solutions according to their requirements. In this study, we performed rankings of pairs of eight extraction and three dispersive solvents used...
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Multivariate assessment of anticancer oleanane triterpenoids lipophilicity
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Implementation of multicriteria decision analysis in design of experiment for dispersive liquid-liquid microextraction optimization for chlorophenols determination
PublicationA novel and efficient approach to optimization of extraction step prior the chromatographic determination of nine chlorinated phenols is described. It is based on the combination of design of experiments and multicriteria decision analysis. Such an approach is used to optimize dispersive liquid-liquid microextraction procedure for the determination of 9 chlorophenols in water samples. Three parameters are optimized – sample volume,...
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Sample preparation procedure using extraction and derivatization of carboxylic acids from aqueous samples by means of deep eutectic solvents for gas chromatographic-mass spectrometric analysis
PublicationThe paper presents a new procedure for the determination of organic acids in a complex aqueous matrixusing ultrasound-assisted dispersive liquid–liquid microextraction followed by injection port derivati-zation and GC–MS analysis. A deep eutectic solvent (choline chloride: 4-methylphenol in a 1:2 mol ratio)was used both as an extracting solvent and as a derivatizing agent to yield ion pairs which were next con-verted to methyl...
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Determination of polybrominated diphenyl ethers (PBDEs) in dust samples collected in air conditioning filters of different usage – method development
PublicationThis study presents the results of studies aimed at the development of an analytical procedure for separation, identification, and determination of PBDEs compounds in dust samples collected from automotive cabin air filters and samples collected from filters installed as part of the air purification system in academic facilities. Ultrasound-assisted dispersive solid phase extraction (UA-dSPE) was found to perform better in terms...
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Chromatographic lipophilicity determination using large volume injections of the solvents non-miscible with the mobile phase
PublicationA new perspective in the lipophilicity evaluation through RP-HPLC is permitted by analysis of the retentionfactor (k) obtained by injecting large volumes of test samples prepared in solvents immiscible withmobile phase. The experiment is carried out on representative groups of compounds with increasedtoxicity (mycotoxins and alkaloids) and amines with important biological activity (naturally occurringmonoamine compounds and related...
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Determination of thiocyanate as a biomarker of tobacco smoke constituents in selected biological materials of human origin
Publicationn order to protect human health, it is necessary to biomonitor toxic substances originating from tobacco smoke in biological materials sampled from persons with different exposures to tobacco smoke constituents. Thiocyanate anion is a biomarker of exposure to tobacco smoke components which is characterized by a relatively long half‐life in the human body, i.e. 6 days. In this work, we present the results of thiocyanate determinations...
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Using different types of capillary columns as denudation traps: a comparision of sorption properties
PublicationOpisano badania odcinków kapilarnych kolumn chromatograficznych (WCOT, SCOT,PLOT) jako pułapek denudacyjnych do ilościowego zatrzymywania śladowych ilości lotnych związków organicznych ze strumienia powietrza. W trakcie badań modelowych (z wykorzystaniem gazowych mieszanin wzorcowych) określono wartości współczynników podziału benzenu, toluenu, etylobenzenu, o-ksylenu i chlorobenzenu (Kfs). Stwierdzono, że grubość filmu fazy stacjonarnej...
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Evaluation of headspace solid-phase microextraction for the analysis of volatile carbonyl compounds in spirits and alcoholic beverages
PublicationOpracowano metodę oznaczania C1-C6 związków karbonylowych w układzie GC-ECD w roztworach alkoholowych poprzez derywatyzację pentafluorobenzylohydroksy-aminą i mikroekstrakcję w fazie stacjonarnej z fazy nadpowierzchniowej. Zoptymalizowano warunki eksperymantalne: zawartość alkoholu, czas ekspozycji, temperaturę i sposób mieszania próbki. W metodzie tej najpierw przeprowadza się rozcieńczenie spirytusu lub napojów alkoholowych do...
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Solid phase extraction clean up of soil and sediment extracts for the determination of various types of pollutants in a single run.
PublicationOpisano nową procedurę oczyszczania ekstraktów rozpuszczalnikowych (uzyskanych w trakcie obróbki próbek gleby i osadów dennych) z wykorzystaniem techniki ekstrakcji do fazy stałej. Oryginalność podejścia polega na znalezieniu takiej kombinacji sorbentów, że uzyskuje się ekstrakt przygotowany do analizy chromatograficznej na zawartość różnych typów zanieczyszczeń (polichlorowane bifenyle, wielopierścieniowe węglowodory aromatyczne,...
