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Search results for: excitation energy transport
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Study of excitation energy transport and degradation in aqueous solution of FMN
PublicationStudy of excitation energy transport and degradation in aqueous solution of FMN
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Nonradiative excitation energy transport and its analysis in concentrated systems
PublicationW pracy przedstawiono analizę transportu energii w roztworach dwuskładnikowych. Porównano wyniki pomiarów z modelem hoppingowym i diagramatycznym oraz z wynikami symulacji Monte Carlo. Stwierdzono dobrą zgodność wyników eksperymentalnych z przewidywaniami teorii i symulacjami komputerowymi.
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Excitation energy transport and trapping in concentrated solid solution of flavomononucleotide
PublicationW pracy analizowano bez promienisty transfer energii w stężonych stałych roztworach (folie polimerowe) FMN. W w/w roztworach występują świecące dimery FMN. Pokazano, że jedynie uwzględnienie powrotnego transferu energii pozwala zadowalająco wyjaśnić mechanizm przenoszenia energii w badanych układach.
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Excitation energy transport and trapping in concentrated solid solutions offlavomononucleotide.
PublicationPraca dotyczy właściwości transportu i pułapkowania energii wzbudzenia w układzie monomer dimer dla flawomononukleotydu rozpuszczonego w filmach alkoholu poliwinylowego. Pokazano, że w tym przypadku wydajność kwantowa i depolaryzacja nie dają się opisać w ramach teorii nie uwzględniającej powrotnego przekazywania energii i że znacznie lepsza zgodność uzyskanych wyników doświadczalnych zachodzi z teorią, w której fluoryzujące...
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Energy recovery effectiveness in trolleybus transport
PublicationNowadays the issue of electric energy saving in public transport is becoming a key area of interest whichis connected both with a growth in environmental awareness of the society and an increase in the pricesof fuel and electricity. One of the possibilities to reduce energy consumption in urban public transport isto increase the extent of regenerative braking energy utilization. This can be achieved by its accumulationin the supercapacitors...
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Excitation energy migration in uniaxially oriented polymer films.
PublicationPrzedstawiono wyniki pomiarów i symulacji Monte Carlo anizotropii emisji dla procesu bezpromienistego transportu energii w orientowanych osiowo foliach polimerowych. Badany układ stanowiły molekuły DTCI (3,3´-diethylthiacarbocyamine iodine) umieszczony w folii PVA (poliwinyl). Za przestrzenny rozkład orientacji dipoli emisji molekuł w symulacjach Monte Carlo przyjęto rozkład Tanizaki.
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Vibrational excitation of tetrahydrofuran by electron impact in the low energy range
PublicationWzbudzenie oscylacyjne cząsteczki tetrahydrofuranu w zderzeniach z elektronami przeprowadzone było w zakresie energii 5-14 eV w szerokim kącie rozproszenia (20°-180°). Pomiary funkcji wzbudzenia oscylacyjnego modów rozciągających w grupie CH2 (wiązania C-H) wykazują obecność struktur dla energii 6.0, 7.9 i 10.3 eV, którym można przypisać formowanie się stanów rezonansowych jonów ujemnych cząsteczki. W pracy wyznaczono także różniczkowy...
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Electronic excitation energy migration in partly ordered polymeric films
PublicationWieloetapowa migracja energii pomiędzy podłużnymi fluoroforami (karbocyjaniny) w osiowo rozciąganych foliach polimerowych była studiowana na podstawie pomiarów anizotropii emisji i symulacji Monte Carlo. W przeciwieństwie do układów nieuporządkowanych pokazano eksperymentalnie, że stężeniowa depolaryzacja fluorescencji w osiowo orientowanych foliach jest ekstremalnie słaba, mimo tego, że zachodzi zjawisko migracji energii. Opierając...
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Energy-Saving Inertial Drive for Dual-Frequency Excitation of Vibrating Machines
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Analysis of energy efficiency of suburban railway transport network
PublicationRising numbers of agglomeration residents cause increased need for people movement on daily basis. Because of congestion of local roads, air pollution and limited parking space, providing mass transit based on electric traction is reasonable. While the electric rail vehicles are considered highly efficient in themselves, they need to be analyzed as a part of a transport network, because energy consumption depends on operating conditions...
