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Search results for: NONIONIC SURFACTANTS
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Aggregation of nonionic surfactants in imidazolium ionic liquids
PublicationMicellar aggregation of surfactants in aqueous solutions has been described in terms of the balance between dispersive interactions of the hydrocarbon part of the amphiphilic molecule, and the hydration and electrostatic repulsive effects of hydrophilic head group. Changing the interactions by replacing water with another polar solvent, such as amides or glycols, has been studied to a smaller extent (Singh, Saleem et al. 1980;...
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Studies on micellar aggregation of nonionic surfactants in imidazolium liquids
PublicationA number of imidazolium ionic liquids, with 2-8 carbon atoms in cation alkyl chains, and tetrafluoroborate, hexafluorophosphate, bis(trifluoromethylsulfony)imide and trifluoromethanesulfonate anions, were characterized for their ability to support micellar aggregation of nonionic surfactants in binary solutions.
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Solubilization of tetrachloroethylene and dichlorobenzene in micellar solutions of nonionic surfactants
PublicationZbadano solubilizację tetrachloroetylenu i dichlorobenzenu w roztworach surfaktantów niejonowych (oksyetylenowanych alkoholi tłuszczowych i alkilofenoli). Określono wpływ HLB badanych związków powierzchniowo czynnych na efektywność solubilizacji zanieczyszczeń organicznych. Największą efektywność solubilizacji tetrachloroetylenu zaobserwowano dla Rokafenolu N8. W przypadku dichlorobenzenu solubilizacja przebiegała najefektywniej...
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Chapter 18. Emulsifying properties of nonionic surfactants in the context of soil remediation
PublicationPowstające podczas remediacji gruntów emulsje są niekorzystne, gdyż mogą prowadzić do zatykania porów i unieruchomienia strumienia cieczy przemywającej. Czyni to proces przemywania nieefektywnym. Zbadano stabilność emulsji trzech olejów mineralnych i jednego syntetycznego (PAO 6). W badaniach wykorzystano aparat Turbiscan TLab Expert. Stabilność emulsji określono jako zależność delty transmisji od czasu. Spośród przebadanych emulsji...
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Water Solubilization Using Nonionic Surfactants from Renewable Sources in Microemulsion Systems
PublicationIn this study the effect of temperature, NaCl andoils (hydrocarbons: C8-C16) on the formation and solubilizationcapacity of the systems of oil/monoacylglycerols(MAG):ethoxylated fatty alcohols (CEO20)/propylene glycol(PG)/water was investigated. The effects of the surfactantmixture on the phase behavior and the concentration ofwater or oil in the systems were studied at three temperatures(50, 55, 60 C) and with varied NaCl solutions...
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Kinetics and thermodynamics of the reaction of iminodiacetate copper(II) complexes with 1,10-phenanthroline and 2,2′-bipyridine in aqueous, anionic, cationic and nonionic surfactants solutions
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SmallAngle Neutron Scattering Study of the Structure of Mixed Micellar Solutions Based on Nonionic and Two Cationic Surfactants
PublicationThe aggregation in mixed water systems based on nonionic surfactant, i.e., heptaethylene glycol monotetradecyl ether (C14E7), and cationic surfactants, i.e., cetyltrimethylammonium bromide (CTAB), and cetyltrimethylammonium chloride (CTAC) has been investigated using the smallangle neutron scattering method. The preliminary results of the study of the behavior of C14E7 aqueous solutions (for a concentration of 0.17%) when adding...
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Synergistic effects in micellization and surface tension reduction in nonionic gemini S-10 and cationic RTAB surfactants mixtures
PublicationMixtures of nonionic gemini surfactant S-10 (α,α′-[2,4,7,9-tetrametyl-5-decyne-4,7-diyl]bis[ω-hydroxy -polioxyetylene] with cationic alkyltrimethylammonium bromides of different alkyl chain length (RTAB) were investigated. Basing on surface tension measurements the cmc values and other adsorption parameters were found. The Clint, Rubing’s and Rosen theories were applied for evaluation of the synergistic effects in mixed films and...