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Determination of the amount of wash amines and ammonium ion in desulfurization products of process gases and results of related studies
PublicationPrzedstawiono metodę oznaczania tzw. amin myjących i ich produktów degradacji, włączając jon amonowy w wodach procesowych i ściekach wytwarzanych podczas odsiarczania gazów. W procesach rafinacji ropy naftowej zastosowano jonowymienną chromatografię cieczową z detektorem refraktometrycznym oraz tanią kationowymienną kolumnę HPLC. Otrzymane wyniki oznaczeń porównano z wynikami uzyskanymi przez miareczkowanie potencjometryczne....
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Miniaturised analytical procedure of determining polycyclic aromatic hydrocarbons and polychlorinated biphenyls in bottom sediments
PublicationOpisano metodę oznaczania bardzo niskich stężeń polichlorowanych bifenyli w obecności wysokich zawartości wielopierścieniowych węglowodorów aromatycznych. Analizie techniką GC-MS poddawany jest ekstrakt z 1 g próbki osadu. Jako standardy wewnętrzne zastosowano Naftalen-d8, benzo[a]antracen-d12 i PCB 209. Średni odzysk standardów przedstawiał się następująco: 65, 55 i 60% odpowiednio. Do izolacji frakcji PCB stosowano niekomercyjne...
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New procedure of silica gel surface modification. Preparation of gaseousstandard mixtures for calibration purposes.
PublicationPrzedstawiono nową procedurę modyfikacji powierzchni żelu krzemionkowego z wykorzystaniem trimetyloaminy jako odczynnika. Próbki chemiczne modyfikowanego nośnika zostały wykorzystane do sporządzenia gazowych mieszanin wzorcowych (chlorek metylu jako składnik mierzony) techniką termicznego rozkładu związków powierzchniowych. Głównym celem badań było sprawdzenia przydatności nowej procedury modyfikacji powierzchni żelu do...
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Application of the chromatographic retention index system for theestimation of the calibration constants of permeation passivesamplers with polydimethylsiloxane membranes
PublicationW pracy przedstawiono wyniki badań z zastosowaniem pasywnych dozymetrów typu permeacyjnego, wyposażonych w membrany wykonane z PDMS. Badania dotyczyły oszacowania wartości stałych kalibracyjnych dozymetrów przy wykorzystaniu systemu indeksów retencji, wyznaczanych chromatograficznie, w warunkach liniowego narostu temperatury pracy kolumny (LTPRI). Znaleziono korelację pomiędzy wartościami stałych kalibracyjnych próbników typu pasywnego,...
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Human bone marrow as a tissue in post-mortem identification and determination of psychoactive Substances—Screening methodology
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Ultra-high performance liquid chromatographic determination of levofloxacin in human plasma and prostate tissue with use of experimental design optimization procedures
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Development and validation of GC–MS/MS method useful in diagnosing intestinal dysbiosis
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Influence of the extraction mode on the yield of some furanocoumarins from Pastinaca sativa fruits
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Chemometric approach to correlations between retention parameters of non-polar HPLC columns and physicochemical characteristics for ampholytic substances of biological and pharmaceutical relevance
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Multiplatform metabolomics provides insight into the molecular basis of chronic kidney disease
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Sample preparation procedures utilized in microbial metabolomics: An overview
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Environmental Fate of Two Psychiatric Drugs, Diazepam and Sertraline: Phototransformation and Investigation of their Photoproducts in Natural Waters
PublicationExperimental studies were conducted to investigate the photodegradation of diazepam and sertraline, two of the most frequently used psychiatric drugs, induced by xenon lamp irradiation, which overlap the sunlight spectra, and natural sunlight. Degradation kinetics was established indicating the occurrence of autocatalytic reactions. The application of liquid chromatography coupled to quadrupole time-of-flight mass spectrometry...
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Extraction Methods of 10-Deacetylbaccatin III, Paclitaxel, and Cephalomannine from Taxus baccata L. Twigs: A Comparison
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Application of Sea Sand Disruption Method for HPLC Determination of Quercetin in Plants
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Optimization of ASE Conditions for the HPLC Determination of Rutin and Isoquercitrin inSambucus nigraL
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Retention modeling of some saccharides separated on an amino column.