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Fluorescence depolarization in the presence of excitation energy migration in partly ordered polymer films.
PublicationW pracy przedstawiono wyniki pomiarów i symulacji Monte Carlo zaników anizotropii emisji fluorescencji dla układu 3,3'-diethylthiacyanine iodine (barwnik) w osiowo rozciąganych foliach polimerowych.
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Computed vibrational excitation ofCF4by low-energy electrons and positrons: Comparing calculations and experiments
PublicationQuantum calculations for the excitation of the asymmetric modes of the CF4 target gas, ν3 and ν4, by impact of low-energy electrons and positrons are carried out in the energy range around 1 eV and are compared with recent experimental findings. The similarities and differences between the two types of projectiles, and the two different modes, are analyzed and discussed vis à vis the present accord with the experimental results.
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Low-energy electron scattering from molecular hydrogen: Excitation of the X1Σg+ to b3Σu+ transition
PublicationWe present time-of-flight differential cross-section measurements and convergent close-coupling calculations of differential cross sections for the electron-impact excitation of the X 1 g + → b 3 u + transition in molecular hydrogen. A part of this work was recently published [M. Zawadzki et al., Phys. Rev. A 97, 050702(R) (2018)]. In this work, agreement between theory and experiment is excellent overall, and marks a transition...
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Excitation energy migration between elongated fluorophores in uniaxially oriented polyvinyl alcohol films
PublicationBezpromienisty wieloetapowy transfer energii jest studiowany dla molekuł DTCI w osiowo rozciąganych i nierozciąganych foliach poliwinylowych. Wyniki pomiarów zaników anizotropii znacznie różnią się dla rozciąganych i nierozciąganych folii. Dla układów nieuporządkowanych zaobserwowano szybką depolaryzację fluorescencji wynikającą z efektywnej migracji energii. Dla częściowo uporządkowanych układów, depolaryzacja była znacznie wolniejsza...
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Modern technologies in energy demand reducing of public transport — Practical applications
PublicationCity of Gdynia (Poland) exploits one of the most modern trolleybus network in Europe, which has been involved in many projects related to the reduction of energy consumption. Some of them are connected with the improving of energy breaking recovery usage. An experimental stationary storage system at Północna substation, which was tested in 2012-2014, is a bright example of a system which is connected with the improving of the...
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Excitation energy transfer in partly ordered polymer films differing in donor and acceptor transition moments orientation
PublicationBased on spectroscopic measurements selected properties of nonradiative Förster energy transport are studied in uniaxially stretched polyvinyl alcohol thin films for three systems differing in donor and acceptor transition moments orientation relative to the axis of stretching. In particular, donor – acceptor emission anisotropy spectra yield completely different regularities for these systems in uniaxially stretched films, whereas...
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Optimization of the efficiency of braking energy recovery in rail transport by changing arrival time
PublicationThe article refers to the previous work of the authors, in which the model of traffic organization of cooperating trains including the optimization of the use of energy returned to the catenary was presented. In the presented article, the model was modified by changing the main control variable, which affects the efficient use of energy. Departure time was changed for the arrival time of the train to the stop or station. The optimization...
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Elastic electron scattering and vibrational excitation of isoxazole molecules in the energy range from 2 to 20 eV
PublicationDifferential cross sections for elastic electron scattering and the excitation of the C-H vibrational modes of isoxazole molecules were measured in the energy range from 2 to 20 eV and over the scattering angle range from 10◦ to 180◦. The cross sections at the scattering angles of and above 90◦ were accessible with the use of a magnetic angle changer. The differential cross sections were integrated to yield integral and momentum...
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Reducing of energy consumption in public transport - results of experimental exploitation of super capacitor energy bank in Gdynia trolleybus system
PublicationPaper presents the result of test exploitation supercapacitor energy bank in Gdynia trolleybus system. In the first part of the article the basics of the regenerative breaking are presented and the construction and control strategy of the supercapacitor bank are described. The area of research and method of measurement are explained. In the second part of paper the results of tests and measurements are described. Emphasis was placed...