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The effect of alkyl chain length on synergistic effects in micellization and surface tension reduction in nonionic gemini (S-10) and anionic surfactants mixtures
PublicationMixtures of nonionic gemini surfactant S-10 ( α, α'-[2,4,7,9-tetrametyl-5-decyne-4,7-diyl]bis[ω-hydroxy -polioxyetylene] with anionic SRS (sodium alkylsulfates) and SRSO3 (sodium alkylsulfonates) of different alkyl chain length (from 10 to 14 carbon atoms) were investigated. Surface tension measurements were used to find the cmc values and other adsorption parameters. The Clint, Rubingh’s and Rosen theories were applied for evaluation...
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Similar concentration of surfactants in rural and urban areas
PublicationSince surfactants are used in various products, they end up in surface and wastewater. Surfactants may therefore impact ecosystems and living organisms. Actually, only few anionic surfactants and some alkylphenols are regulated. There is no comprehensive evaluation of surfactants in the atmosphere, surfaces and waters of areas of increasing anthropic levels. Here, we measured the levels of cationic, anionic and nonionic surfactants...
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The effect of surfactants mixtures composition on wetting of different solid materials
PublicationThe wetting properties of surfactants mixtures were investigated. Three types of compounds were used: nonionic gemini α, α'-[2,4,7,9-tetramethyl-5-decyne-4,7-diyl]bis[ω-hydroxyl-olioxyethylene] (S-10), anionic sodium dodecyl sulphates (SDS) and cationic dodecyl trimethyl ammonium bromide (DTAB). The materials used in wetting experiments were steel and methyl polymethacrylate. These materials differ...
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Oil removal from polluted soil by washing with surfactants solutions in dynamic conditions
PublicationFor washing of the oil from polluted soil surfactants solutions were applied. In a research a nonionic synthetic surfactant - polyoxyethylene ether of synthetic fatty alcohol (Rokanol NL6), rhamnolipid biosurfactant JBR 425 (Jeneil Biosurfactant Co. LLC) and their mixtures were used. Results of oil removal from peat soil and sand with mixtures of surfactants solutions at concentration 0,5 g/dm...
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One-Step Synthesis of W/O and O/W Emulsifiers in the Presence of Surface Active Agents
PublicationThe main goal of this study was to describe the method of the synthesis of the dodecyl-, tetradecyl-, hexadecyl- and octadecyl-propylene glycol emulsifiers in the presence of selected anionic and nonionic surfactants. Acyl propylene glycol emulsifiers were produced by esterification of propane-1,2-diol (propylene glycol, PG) with C12:0-C18:0 fatty acids in the presence of anionic sodium dodecyl sulfate (SDS) and nonionic-poly(ethylene...
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Analityka surfaktantów w próbkach środowiskowych
PublicationSurfaktanty stanowią grupę związków charakteryzujących się specyficznymi właściwościami fizykochemicznymi (m.in. amfifilowa budowa, zdolność rozpuszczania się w cieczach o różnej polarności, zdolność do tworzenia micelli) i z tego względu są one wykorzystywane w wielu sferach działalności człowieka. Związki powierzchniowo-czynne ulegają różnorodnym przemianom fizykochemicznym, co umożliwia ich migrację między różnymi elementami...
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Cold-Active beta-Galactosidases: Sources, Biochemical Properties and Their Biotechnological Potential
Publicationbeta-D-Galactosidases have been studied extensively in terms of their application to a variety of industrial technologies. To date, considerable research efforts have been devoted to characterization of new cold-active beta-D-galactosidases which were isolated directly from selected species of bacteria and yeasts, as well as with the use of metagenomic approaches. This chapter will provide a review of current research towards cold-active...
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Wetting properties of biosurfactant (rhamnolipid) with synthetic surfactants mixtures in the context of soil remediation
PublicationWetting properties of synthetic surfactant Rokanol NL6, biosurfactant JBR 425 and their mixture have been investigated.The results show that synthetic surfactant addition worsens physicochemical properties of pure biosurfactant but exhibits much higher oil removal efficiency than biosurfactant does.
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Emulsifi ers from renewable materials: an eco-friendly synthesis and properties
PublicationThe focus of this study was the preparation of novel bio based polyglycerol emulsifiers characterized by a one pot synthesis, thus by modified properties with respect to interfacial activity and effectiveness as emulsion stabilizers. The final products of the esterification process, carried out in the presence of carboxylates were used directly as emulsifiers (without purification or fractionation). Polyglycerol emulsifiers obtained...