PublicationUsing an amino column (Supelcosil LC-NH2) and different mixtures of acetonitrile-water, quantitative structure-retention relationship models are discussed. These models are based on computed molecular descriptors representing numerically structured features of some saccharides. The obtained results are underlining the lipophilicity/hydrophilicity balance, and how this is controlling the separation of the saccharides. The resulting...
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Study of the chromatographic behavior of selected steroid hormones on aluminum oxide plates based on quantitative structure-retention relationships
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Chemical fingerprint ofPotentillaspecies by using HPTLC method
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Identification of novel psychoactive substances 25B-NBOMe and 4-CMC in biological material using HPLC-Q-TOF-MS and their quantification in blood using UPLC–MS/MS in case of severe intoxications
PublicationThis paper describes cases of poisoning caused by new psychoactive substances such as: 25BNBOMe (2-(4-bromo-2,5-dimethoxyphenyl)-N-[(2-methoxyphenyl)methyl]ethanamine) and 4-CMC (1-(4-chlorophenyl)-2-(methylamino)-1-propanone). The analytical procedure includes rapid and selective method for the extraction and determination of 4-CMC and 25B-NBOMe in blood samples using UPLC–MS/MS technique. To the best of our knowledge,this is...
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Separation and determination of the group-type composition of modern base and lubricating oils with a wide range of polarity, especially emitted to the environment
PublicationLubricating oils are composed of base oils (>85% v/v) and enriching additives (<15% v/v). Three types of base oils may be distinguished: 1) traditional bases (obtained by low-volatile fractions from crude oil distillation refining), 2) synthetic bases (mainly poly-alpha-olefins, sometimes esters, especially succinic acid esters), 3) bases of natural origin (especially obtained from refined plant oils). The bases of natural origin...
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Modern approach for determination of lactulose, mannitol and sucrose in human urine using HPLC-MS/MS for the studies of intestinal and upper digestive tract permeability
PublicationA new analytical procedure was described for the simultaneous determination of lactulose, mannitol and sucrose in urine, in which HILIC chromatography and tandem mass spectrometry detection are used. Sugars are orally administered for the estimation of intestinal permeability in children digestive tract. Samples were purified by dispersive solid phase extraction (d-SPE) using Amberlite MB150 resin. Raffinose was selected as an...
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Measurement of plasma 25-hydroxyvitamin D2, 25-hydroxyvitamin D3 and 3-epi-25-hydroxyvitamin D3 in population of patients with cardiovascular disease by UPLC-MS/MS method
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Effective phospholipid removal from plasma samples by solid phase extraction with the use of copper (II) modified silica gel cartridges
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Validated HPTLC method for determination of ledol and alloaromadendrene in the essential oil fractions of Rhododendron tomentosum plants and in vitro cultures and bioautography for their activity screening
PublicationRhododendron tomentosum (Ledum palustre) is a bog shrub used in traditional medicine for treatment of respiratory and rheumatic diseases. Due to the large variability of the chemical composition of its essential oil, depending on the habitat, the in vitro cultures were established as the alternative source of the volatile fraction. There is a need to monitor a quality of the field grown as well as in vitro plant material, especially...
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A magnetic stir bar sorbent of metal organic frameworks, carbon foam decorated zinc oxide and cryogel to enrich and extract parabens and bisphenols from food samples
PublicationA porous composite magnetic stir bar adsorbent was fabricated for the extraction and enrichment of parabens and bisphenols from selected beverage samples. The adsorbent comprised a metal organic framework, carbon foam decorated zinc oxide and magnetic nanoparticles embedded in polyvinyl alcohol cryogel. The porous composite stir bar adsorbent could adsorb parabens and bisphenols via hydrogen bonding, π-π and hydrophobic interactions....
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Determination of the content of saccharides and ethanol in samples of fermented beverages
Open Research DataThe data set presents the results of measurements of the content of mono- and disaccharides: glucose, maltose, fructose and ethanol in samples of beverages fermented by high performance liquid chromatography (HPLC-RID).
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Iwona Hołowacz dr inż.
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Zdzisław Kowalczuk prof. dr hab. inż.
PeopleZdzislaw Kowalczuk received his M.Sc. degree in 1978 and Ph.D. degree in 1986, both in Automatic Control from Technical University of Gdańsk (TUG), Gdańsk, Poland. In 1993 he received his D.Sc. degree (Dr Habilitus) in Automatic Control from Silesian Technical University, Gliwice, Poland, and the title of Professor from the President of Poland in 2003. Since 1978 he has been with Faculty of Electronics, Telecommunications and Informatics...