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O 1s excitation and ionization processes in the CO2molecule studied via detection of low-energy fluorescence emission
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Excitation energy transfer in partly ordered polymer films differing in donor and acceptor transition moments orientation
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Excitation energy migration in uniaxially oriented polymer films: a comparison between strongly and weakly organized systems
PublicationMechanizm wieloetapowej migracji energii w osiowo rozciąganych foliach polimerowych jest analizowany w układach o silnej i słabej orientacji molekuł barwników umieszczonych w matrycach poliwinylowych. Porównanie tych różnie orientujących się układów bazuje na zjawisku depolaryzacji stężeniowej anizotropii emisji, symulacjach Monte Carlo i wartościach liniowego dichroizmu. Pokazano, że uporządkowanie momentów przejścia fluoroforów...
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Excitation of the 1deltaU (V1B2) state of carbon disulfide by electron impact in the 3-12 eV energy range
PublicationZbadano wzbudzenie cząsteczek dwusiarczku węgla do stanu 1deltaU (V1B2). W pomiarach wykorzystano metodę optyczną, w której rejestrowano emisję fluorescencji w zakresie 300-600 nm.
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O 1s excitation and ionization processes in the CO2 molecule studied via detection of low-energy fluorescence emission
PublicationOxygen 1s excitation and ionization processes in the CO2 molecule have been studied with dispersed and non-dispersed fluorescence spectroscopy as well as with the vacuum ultraviolet (VUV) photon-photoion coincidence technique. The intensity of the neutral O emission line at 845 nm shows particular sensitivity to core-to-Rydberg excitations and core-valence double excitations, while shape resonances are suppressed. In contrast,...
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Low energy inelastic electron scattering from carbon monoxide: I. excitation of the a3Π, a’3Σ+ and AΠ1 electronic states.
PublicationDifferential scattering cross sections for electron excitation of the three lowest excited electron states of carbon monoxide are obtained experimentally using low-energy electron energy-loss spectroscopy and theoretically using the R-matrix method. The incident electron energies range from near-threshold of 6.3 eV to 20 eV. Experimental scattering angles range from 20◦ to 120◦. The normalization of the experimental cross sections...
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Luminescent GeO2–Pb–Bi2O3 glasses co-doped with Tb3+1 and Eu3+: Excitation energy transfer and color chromaticity
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Application of road map of operating condition for estimation of fuel and electric energy consumption from city transport
PublicationThe paper presents procedure of data collecting and generation of road map of operating condition in the selected urban area. This map allows forecasting the selected vehicle operating parameters for the assumed road. The main parameters calculated using the road maps of operating conditions are: total energy spent to drive the selected vehicle, consumed fuel, travel time, average speed of travel, CO2 emissions. Presented example...
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Low energy inelastic electron scattering from carbon monoxide: II. Excitation of the b3Σ+, j3Σ+, B1Σ+, C1Σ+ and E1Π Rydberg electronic states
PublicationIn this second part of a two part paper (first part: Zawadzki et al (2020 J. Phys. B: At. Mol. Opt. Phys. 53 165201)) we present differential scattering cross sections for excitation of several Rydberg electronic states of carbon monoxide by electron impact. The first part concerned the low-lying valence states of CO. In the present study cross sections are obtained experimentally using low-energy electron energy-loss spectroscopy...
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The impact of the overhead line's power supply system spatial differentiation on the energy consumption of trolleybus transport: planning and economic aspects
PublicationNowadays the issue of electric energy saving in public transport is becoming a key area of interest, which is connected both with a growth in environmental awareness of the society and an increase in the prices of fuel and electricity. It can be achieved by reducing of the transmission losses in supply system or by the improving of the usage of the regenerative breaking. The spatial differentiation of the energy supply system of...
