Search results for: dehydrocoupling

• Syntheses, Structures and Reactivity of Terminal Phosphido Complexes of Iron(II) Supported by a β-Diketiminato Ligand

  Publication

  • K. Kaniewska-Laskowska
  • A. Dragulescu-Andrasi
  • Ł. Ponikiewski
  • J. Pikies
  • S. Stoian
  • R. Grubba

  - EUROPEAN JOURNAL OF INORGANIC CHEMISTRY - Year 2018

  We report the synthesis of the first series of terminal phosphido iron complexes supported by a β‐diketiminato ligand (Dippnacnac) and their catalytic activity in dehydrocoupling of secondary phosphines. Anionic and neutral mono‐ or diphosphido complexes were obtained from the reaction of [(Dippnacnac)FeCl2Li(dme)2] with the R2PLi (R = iPr, tBu, Cy, Ph) phosphides by tuning the stoichiometric ratio, polarity of the solvent, and...

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