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Decision Support in Selecting a Reliable Strategy for Sustainable Urban Transport Based on Laplacian Energy of T-Spherical Fuzzy Graphs
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Research on the Relationship between CO2 Emissions, Road Transport, Economic Growth and Energy Consumption on the Example of the Visegrad Group Countries
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ENERGY ANALYSIS OF PROPULSION SHAFT FATIGUE PROCESS IN ROTATING MECHANICAL SYSTEM PART I TESTING SIGNIFICANCE OF INFLUENCE OF SHAFT MATERIAL FATIGUE EXCITATION PARAMETERS
PublicationThe article discusses the problem of mathematical modelling of energy conversion processes in a rotating mechanical system for the purpose of identifying fatigue states of propulsion shafts in this system. A simplified physical model of the analysed system, constructed in an appropriate scale, has made the basis for the experimental research. The research programme took into consideration mechanical fatigue excitation of the model...
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$^{93m}$Mo Isomer Depletion via Nuclear Excitation by Electron Capture: Energy Released for Different Atomic Subshells as Benchmarks for a Beam-based Scenario Approach
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Differential cross sections for electron elastic scattering and vibrational v=1 excitation in nitrogen in the energy range [online] from 5 to 20 eV measured over an angular range 10deg-180deg
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Electron energy-loss spectra of isoxazole
Open Research DataThe data set contains numeric values of electron energy-loss spectra measured in isoxazole in the excitation energy range 3.5−10 eV. The data have been published in graphical form (figure 3 and figure 4) in the following paper:Ireneusz Linert, Mariusz Zubek "Excited states of isoxazole molecules studied by electron energy-loss spectroscopy"Journal...
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Electron energy-loss spectra of pyridazine
Open Research DataThe data set contains numeric values of electron energy-loss spectra measured in pyridazine in the excitation energy range 2.5−10 eV. The data have been published in graphical form (figures 3 - 6) in the following paper:
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Jarosław Guziński prof. dr hab. inż.
PeopleJaroslaw Guzinski received M.Sc., Ph.D. and D.Sc. degrees from the Electrical Engineering Department at Technical University of Gdansk, Poland in 1994, 2000 and 2011 respectively. Since 2016 he is Associate Professor at Gdansk University of Technology. Currently he is the head of the Department of Electric Drives and Energy Conversion. From 2006 to 2009 he was involved in European Commission Project PREMAID Marie Curie, ‘Predictive...
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Electron energy-loss spectroscopy of excited states of the diazine molecules: Pyridazine
PublicationExcitation of the valence electronic states of the pyridazine molecules in the gas phase have been studied using the technique of electron energy-loss spectroscopy. Varying the electron scattering conditions, the residual electron energy and scattering angle, enabled the optically-allowed and -forbidden excitations to be differentiated. The measured energy-loss spectra enabled the vertical excitation energies of the observed states...
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Excited states of isoxazole molecules studied by electron energy-loss spectroscopy
PublicationElectron energy-loss spectra were measured in isoxazole in the excitation energy range 3.5−10 eV to investigate the valence excited states. Spectra recorded at different scattering conditions enabled the identification of the singlet and triplet states and the determination of their vertical excitation energies. The two lowest energy triplet bands, ππ* 13A' and ππ* 23A' at 4.20 and 5.30 eV, respectively show vibrational progressions....
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A study of the electronic states of pyrimidine by electron energy loss spectroscopy
PublicationThe electron energy loss spectra were measured in pyrimidine at the constant electron residual energy varied from 15 meV to 10 eV and in the scattering angle range 0–180°. The spectra were analysed applying an iteration fitting procedure to resolve the energy loss bands corresponding to excitation of the electronic states of pyrimidine. The vertical excitation energies of the singlet states of pyrimidine and of a number of the...
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Electron energy-loss spectroscopy of excited states of the pyridine molecules
PublicationElectron energy-loss spectra of the pyridine, C5H5N, molecules in the gas phase have been measured to investigate electronic excitation in the energy range 3.5–10 eV. The applied wide range of residual electron energy and the scattering angle range from 10 ◦ to 180 ◦ enabled to differentiate between optically-allowed and -forbidden transitions. These measurements have allowed vertical excitation energies of the triplet excited...
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Leszek Jarzębowicz dr hab. inż.
PeopleLeszek Jarzebowicz received the M.Sc., Ph.D. and D.Sc. degrees from Gdansk University of Technology (GUT), Poland, in 2005, 2010 and 2019, respectively. His research areas include control and modeling of electric drives, diagnostics of railway vehicles, analysis of energy efficiency in electrified transport, and microprocessor implementation of control algorithms. His teaching interests focus on electric vehicles, electrical engineering...
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Electron collisions with cyanoacetylene HC3N : Vibrational excitation and dissociative electron attachment
PublicationWe experimentally probe electron collisions with HC3N in the energy range from 0 to 10 eV with the focus on vibrational excitation and dissociative electron attachment. The vibrational excitation cross sections show a number of resonances which are mode specific: the two dominant π∗ resonances are visible in the excitation of all the vibrational modes; however, broad σ ∗ resonances are visible only in certain bond-stretching vibrational...
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Unraveling Luminescent Energy Transfer Pathways: Futuristic Approach of Miniature Shortwave Infrared Light-Emitting Diode Design
Open Research DataPhosphor-converted shortwave infrared phosphor light-emitting diodes (pc-SWIR LEDs, 900–1700 nm) are promising next-generation portable light sources for spectroscopy, security, optical communication, and medical applications. A typical design strategy involves energy transfer from Cr3+ to Ni2+, and thus, energy transfer from Cr3+–Cr3+ pairs to Ni2+...
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Enhancement of self-trapped excitons and near-infrared emission in Bi3+/Er3+ co-doped Cs2Ag0.4Na0.6InCl6 double perovskite
Open Research DataErbium (Er) complexes are used as optical gain materials for signal generation in the telecom C-band at 1540 nm, but they need a sensitizer to enhance absorption. Na+ substitution for Ag+ and Bi3+ doping at the In3+ site is a possible strategy to enhance the broadband emission of Cs2AgInCl6, which could be used as a sensitizer for energy transfer to...
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Electronic states of tetrahydrofuran molecules studied by electron collisions
PublicationElectronic states of tetrahydrofuran molecules were studied in the excitation energy range 5.5-10 eV using the technique of electron energy loss spectroscopy in the gas phase. Excitation from the two conformations, C2 and Cs, of the ground state of the molecule are observed in the measured energy loss spectra. The vertical excitation energies of the 3(no3s) triplet state from the C2 and Cs conformations of the ground state of the...
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Effect of excitation intensity on slope stability assessed by a simplified approach
PublicationThe paper concerns the selection of a design accelerograms used for the slope stability assessment under earthquake excitation. The aim is to experimentally verify the Arias Intensity as an indicator of the excitation threat to the slope stability. A simple dynamic system consisting of a rigid block on a rigid inclined plane subjected to horizontal excitation is adopted as a slope model. Strong ground motions recorded during earthquakes...
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Dual role of oxygen-related defects in the luminescence kinetics of AlNMn2+
Open Research DataThis dataset presents the impact of temperature and pressure on AlN:Mn2+ luminescence kinetics. Unusual behavior of Mn2+ optical properties during UV excitation is observed, where a strong afterglow luminescence of Mn2+ occurs even at low temperatures. When the temperature increases, the contribution of the afterglow luminescence is further enhanced,...
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The luminescence study of Bi-doped Cs2AgInCl6 double perovskite.
Open Research DataHere, we report a halide precursor acid precipitation method to synthesize Cs2AgIn1−xBixCl6 (x = 0, 0.02, 0.04, 0.08, 0.16, 0.32, 0.64, and 1) microcrystals. Cs2AgInCl6 and Bi derivative double perovskites show broadband white light emission via self-trapped excitons (STEs) and have achieved the highest internal quantum efficiency of up to 52.4% at...
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A general approach to study molecular fragmentation and energy redistribution after an ionizing event
PublicationWe propose to combine quantum chemical calculations, statistical mechanical methods, and photoionization and particle collision experiments to unravel the redistribution of internal energy of the furan cation and its dissociation pathways. This approach successfully reproduces the relative intensity of the different fragments as a function of the internal energy of the system in photoelectron–photoion coincidence experiments and...